单极手机天线电磁辐射的数值模拟

在建立手机辐射的电磁模型和分层球型人脑模型基础上,利用时域有限差分法计算了900 MHz频率时单极手机天线作用下人脑内比吸收率的分布,重点讨论了在不同通话情况下手机距人体头部不同距离时人脑中比吸收率的分布情况。计算结果表明:手机距人体头部越近人脑内比吸收率值越大,当戴有金属边框眼镜或在金属壁旁通话时,人脑内比吸收率会有不同程度的增加。     

黄铜铬酸表面膜的导电性

采用金属－膜金属结构测量了黄铜在铬酸中形成的表面膜的导电性。实验得到膜的导电性良好，虽为半导体，却表现出准金属行为这一瑟文献报导不同的结论。     

金属纳米颗粒的极化率与异常光学性质

基于金属纳米材料的异常光学现象,考虑了束缚电荷作用的情况,从理论上推导出在光波照射下金属纳米颗粒的极化率与颗粒尺度关系的结果,进而得到金属颗粒对光波的吸收率,并讨论颗粒尺度对极化率和吸收率的影响,即当金属粒子尺寸达到纳米级时,将金属粒子看作纳米小球,小球极化率出现半径的立方因子,且小球半径小于电子平均自由程,电子的衰减因子受小球半径的制约.由推导结果可以得出,光吸收峰增强,并产生红移.这些结果为深入理解金属纳米颗粒的异常光学性质,揭示和开发应用金属纳米材料的性质提供理论基础.     

Cl-对镁-铝合金β相模型合金表面膜稳定性的影响

采用电化学阻抗测试技术(EIS)、Mott-Schottky方法对β相模型合金在Cl-溶液环境中形成的表面膜的稳定性和半导体特性进行研究.结果表明,Cl-浓度的增加,使β相表面膜形成和活化溶解的趋势均加剧,即表面膜的稳定性变差.原因在于Cl-浓度较低时,β相表面膜的半导体类型为P型,P型半导体膜是一种阳离子导体膜,Cl-很难通过迁移扩散的方式穿过表面膜.随着Cl-浓度的增大,β相表面膜的半导体类型转变为N型,N型半导体膜便于Cl-穿越膜层到达膜层底部,继续腐蚀金属并使表面膜发生破裂.     

金属边框眼镜对手机辐射剂量的影响

基于医学解剖学人体模型,建立包括头部和手部的人体电磁模型,通过数值模拟计算,在垂直和旋转两种手机操作方式下,分析了配戴金属边框眼镜对人体所受手机天线电磁辐射剂量的影响.结果表明:配戴金属边框眼镜会导致手机天线对人体辐射的比吸收率明显增加,尤其是对人眼的比吸收率增幅可达到1倍以上,但所有计算值未超出目前公认的国际非电离辐射防护标准.     

椭园法在金属腐蚀研究中的应用

金属的腐蚀与防护,都与其表面膜的特性有关。椭园法是研究金属表面膜的一种有用工具。本文对椭园法在金属腐蚀研究中的应用作了概括的介绍。     

石墨烯可调谐双频完美吸收器设计

利用石墨烯优异的可调光学特性，设计了一种由石墨烯谐振器、SiO₂介质层及金属反射层组成的可调谐双频完美吸收器，研究了石墨烯化学势、偏振角及尺寸大小对吸收器吸收性能的影响，并分析了共振频率处的电场模式，进一步解释吸收器的吸收原理.结果表明，吸收器在6.363 THz和8.987 THz处的吸收率分别为99.98%和99.99%;吸收峰位可通过改变石墨烯化学势进行有效调节，0°～80°范围内的任意偏振角下，峰值吸收率均可达90%以上；SiO₂介质层厚度对吸收器的共振峰位几乎没有影响，但对峰值吸收率有一定影响，随着厚度的逐渐增加，吸收率先升高后降低，在厚度为3.1μm附近时实现完美吸收.以上结果说明，吸收器的高吸收率主要源于电磁共振作用.     

CTAB表面膜在金属防腐蚀上的应用

本文研究了在碳钢样片上强化制备CTAB表面膜的条件,所制CTAB表面膜的防腐蚀系数平均达到90％以上。经过CTAB表面膜预处理的碳钢样片提高了与氯磺化聚乙烯涂料的附着性能。从而明显地提高了氯磺化聚乙烯涂料的防腐蚀性能。其次,经过CTAB表面膜和氯磺化聚乙烯涂料处理的钢筋与混凝土的粘接系数增加36％,这是适用于钢筋混凝土防腐工程的一个有价值的信息。     

原油各组分表面膜性质的研究

从草桥重质原油和草桥重油中分离出饱和分、芳香分、胶质和沥青质,用Ｌａｎｇｍｕｉｒ膜天平研究了这些物质在水面上形成的表面膜的膜压及水相ｐＨ值对膜压的影响。研究结果表明,在相同的归一化面积下,沥青质表面膜的膜压明显高于其它组分的表面膜膜压。与沥青质相比,胶质的表面膜膜压随水相ｐＨ值的增大有较显著的增高。     

基于石墨烯光电特性的超宽带可调超材料吸波体设计

利用石墨烯的电导率可调特性设计了一种超宽带可调超材料吸波体。模拟计算了不同石墨烯费米能级时吸波体的吸收率,结果表明,当石墨烯费米能级为0.7 eV时,吸波体在1.74 GHz ~10.44 GHz 的吸收率保持在90%以上,实现了电磁波的超宽带吸收;当改变外加电压使石墨烯的费米能级从0.7 eV逐渐减少到0 eV时,吸波体在1.74 GHz~10.44 GHz的吸收率逐渐下降,其调制深度可达53.8%,实现了吸收率可调的功能;通过对表面电流分布进行仿真与分析,阐述了其电磁波宽带吸收及吸收率可调的机理;模拟分析了石墨烯费米能级为0.7 eV时,入射波极化状态和入射角度对吸波体吸收特性的影响,结果表明,由于结构单元的旋转对称性,吸波体的吸收特性具有极化不敏感的特点;随着电磁波入射角度的增大,其吸收率逐渐降低。     

Anodic dissolution of metals in ionic liquids

The anodic dissolution of metals is an important topic for battery design, material finishing and metal digestion. Ionic liquids are being used in all of these areas but the research on the anodic dissolution is relatively few in these media. This study investigates the behaviour of 9 metals in an ionic liquid [C4mim][Cl] and a deep eutectic solvent, Ethaline, which is a 1:2 mol ratio mixture of choline chloride and ethylene glycol. It is shown that for the majority of metals studied a quasi-passivation of the metal surface occurs, primarily due to the formation of insoluble films on the electrode surface. The behaviour of most metals is different in [C4mim][Cl] to that in Ethaline due in part to the differences in viscosity. The formation of passivating salt films can be decreased with stirring or by increasing the electrolyte temperature, thereby increasing ligand transport to the electrode surface.     

Influence of substrate metals on the crystal growth of AlN films

AlN films were deposited by reactive radio frequency (RF) sputtering on various bottom electrodes, such as Al, Ti, Mo, Au/Ti, and Pt/Ti. The effects of substrate metals on the orientation of AlN thin films were investigated. The results of X-ray diffraction, atomic force microscopy, and field emission scanning electron microscopy show that the orientation of AlN films depends on the kinds of substrate metals evidently. The differences of AlN films deposited on various metal electrodes are attributed to the differences in lattice mismatch and thermal expansion coefficient between the AlN material and substrate metals. The AlN film deposited on the Pt/Ti electrode reveals highly the c-axis orientation with well-textured columnar structure. The positive role of the Pt/Ti electrode in achieving the high-quality AlN films and high-performance film bulk acoustic resonator (FBAR) may be attributed to the smaller lattice mismatch as well as the similarity of thermal expansion coefficient between the deposited AlN material and the Pt/Ti electrode substrate.     

低温等离子体诱导下导电高分子复合膜的制备

利用等离子体技术对PET薄膜进行表面处理,并诱导引发AAc在其表面接枝聚合,制备PAAc-g-PET复合膜,用化学氧化方法使PPy接枝聚合在PAAc-g-PET表面,制备出PPy-g-PAAc-g-PET复合膜.利用ATR-FTIR和SEM对制备的复合膜分别进行结构和表面形貌分析.导电性测试结果表明,PPy-g-PAAc-g-PET复合膜的导电性也明显提高.同时考察了温度、时间、浓度等对PPy-g-PAAc-g-PET复合膜接枝率的影响,得到PET薄膜接枝PPy的最佳条件为温度60 ℃,反应时间6 h.研究结果表明,PPy能很好地接枝到PAAc-g-PET复合膜的表面.     

退火处理对等离子体显示器中氧化镁薄膜特性的影响

研究了电子束蒸发法制备的氧化镁薄膜在退火处理过程中特性的变化.研究表明:退火处理改善了薄膜的结晶性,降低了红外光谱中水分子吸收峰的强度,并使得低温或低通氧气量制备的氧化镁薄膜的可见光透射比下降,且这些薄膜在退火处理中极易产生裂纹.薄膜的结晶取向或结晶性是薄膜可见光谱变化和表面裂纹产生的主要原因,薄膜表面光洁度对可见光谱变化影响不大.     

Surface Modification of Anionic Polyurethane with Silk Fibroin Peptide and Its Effects on the Culture of Fibroblasts

The surface modification of the anionicpolyurethane(APU) film was carried out by immersing it insilk fibroin peptide(SFP) solution for 12 h and then treatingwith low temperature plasma glow discharge. The physicalproperties and moisture permeability of modified films wereexamined. The results showed that SFP-modified APU filmshad better moisture permeability than oleophilicpolyurethane, as well as modified APU films kept goodflexibility. Modified APU films could overcome rigid andbrittle weaks of silk fibroin films. The morphology of SFPon the APU film was corpuscular aggregations. The water-contact angle measurement indicated that the change ofhydrophilicity and the element chemical analysis suggestedthat the SFP-modified film surface was enriched withnitrogen atoms. The biocompatibility of APU films may beimproved due to the change of surface compooents. Cellviability and proliferation of rat embryo dermal fibroblastsseeded on control films, APU films and SFP-modified APUfilms were evaluated by MTT assay and viable cell counts,respectively. The results indicated that the APU filmmodified by SFP protein showed the proliferation offibroblasts on the film, and that the compound interface hadgood stability in the air. Results also showed thatpresoaking treatment for APU films was effective toaccomplish the goal of surface modification.     

润滑表面膜在线电测技术研究

为了在线研究摩擦副中表面膜的变化,提出采用摩擦副间的动态接触电阻定性地表征表面膜状态的测试技术．测量电路包括四臂电桥测电阻,信号放大、光耦隔离等模块．针对往复运动的特点,提出了可揭示表面膜状态的数据处理方法,并在自制的缸套／活塞环摩擦试验机上进行润滑条件下表面膜形成和损伤的试验研究．研究表明：采用接触电阻法可在线观测表面膜的形成、损伤及恢复等表面膜变化比较显著的过程．     

Effect of Cu surface segregation on the exchange coupling field of NiFe/FeMn bilayers

The NiFe/FeMn bilayers with different buffer layers (Ta or Ta/Cu) were prepared by magnetron sputtering. Results show that the exchange coupling field of NiFe/FeMn films with Ta buffer is higher than that of the films with Ta/ Cu buffer. We analysed the reasons by investigating the crystallographic texture, surface roughness and surface segregation of both films, respectively. We found that the decrease of the exchange coupling fields of NiFe/FeMn films with Ta/ Cu buffer layers was mainly caused by the Cu surface segregation on NiFe surface.     

原位氧化制备氧化锌薄膜及其表征

在云母基底上热蒸镀锌膜,再采用简单的原位氧化方法制备氧化锌薄膜.研究发现氧化锌膜上表面具有纳米尺度的丛生珊瑚状结构,而与云母接触的下表面具有圆饼状结构.     

聚吡咯对PC-12细胞轴突生长情况的研究

在导电玻璃表面电化学聚合聚吡咯,通过改变掺杂剂和膜层数得到三种聚吡咯膜,利用Hitachi-530扫描电镜观测其表面性能,在阳极电刺激下,使用光学显微镜等观察接种神经细胞的黏附数量。由此得出：聚吡咯表面性能和医学性能可以通过改变掺杂剂,膜层数来进行调整。     

钨铜基电镀铝层阳极氧化后的组织和性能研究

采用直流草酸法对镀铝层进行阳极氧化,研究了氧化电压和氧化时间对氧化层表面形貌、组织结构及表面绝缘性的影响。采用金相显微镜对镀铝层和氧化层表面形貌进行观察,扫描电镜和X射线衍射仪分析镀铝层和氧化层的成分与结构,并对其硬度进行测试,探索钨铜箔片上制备氧化铝的最佳工艺。实验现象表明:经过阳极氧化处理后,氧化层表面致密平滑,由非晶Al2O3和Al相组成,电绝缘性能良好;氧化铝膜的硬度随着氧化时间呈现先增加后降低,最后趋于稳定的趋势;而氧化铝膜的硬度随着氧化电压增大而增大。当氧化电压控制在30 V,氧化时间在3-6 h时,最有利于氧化膜的形成,且膜厚呈增大趋势。