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1.
活性炭C40/4吸附甲苯和丙酮吸附性能研究   总被引:3,自引:1,他引:3  
为探讨活性炭吸附C40/4有机蒸汽的性能曲线规律,在不同温度288.15K,293.15K和298.15K下实验测试了活性炭C40/4吸附有机气体甲苯和丙酮的吸附性能,基于langmuir等温吸附理论,从吸附动态平衡的角度,理论分析了吸附性能曲线中参数与温度之间的关系,提出一个经验的langmuir等温吸附曲线模型,它能很好地描述不同温度下的有机蒸汽在活性炭上的吸附性能曲线,模型计算值与实验测试值之间的误差小于6%,为确定活性炭吸附有机蒸汽的吸附量提供了有效的计算模式,从而为有机蒸汽吸附过程的设计、预测和优化提供有益的支持。  相似文献   

2.
基于对现有页岩吸附、超临界吸附的认识通过基本假设和统计热力学基本原理推导出一个高温高压等温吸附新模型,并用GAI-100高压等温吸附仪获取95.6℃下页岩及活性炭在0~50 MPa压力范围内的等温吸附曲线,研究结果表明:页岩及活性炭的高温高压等温吸附曲线具有超临界高压等温吸附曲线的典型特征即随着压力的增大过剩吸附量先增大后减小;该新模型能很好地描述页岩及活性炭的高温高压等温吸附曲线,说明此模型在很大程度上反映出超临界高压吸附的特性而且可用来描述页岩及活性炭的高温高压等温吸附曲线。  相似文献   

3.
从Gibbs关于吸附的定义出发,结合Langmuir—Freundlich(L—F)方程描述了甲烷吸附的超临界吸附等温线模型,将模型应用于30℃下静态容积法测试的煤吸附甲烷的吸附等温线数据回归,模型对实验数据的拟合的相关系数R在0.9986以上.并分析了煤表面自由能的形成过程和特点,进一步根据表面化学的原理计算了煤的表面自由能。  相似文献   

4.
]为研制ANG新型碳基吸附剂,分别选用比表面积为2074 m2·g-1的椰壳活性炭SAC-02和345 m2·g-1的石墨烯,在温度区间263~313 K、压力范围0~6 MPa,依据容积法的原理测试了甲烷在其上的吸附平衡数据,并由吸附等温线和等量吸附热的比较,分析了甲烷在两吸附剂上吸附平衡.结果表明:甲烷在活性炭上的过剩吸附等温线为典型的Ⅰ型,而石墨烯上在压力2 MPa以下为Ⅰ型,2~6 MPa之间吸附量与压力接近线性关系.在273 K和6 MPa时,甲烷在石墨烯上吸附量为4.6 mmol·g-1,活性炭的吸附量为11.2 mmol·g-1;甲烷在石墨烯和活性炭上的等量吸附热分别为14.32 kJ·mol-1~2.66 kJ·mol-1和13.99 kJ·mol-1~17.57 kJ·mol-1,石墨烯表面对甲烷分子作用能强  相似文献   

5.
采用重量法对加温加压下苯和环己烷在γ-Al2O3颗粒上的吸附进行了研究.实验结果表明,随着吸附温度升高,吸附等温线的滞后环逐渐朝着相对压力增大的方向移动且宽度变窄;苯和环己烷在γ-Al2O3上的吸附类似.将改进的Halsey方程和Kelvin方程相结合,建立起描述上述吸附过程的理论模型,实验结果验证了该模型的准确性.  相似文献   

6.
分散MgO对活性炭纤维结构及吸附性能的影响   总被引:1,自引:0,他引:1  
以Mg(NO3)2及沥青基炭纤维(pitch-based carbon fiber-PCF)为原料,通过热分解方法在沥青基活性炭纤维上分散纳米级MgO颗粒,平均粒径50nm,并用XRD,XPS,SEM,BET对分散MgO的沥青基活性炭纤维的微观结构进行了分析。同时考察分散MgO后沥青基活性炭纤维的甲烷吸附性能。负载MgO的沥青基活性炭纤维的比表面积为1210m^2/g,4Mpa下的甲烷吸附量为0.124g/g。  相似文献   

7.
改性活性炭吸附H2S和C2H2相平衡研究   总被引:6,自引:0,他引:6  
开发了一种新型改性活性炭,用定容法测定了H2S和C2H2在活性炭上吸附的平衡数据。由此得到的吸附等温方程符合Freundlich模型。该模型与实验数据吻合,平均相对误差为1.1% ̄3.1%。  相似文献   

8.
新型富集材料的研究及应用   总被引:2,自引:0,他引:2  
研究了4种螯合剂在活性炭上的吸附和解吸特性,并在pH7,0-7.5范围内对8种元素进行了在二元螯合活性炭柱上的吸附、硝酸反洗及样品分析试验。结果表明,本富集材料适合于野外现场直接富集水质中8种痕量元素,富集倍数为100,变异系数为0.58%-2.48%之间,加入回收率在96.3%-105.5%之间,可用原子吸收法分析。  相似文献   

9.
新型竹活性炭对水体违禁药物孔雀石绿吸附性能的影响   总被引:1,自引:0,他引:1  
为去除水体残留的违禁药物孔雀石绿,采用自制竹活性炭以及3种市售竹炭为吸附剂,将孔雀石绿溶液作为吸附体系,研究27,35和40℃时孔雀石绿在活性炭上的吸附平衡与动力学,检测违禁药物孔雀石绿的残留量,并对自制和市售吸附剂的吸附性能进行对比。研究结果表明:高比表面积活性炭对废水中残留孔雀石绿去除效果明显;Freundlich吸附等温线模型可较好地用于描述孔雀石绿在活性炭上的吸附平衡,Freundlich常数KF随比表面积和孔容的增大而增大,自制竹活性炭性能更佳;准二级方程可用于描述孔雀石绿在活性炭上吸附的最佳动力学模型,并可得到相应动力学参数;对同一种吸附剂,温度对吸附动力学速率常数有较大的影响,在35℃时,速率常数最小。  相似文献   

10.
提出一个能描述中孔活性炭吸附氮气毛细孔凝聚作用的吸附等温式,实验表明:在相对压强小于0.9的范围内,吸附氮气体积的理论值与实验值能很好地吻合,为研究气体在固体表面的第Ⅳ和第Ⅴ类吸附提供了科学依据。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

15.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

16.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

17.
以AC-13级配为基础,将橡胶颗粒代替部分集料掺入混合料中,以低温弯曲试验为评价方法对不同橡胶颗粒掺量下沥青混合料的低温抗裂性进行研究,并引入应变能密度值对混合料的低温抗裂性进行综合评价.试验结果表明:橡胶颗粒沥青混合料试件的破坏微应变均超过2 300,满足冬寒区的技术指标;无论是否掺加橡胶颗粒,随着温度的下降,沥青混合料破坏时的最大弯拉强度增大,弯拉应变降低,劲度模量增大;弯曲应变能密度在胶粒掺量为1%左右时具有较大的弯曲应变能密度值,此时橡胶颗粒沥青混合料具有较好的低温抗裂性.  相似文献   

18.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

19.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

20.
Quality traits in wheat (Triticum aestirum L.) were studied by quantitative trait locus (QTL) analysis in a recombinant inbred line (RIL) population, a set of 131 lines derived from Chuan 35050 × Shannong 483 cross (ChSh). Grains from RILs were assayed for 21 quality traits related to protein and starch. A total of 35 putative QTLs for 19 traits with a single QTL explaining 7.99-40.52% of phenotypic variations were detected on 10 chromosomes, 1D, 2A, 2D, 3B, 3D, 5A, 6A, 6B, 6D, and 7B. The additive effects of 30 QTLs were positive, contributed by Chuan 35050, the remaining 5 QTLs were negative with the additive effect contributed by Shannong 483. For protein traits, 15 QTLs were obtained and most of them were located on chromosomes 1 D, 3B and 6D, while 20 QTLs for starch traits were detected and most of them were located on chromosomes 3D, 6B and 7B. Only 7 QTLs for protein and starch traits were co-located in three regions on chromosomes 1D, 2A and 2D. These protein and starch trait QTLs showed a distinct distribution pattern in certain regions and chromosomes. Twenty-two QTLs were clustered in 6 regions of 5 chromosomes. Two QTL clusters for protein traits were located on chromosomes 1D and 3B, respectively, three clusters for starch traits on chromosomes 3D, 6B and 7B, and one cluster including protein and starch traits on chromosome 1D.  相似文献   

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