玉米秸秆纤维复合缓冲包装材料的研究

研究了以聚醚多元醇、聚异氰酸酯为基体,以玉米秸秆纤维为增强体的新型复合缓冲包装材料,通过控制玉米秸秆纤维的添加量、发泡剂用量、交联剂与催化剂用量、反应温度等工艺参数,实验制备了具有可降解性能的缓冲包装材料,并利用静态压缩实验方法对比了该材料与发泡聚苯乙烯的缓冲性能.     

PTMC-LLA共聚物及PLGA纤维增强PTMC-LLA共聚物的力学性能和降解行为

通过开环聚合合成了PTMC-LLA共聚物并采用PLGA纤维增强制备了新一代生物可降解心血管支架材料.使用1 H NMR、GPC和DSC等仪器分析了PTMC-LLA共聚物的化学结构和性能,采用静力拉伸测试了共聚物及其增强材料的拉伸强度.力学测试结果显示,通过PLGA纤维增强,得到了拉伸强度为46MPa的复合材料,可作为支...     

剑麻增强氰乙基化木复合材料的研究

报道了一种全天然植物纤维复合材料。该材料是以塑化的天然植物纤维(木粉)作为基体树脂,以天然植物纤维(剑麻)作为增强材料。通过氰乙基化反应,使木粉转化成为热塑性材料,再与短切剑麻纤维混合,热压制得植物纤维增强塑化植物纤维基复合材料。这种全天然纤维复合材料不仅具有与植物纤维增强传统聚合物基复合材料相似的性能,而且价廉、环境友好。     

酚醛树脂基减摩复合材料的研究

通过实验研究了树脂基减摩复合材料中树脂、纤维对减摩材料的机械性能、摩擦性能的影响。在此基础上，以实验室自制的改性酚醛树脂为基体，以混杂纤维及复合润滑组份为增强材料，研制出一种高强度、低摩擦系数小磨损量的酚醛树脂基纤维增强减摩复合材料。这种新型材料已通过技术成果鉴定，可望应用于电车滑块、机车受电弓等多种用途。     

加固用CFRTP模压成型工艺及片材力学性能研究

针对传统的混凝土结构加固用纤维增强热固性复合材料的一系列缺点，提出用热塑性树脂来制备加固用复合材料．并且研究了连续芳纶纤维Keylar49增强热塑性树脂基复合材料的模压成型工艺和片材力学性能．所研制的复合材料力学性能达到国外现有加固材料指标．纤维和片材的SEM照片表明该材料的破坏是韧性破坏，且纤维和树脂存在最佳配比，在该配比下树脂能良好地浸润纤维束．     

生态节能复合墙体植物纤维水泥基材料试验

农作物秸秆纤维水泥基复合材料是一种新型的绿色环保建材产品,密肋复合墙结构是适应我国墙体改革及住宅产业化要求的产物.通过对4组不同配合比稻秸秆纤维水泥基材料的试验研究,就其掺量对复合材料物理及力学性质的影响进行了探讨,通过ANSYS有限元分析,模拟了稻秸秆纤维水泥基砌块墙板的受力性能.试验表明,6%掺量的试件各项性能指标较符合墙板的砌块材料要求.     

炭纤维增强树脂炭复合材料微观结构与烧蚀性能

采用金相显微镜和扫描电镜对炭纤维增强树脂炭复合材料微观结构进行分析,采用等离子烧蚀方法研究了炭纤维增强树脂炭复合材料不同方向的烧蚀性能,并对其烧蚀表面形貌进行扫描电镜观察,分析了复合材料烧蚀性能差异的原因.研究结果表明:炭纤维增强树脂炭复合材料中炭纤维和树脂炭结合较好,基体中产生了应力石墨化,材料烧蚀优先从纤维与树脂炭的界面及缺陷处开始,轴向垂直于气流方向的纤维越多,材料烧蚀率越小.     

水悬浮法制备玻璃纤维／聚氯乙烯复合材料的研究

阐述了水悬浮法制备纤维增强热塑性树脂基复合材料的主要优点,着重研究了用水悬浮法制备玻璃纤维增强聚氯乙烯复合材料的工艺技术和工艺配方以及用该方法制备的复合材料的性能．并研究了水悬浮法制备ＧＦ／ＰＶＣ复合材料的界面层设计及其对材料性能的影响     

A型分子筛/活性炭纤维复合材料的制备与吸附性能研究

为获得一种具有高效吸附性能的微孔吸附材料,以黏胶基活性炭纤维为基材,采用溶胶-凝胶水热合成法制备了A型分子筛/活性炭纤维复合材料。通过XRD、SEM、N2吸附等测试方法对该材料的晶体结构、形貌和孔隙结构进行表征,通过复合材料对低浓度二氯甲烷气体的吸附研究,系统考察了晶化温度和晶化时间对复合材料吸附性能的影响。结果表明:与活性炭纤维基材相比,分子筛/活性炭纤维复合材料的吸附性能有所提高。晶化温度和晶化时间对复合材料的吸附性能影响显著,当晶化温度为100℃、晶化时间为6h时,复合材料对二氯甲烷表现出最佳吸附性能。     

碳纤维增强树脂基复合材料力学性能预测

利用有限元软件ABAQUS作为建模计算平台,应用Python语言编程,实现了纤维增强复合材料有限元模型中纤维体积分数含量的控制和各向异性材料局部坐标与整体坐标下输出变量的转换,对碳纤维增强树脂基复合材料的基本力学性能进行了预测,提出了预测纤维增强复合材料基本力学性能的新方法.可对不同性能的纤维、基体材料、不同纤维体积分数含量、不同纤维铺设铺层角度、不同加载方向的纤维增强复合材料的力学性能进行预测.     

聚甲基乙撑碳酸酯/淀粉复合材料的形貌、机械性能和热性能研究

采用溶液共混方法制备了聚甲基乙撑碳酸酯(PPC)/淀粉复合材料,并对其形貌、机械性能和热性能进行了表征.复合材料的模量随淀粉含量的增加而提高,拉伸强度在淀粉含量小于35%时有明显提高.复合材料的玻璃化转变温度和5%失重温度分别比纯PPC提高10℃和30℃左右.TEM表明复合材料中PPC基体与淀粉有较好的界面相互作用.GPC表明复合材料中PPC的分子量由于淀粉的架桥作用而显著提高.     

聚碳酸亚丙酯/淀粉在城市垃圾中生物降解性能研究

将聚碳酸亚丙酯新型高分子材料与淀粉进行共混, 研究了共混物的机械性能及其在城市垃圾中的生物降解过程.结果表明, 淀粉的加入可提高材料的拉伸强度和拉伸模量, 促进聚碳酸亚丙酯的微生物降解速度. 降解实验显示半年降解样出现大量空洞, 共混物中聚碳酸亚丙酯的数均分子量下降40.5%,其降解可分为三个过程, 分别对应微生物的生长、淀粉的降解及PPC的降解. 红外测试表明半年降解样仍含有少量淀粉.     

Research on Flax Fiber Reinforced Polylactide Environmental Friendly Composite

Biodegradable polylactide acid （PLA） resin can be combined with flax fibers to produce biodegradable composite materials. In our study, commercial PLA fibers were mixed with flax fibers by a non-woven method so as to make non- woven pre-forms, which can be generated into flax fiber reinforced PLA environmental friendly composites by heat pressing technology. The tensile, flexural and impact properties are tested in order to evaluate the basic physical properties of the composites, and the influenced factors listed as making technology of the pre-forms, weight ratio of flax fibers and heat pressing technology are discussed and optimized, which can be described as weight ratio of flax fibers and PLA fibers is 50/50, heating temperature, time and pressure are respectively 195℃, 20 rain and 12.5 Mpa. Preliminary results show that mechanical properties of the flax/PLA composites are quite promising compared with flax/PP composites in coclrnon commercial automotive use. Scanning electron microscope （SEM） is used to analyze the tensile specimen fracture surfaces, which shows voids and gaps occurring between flax fibers and PLA matrix and sign of fiber pull.out, the strength of flax/PLA interface can be further improved.     

聚丁二酸丁二醇酯/氢氧化镁生物可降解阻燃复合材料的性能研究

熔融挤出制备了聚丁二酸丁二醇酯/氢氧化镁（PBS/Mg(OH)2）生物可降解阻燃复合材料,并对其熔体流动性、热稳定性、阻燃性能、结晶与熔融行为和力学性能进行研究. 结果表明,加入Mg(OH)2降低了PBS的熔体流动速率,延缓PBS在燃烧过程中的分解,有效提高PBS的极限氧指数和抗滴落性能. Mg(OH)2对PBS结晶具有的异相成核作用,显著提高PBS的结晶温度并改变PBS的熔融行为. 当Mg(OH)2质量分数低于40%时,Mg(OH)2提高PBS的拉伸强度、拉伸模量、弯曲强度和弯曲模量,但降低PBS的断裂伸长率和冲击强度;当Mg(OH)2质量分数大于50%时,由于PBS和Mg(OH)2的相容性较差,PBS/ Mg(OH)2复合材料在拉伸和弯曲过程中均呈现出脆性断裂现象,导致拉伸强度和弯曲强度降低.     

Forming of magnesium alloy microtubes in the fabrication of biodegradable stents

Magnesium alloys have, in recent years, been recognized as highly promising biodegradable materials, especially for vascular stent applications. Forming of magnesium alloys into high-precision thin-wall tubes has however presented a technological barrier in the fabrication of vascular stents, because of the poor workability of magnesium at room temperature. In the present study, the forming processes, i.e., hot indirect extrusion and multi-pass cold drawing were used to fabricate seamless microtubes of a magnesium alloy. The magnesium alloy ZM21 was selected as a representative biomaterial for biodegradable stent applications. Microtubes with an outside diameter of 2.9 mm and a wall thickness of 0.2 mm were successfully produced at the fourth pass of cold drawing without inter-pass annealing. Dimensional evaluation showed that multipass cold drawing was effective in correcting dimensional non-uniformity arising from hot indirect extrusion. Examinations of the microstructures of microtubes revealed the generation of a large number of twins as a result of accumulated work hardening at the third and fourth passes of cold drawing, corresponding to the significantly raised forming forces. The work demonstrated the viability of the forming process route selected for the fabrication of biodegradable magnesium alloy microtubes.     

Preparation and Properties of Cellutose-Alginic Acid Interpolymeric Complex Films

1 Introduction General synthetic polymers such as polyethylene, polyvinyl chloride, polystyrene etc. have been produced and used in large quantities. They are very cheap, but their wastes are difficult to decompose in nature so to cause environmental pollution .In order to overcome such disadvantage, various kinds of biodegradable synthetic polymers such as polyactic acid, aliphatic polyester, polyvinyl alcohol complexes etc. have been researched~([1]). However, they are expensive, so cannot b…     

Fabrication and Properties of Porous Film/Fabric Composites for Vascular Scaffold Application

A composite vascular scaffold combining textile reinforced structure and biodegradable polymer is introduced, which may possess high porosity and connectivity. Moreover, the porous size could be controlled. The proposed scaffold consists of a warp-knitted poly （ethylene terephthalate ） （PET） fabric with well-defined macropores, which is embedded with a porous biodegradable polymer membrane. The aim of this paper is to study the fabrication and properties of porous polymer membrane through optimizing the parameter of composite methods from freeze drying/particle leaching （ FD/PL ） and gas foaming/particle leaching （ GF/PL ）, subsequently combining with the warp-knitted fabric. Weighing method was utilized to analyze the porosity of the samples and the scanning electron microscope （SEM） images were taken to observe the porous structure of the vascular membrane. In addition, ,the static contact angle （CA） was measured to estimate the hydrophilicity of the samples, and the tensile testing of the composites was performed on the universal mechanical tester. Furthermore, the water permeability of the membrane was also calculated. The results showed that the porosity and pore connectivity of the vascular membrane were diverse, became of solution concentration, particle size, ratio of content, etc. Meanwhile, the stress-strain curves and the bursting strength showed the different mechanical properties among composite scaffolds in different structures.     

石墨烯增强铝基复合材料研究进展

铝基复合材料作为金属基复合材料中最重要的材料之一,在工业生产以及日常生活中有着非常广泛的应用。石墨烯由于其高导热性、高阻尼性、高弹性模量、高强度以及良好的自润滑性成为复合材料中重要的增强体。将石墨烯用作增强体增强铝基复合材料有着非常大的应用潜力。归纳了石墨烯增强铝基复合材料的研究进展;总结了影响其性能的主要因素即增强体材料种类,石墨烯在铝基体中的均匀分散性以及铝基体与石墨烯之间的界面情况;介绍了石墨烯增强铝基复合材料的两种制备方法;分析了石墨烯增强铝基复合材料的增强机制;并展望了其发展前景,以期为制备高性能石墨烯增强铝基复合材料提供参考。     

热氧老化对高密度聚乙烯/木粉吸水性能的影响

选用高密度聚乙烯(HDPE)和木粉为主要原料,马来酸酐接枝聚乙烯作界面增容剂,采用模压工艺制造木塑复合材料,同时加入不同抗氧剂,对不同木塑复合材料分别进行热氧老化实验,取不同老化时间段的样品置于自来水中常温浸泡,研究热氧老化对木塑复合材料吸水性能的影响。结果表明：热氧老化后的木塑复合材料吸水性能仍然遵循材料吸水过程的一般规律,即初始阶段吸水较快,之后将达到吸水平衡;但随着老化时间的延长,木塑复合材料吸水现象更加严重。不同的抗氧化剂对木塑复合材料的吸水性能存在不同的影响。     

海洋环境玻璃纤维增强复合材料自然老化试验

采用海水浸泡-阳光暴晒循环老化的方法来模拟海洋环境中复合材料的实际工作环境,分别评价手糊和真空成型两种玻璃纤维复合材料在海洋环境中的耐久性.通过对老化前后复合材料的质量变化、轴向拉伸强度和面内剪切强度的分析,研究玻璃纤维增强复合材料的老化规律.结果表明:经过湖北武汉和海南三亚70d的自然循环老化,增质量率随时间的增加而增加,干燥试件强度大于湿态试件剩余强度,武汉试件老化剩余强度大于三亚试件剩余强度,手糊和真空成型2种工艺的玻璃纤维增强复合材料表现出不同的老化规律和失效类型.