红石泉铀矿床早志留世二长正长岩成因及与铀成矿关系

为了研究红石泉铀矿床二长正长岩形成年龄与成因,探讨其与热液铀成矿之间的关系,选择红石泉矿区内二长正长岩作为研究对象,开展锆石U-Pb同位素年代学和元素地球化学特征研究.结果表明:红石泉二长正长岩形成于(421±2.3)Ma,属于碱性系列;稀土元素总量变化较大,轻稀土元素相对富集,重稀土元素相对亏损,富集Th、U、Nd和...     

吕梁地区宁家湾岩体锆石 U-Pb 年代学、地球化学特征及地质意义

对呈小规模岩株状产出的宁家湾岩体进行野外地质、岩石学、岩石地球化学、锆石U-Pb同位素年代学和Hf同位素组成研究, 目的是确定其岩石成因及地球动力学意义。两件样品的LA-ICP-MS锆石U-Pb定年结果分别为2364±6 Ma (MSWD=0.13)和2360±23 Ma (MSWD =4.0), 属古元古代岩浆活动的产物。研究结果表明, 宁家湾岩体富碱、高K和Si, 具有高FeO^T/MgO 比值和高的高场强元素(HFSE)含量, 富集Rb, Ba, Th和U等元素, 具有低的Ca和Mg含量, 明显亏损P和Ti, 具弱轻重稀土分异和强Eu负异常(δEu=0.13~0.36)的海鸥型稀土分配模式, 显示高分异I型花岗岩的特征。较高的Y/Nb值(1.2~2.8)、锆石的ε_Hf(t)均为正值(+1.6~+6.4)以及单阶段模式年龄t_DM1(Hf)和二阶段模式年龄t_DM2(Hf)分别为2449~2629 Ma和2474~2711 Ma的特点, 表明源区可能为壳幔混合。明显的Nb, P 和 Ti负异常及Ce, Nd和Zr正异常, 反映出大陆边缘弧岩浆岩的特征。结合区域地质背景, 认为宁家湾岩体很可能形成于岛弧构造环境。     

辽南梁屯-矿洞沟古元古代岩体LA-ICP-MS锆石U-Pb年龄及岩石地球化学特征

辽南梁屯-矿洞沟古元古代岩体包括坎子岩体、卧龙泉岩体、学校后街岩体与梁屯岩体,岩性分别为中细粒二长花岗岩、中细粒似斑状黑云母二长花岗岩、细粒黑云母二长花岗岩、细粒正长岩。学校后街岩体与梁屯岩体LA-ICP-MS锆石U-Pb年龄加权平均值为1 887.2±5.4 Ma、1 883.9±2.6 Ma,为古元古代。从坎子岩体到梁屯岩体岩石化学体现了一个偏铝-过铝型,钙碱性-碱性的演化序列,K及Mg O含量逐渐增高,富集大离子亲石元素K、Rb、Ba、Sr,亏损高场强元素Nb、Ta、Zr、Hf,稀土元素配分模式右倾,属具有负铕异常的轻稀土富集、重稀土亏损型。结合相关构造环境分析,古元古代岩体在辽河岩群沉积完成后存在着一个活动大陆边缘-碰撞造山-造山晚期,岩石类型由I型-S型-A型的演化过程。     

东昆仑金水口南变余辉长岩地球化学及锆石定年

目的 限定东昆仑造山带在新元古代Rodinia超大陆裂解的时限.方法 依据主、微量元素地球化学判别变余辉长岩的构造属性,并通过LA-ICP-MS对其中的锆石进行U-Pb测年.结果 变余辉长岩富集大离子亲石元素,轻稀土元素(LREE)及高场强元素(Nb,Ta)弱亏损,形成于较典型的大陆裂谷环境;U-Pb锆石测年结果显示,变余辉长岩形成年龄为(796±41)Ma(MSWD=0.47).结论 东昆仑造山带在新元古代裂解的时间为(796±41)Ma(MSWD=0.47).     

阿尔泰地区霍热木德克花岗岩体年代学、地球化学特征及构造意义

中阿尔泰构造带出露大面积晚三叠世花岗岩,对其进行详细研究是了解阿尔泰造山带构造演化和陆壳增生过程的重要途径。本文对霍热木德克岩体进行详细的岩石学、锆石U-Pb年代学、岩石地球化学及Sr-Nd同位素研究。霍热木德克花岗岩体主要有粗粒二长花岗岩、细粒二长花岗岩和正长花岗岩。LA-ICP-MS锆石U-Pb年代学研究结果表明,其结晶年龄为(222.3±1.8)Ma(MSWD=1.6),为晚三叠世岩浆活动产物。地球化学研究表明,岩石具有高SiO_2、Al_2O_3、ALK,低TiO_2、MnO、MgO、P_2O_5的特征,轻稀土富集、轻重稀土分馏明显,具有Eu的负异常(δEu=0.37~0.50),富集大离子亲石元素、相对亏损高场强元素,显示出强过铝质S型花岗岩的特征,花岗岩具有负的εNd(t)(-3.7~-2.7)和较老的二阶段模式(T2DM)年龄(1.2~1.3Ga)。综合分析认为,霍热木德克花岗岩由富含白云母和黑云母的变泥质岩经历部分熔融形成,其源区有富钙斜长石、钛铁矿的残留,为同碰撞造山阶段挤压环境下地壳加厚而发生部分熔融的产物,形成于同碰撞构造环境。     

青海省昆仑河晚三叠世花岗岩岩石地球化学特征及其构造背景

为了研究青海省昆仑河地区的大地构造环境及岩石年代学意义,对昆仑河两侧的晚三叠世花岗岩的主量元素、微量元素及LA-ICP-MS锆石U-Pb同位素定年进行研究和探讨。结果表明:该岩石为高钾钙碱性过铝质岩石,主量元素具有高K_2O(5.36%~5.92%),低P_2O_5(0.07%~0.08%),FeO(0.27%~1.6%),TiO_2(0.18%~0.24%)的特征,大离子亲石元素Rb,Th相对富集,而高场强元素Nb,Hf,Zr则明显亏损,稀土元素含量高,ΣREE为(433.67~590.00)×10~(-6),稀土元素配分模式呈轻稀土强烈富集的右倾斜型,(La/Yb)N值为9.74~16.86,岩石具明显的负铕异常(δEu=0.15~0.19),说明岩浆物质来源于地壳上部,可能有少量地幔物质混入。锆石LA-ICP-MSU-Pb同位素定年结果表明,该地区花岗岩的成岩年龄为(200.9±1.1)Ma(MSWD=3.2),为晚印支期岩浆活动产物。结合地球化学图解、区域地质背景及年代学证据,认为该花岗岩应为后碰撞构造环境的产物。     

江西余干支家桥地区镁铁质岩体的LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义

对江西余干支家桥地区镁铁质岩体进行了年代学、岩石学和地球化学研究,主量元素特征和微量元素分析结果显示,铁镁质岩具富钙、富铝、富铁、富镁、贫碱特征,岩体为钙碱性系列的镁铁质堆积岩,岩浆基性程度较高;A/NCK均大于1,属于铝质基性-超基性岩类。镁铁质岩体LA-ICP-MS锆石U-Pb定年法测年结果为(47.40±0.5)Ma,时代属于古近纪始新世,表明该镁铁质岩体是喜马拉雅期陆内伸展作用的产物。     

长江中下游大龙山和黄梅尖A型花岗岩锆石U-Pb年代学和Hf同位素

长江中下游地区沿江两岸分布两条A型花岗岩带,岩性主要为石英正长岩和碱性花岗岩。为研究该地区A型花岗岩的形成时代和构造背景,分别选取具有代表性的北带大龙山和黄梅尖岩体的四组石英正长岩,进行LA-ICP-MS锆石U-Pb定年和Hf同位素研究,获得的锆石U-Pb年龄分别为(125.8±1.6)Ma和(126.4±3.5)Ma(大龙山)、(127.6±2.1)Ma和(127.2±2.1)Ma(黄梅尖),其对应的锆石εHf(t)值分别为-4～+1.1和-7.8～-3.6、-3.3～+2.1和-3.8～-0.1,二阶段模式年龄TDM2变化为1 107～1 433 Ma(平均值为1 264 Ma)和1 432～1 671 Ma(平均值为1 555 Ma)、1 045～1 389 Ma(平均值为1 265 Ma)和1 188～1 423 Ma(平均值为1 312 Ma)。结果表明两个岩体与长江中下游地区两条A型花岗岩带其他岩体的形成时代近乎一致,均形成于早白垩世。岩浆源区可能为一个富集地幔,伴随不同程度的地壳混染作用。结合前人的研究成果,大龙山和黄梅尖岩体可能形成于太平洋板块后撤而引发的强烈伸展的构造背景之下。     

黔东南新元古代花岗质岩石的特征及其地质意义

目的研究黔东南新元古代花岗质岩石地球化学、同位素年代学特征及其地质意义。方法对该花岗质岩石样品进行地球化学分析和锆石的LA-ICP-MS U-Pb定年。结果黔东南从江县秀塘花岗质岩石的SiO_2含量为54.21%～75.46%,Na_2O+K_2O为3.12%～6.89%,铝饱和指数均大于1,具有过铝质特征。稀土总量中等(∑REE=106.68×10~(-6)～216.46×10~(-6)),轻稀土强烈富集且轻稀土较重稀土分异明显,具有中等负铕异常(δEu=0.56～0.79)。Cs,K,Th等大离子亲石元素明显富集,Nb,Ta,P亏损,Zr富集。该花岗质岩石样品进行的锆石LA-ICP-MS U-Pb定年获得其年龄值为836 Ma±5.1 Ma。结论黔东南秀塘地区新元古代早中期的花岗质岩浆活动是同时代黔东南—桂北地区超基性至中酸性岩浆活动的一部分,这期岩浆活动是新元古代早中期江南造山带碰撞后伸展作用的产物。     

藏北羌塘南缘早白垩世青草山强过铝质S型花岗岩的成因: 来自地球化学和锆石U-Pb年代学的约束

藏北羌塘南缘扎普?多不杂岩浆弧内的青草山花岗岩体由花岗斑岩和石英二长斑岩组成, 目前缺乏地球化学和年代学数据来约束其成因和形成时代。用 LA-ICP-MS 方法测得石英二长斑岩锆石 206Pb/238U 年龄加权平均值为122±1 Ma (MSWD=3.9), 花岗斑岩的锆石SHRIMP U-Pb 年龄为114.6±1.2 Ma (MSWD=1.1), 表明岩体形成于早白垩世。岩体含白云母、堇青石, 无角闪石, 具有富铝(A1₂O₃ 含量: 14.81%~15.86%)、贫钙(CaO 含量: 1.10%~2.44%)、总碱含量高(K₂O+Na₂O 含量: 6.86%~8.80%)的特征, 铝饱和指数 A/CNK 为1.06~1.20, 在 CIPW 标准矿物计算中出现刚玉分子(1.20%~2.86%), 未出现透辉石, 表明该岩体为一套强过铝质亚碱性 S 型花岗岩。(La/Yb)N=3.24~16.20, LREE/HREE=4.37~12.4, 在配分曲线上显示左高右低的特征, 富集Rb, Th, U, K, La, Ce 等大离子亲石元素, 亏损Ta, Nb, P, Ti, Y 等高场强元素, 具有较典型的岛弧岩浆岩地球化学特征。研究结果揭示, 青草山花岗岩为班公湖?怒江洋壳北向俯冲背景下, 上地壳杂砂岩质成分发生部分熔融作用的产物。     

The zircon SHRIMP chronology and trace element geochemistry of the Carboniferous volcanic rocks in western Tianshan Mountains

The genesis of the Carboniferous volcanic rocks in the Dahalajunshan group, mainly consisting of trachytes and trachy-andesites and distributing widely in western Tianshan Mountains, remains to be controversial. It has been proposed to be relevant to “rift” or “plume”. Detailed petrology and geochemical data presented in this paper show that these volcanic rocks represent typical continental arc magmatism. The volcanic rocks are mainly trachy-andesitic, and the magma source is enriched in LILE, Th and Pb, and depleted in HFSE and Ce. Trace element geochemical study suggests that the basalts could be modeled by 7% -11% partial melt of garnet Iherzolite. The volcanic rocks in the Dahalajunshan group are neither the products of “rift” nor so-called “plume”but represent the continental island arc of the Paleo-Southern Tianshan Ocean. The mantle wedge had been modified by the melt generating in subduction zone during a long evolution history of this island arc. The continental crust materials （i.e. mainly sediment on ocean floor） had been added into island arc through melt in subduction zone. Volcanic rocks occurring in different regions might represent magma eruption in different time. The zircon SHRIMP dating indicates that the ages of the basalt varies between 334.0 Ma and 394.9 Ma. The 13 analyses give an average age of 353.7±4.5 Ma （MSWD = 1.7）. The apparent ages of zircons in trachy-andesite vary between 293.0 Ma and 465.4 Ma. All analyses fall on the U-Pb concordant line and are divided into two groups. 8 analyses produce an average age of 312.8±4.2 Ma （MSWD = 1.7）, which represents the crystallizing age of zircon rims in trachy-andesite. The acquired two ages （i.e. 354 and 313 Ma） belong to the Early Carboniferous and Late Carboniferous epochs, respectively. Thus, the Dahalajunshan group would be separated into several groups with the accumulation of high-quality age dating and data of trace element and isotopic geochemistry, in our opinion.     

内蒙古四子王旗地区中二叠世火山岩年代学、地球化学特征及构造意义

对华北克拉通与兴蒙造山带结合部位的内蒙古四子王旗地区出露的一套原定为中?下侏罗统的流纹岩进行岩石学、岩石地球化学、锆石U-Pb同位素年代学和Hf同位素组成研究, 确定其岩石成因及地球动力学意义。新获得的流纹岩和流纹斑岩LA-ICP-MS锆石U-Pb 年龄分别为262±2和261±2 Ma, 表明流纹岩的时代应为中二叠世晚期。四子王旗地区流纹岩多属高钾钙碱性系列和钾玄岩系列岩石, 具有高硅、高碱、富铝以及贫钙、贫镁的特征。稀土元素总量较大, 配分曲线明显右倾, 具有中度到重度Eu负异常, 富集大离子亲石元素Rb, Th和轻稀土元素, 亏损Nb, Ta, Sr和Ba等元素。火山岩的ε_Hf(t)为负值(-25.97~-11.94), 可能主要来源于古老地壳熔融岩浆。该套火山岩具有高硅流纹岩的地球化学特征, 表明岩浆经历过结晶分异过程, 岩浆喷出与深部幔源岩浆的加热有关。结合相关构造判别图解, 判断该套火山岩可能形成于后碰撞伸展阶段。     

Geochronology and geochemistry of the Fangcheng Neoproterozoic alkali-syenites in East Qinling orogen and its geodynamic implications

Finding of Neoproterozoic syenites at Fangcheng in the northern Qinling region of the East Qinling orogen provides an important constraint on timing of tectonic transformation to extensional regime. The alkaline pluton consists mainly of nepheline syenite, aegirine syenite, and alkali-feldspar syenite. The syenites are of intermediate （SiO2 = 54%-62%）, rich in alkali （K2O＋Na2O = 12%-15%）, aluminum （Al2O3= 16.81%-23.26%） and large ion lithophile elements （LILE）, without any obvious Nb, Ta, Zr, and Hf anomalies. The Fangcheng syenites are geochemically characterized by relative enrichment of LREE, minor differentiation of HREE, significant negative Eu anomalies （Eu = 0.13-0.23）, less negative εNd（t） values of -1.37 to-3.90, young Nd model ages of 1364 to 1569 Ma, and high zircon saturation temperatures of 915 to 1044℃. The syenitic magmas probably originated from small proportion melting of upper mantle in an extensional regime of intraplate-anorogenic tectonic setting, and have been slightly contaminated by crustal materials during ascending and/or emplacement. LA-ICP-MS zircon U-Pb dating yields ages of 844.3±1.6 Ma （MSWD=0.86）, suggesting that the Fangcheng alkaline syenites formed in the early Neoproterozoic. They are the oldest Neoproterozoic alkaline rocks ever recognized in the Qinling orogen as well as in South China. This implies that the tectonic regime of the Qinling region would have transformed from post-collisional stretch to intraplate-anorogenic extension no later than 844 Ma.     

Zircon U-Pb ages of granites at Changba and Huangzhuguan in western Qinling and implications for source nature

Mesozoic granitoids are widespread in the Qinling-Dabie-Sulu orogenic belt. Precise U-Pb dating on these granitoids can reveal the evolution of the continental collision orogen and thus provide information on the nature of magma sources. This study presents zircon LA-ICP-MS U-Pb dating and whole-rock geochemical analyses for two intrusions at Changba and Huangzhuguan in western Qinling. Zircon U-Pb ages for central and marginal phases of the Huangzhuguang intrusion are 214±1 Ma and 213±3 Ma, respectively. Zircons from the Changba intrusion yield a dominant cluster with an U-Pb age of 213±2 Ma. Collectively, these ages are younger than ages of 220 to 240 Ma for ultrahigh-pressure metamorphism due to the continental collision between the South China Block and the North China Block, corresponding to syn-exhumation magmatism. Some inherited zircons occur in the Changba intrusion, yielding a weighted mean of ²⁰⁶Pb/²³⁸U ages at 757±14 Ma. This indicates that the Changba intrusion has the crustal source of mid-Neoproterozoic ages and a tectonic affinity to the South China Block. Geochemically, the two intrusuons are both rich in LILE and LREE but depleted in HFSE and HREE, similar to arc-type igneous rocks. The Huangzhuguang intrusion exhibits linear correlations between SiO₂ and the other major oxides, implying chemical evolution from a cognate magma source. It contains mafic enclaves, suggesting possible mixing of felsic-mafic magmas. The Changba granite is rich in Si and K but poor in Fe and Mg as well as has a high value of Fe*, suggesting strong differentiation of granitic magma. Therefore, the two intrusions were derived from the Late Triassic anatexis of the continental crust of different compositions in the northern margin of South China Block. This process may be coupled with exhumation of the subducted continental crust in the stage of late collision.     

Determination of U-Pb age and rare earth element concentrations of zircons from Cenozoic intrusions in northeastern China by laser ablation ICP-MS

Using the in situ zircon U-Pb dating method of LA-ICPMS, we analyzed the 31 Ma old SHRIMP U-Pb age of the Yongsheng nepheline syenite from southern Jilin Province under different spot sizes. The obtained ages are comparable with that of SHRIMP in both accuracy and precision. The age is also identical to that of the Yinmawanshan gabbro from the Liaodong Peninsula within error. Both the Yongsheng nepheline syenite and the Yinmawanshan gabbro represent the youngest known exposed intrusions in northeastern and even eastern China. The results indicate the Eocene mantle-derived magmatic underplating, and the rapid crustal uplifting of this region since 30 Ma. The analyses also document extremely high LREE concentrations and relatively fiat REE patterns for the zircons from the Yongsheng nepheline syenite, which represent a new type of zircon REE pattern.     

甘肃北山桥湾北花岗岩体的年代学、地球化学及其地质意义

为加深对北山晚古生代构造演化的认识, 选取位于甘肃北山南带、敦煌地块北缘的桥湾北花岗岩体进行年代学、地球化学研究。桥湾北角闪石花岗岩体锆石LA-ICP MS年龄为303.7±2.4 Ma, ε_Hf(t)为-1.2~5.8, ε_Nd(t)相对较高(-0.40~-0.06), (⁸⁷Sr/⁸⁶Sr)_i =(0.704524~0.705062)。 桥湾北花岗岩体K₂O含量为4.09%~5.58%, 属高钾钙碱性岩石, A/CNK值在0.92~1.04之间, 为I型花岗岩; 微量元素较富集LILE, 相对亏损HFSE, 有明显的Nb, Ta负异常。岩体具相对富集的微弱分馏的轻稀土元素, 重稀土元素分馏不明显, 基本没有Eu异常。由Hf, Nd同位素及地球化学特征判断, 桥湾北花岗岩体为壳幔混合成因, 其形式可以是底侵的幔源岩浆再分异, 上升过程中遭受地壳物质混染。根据区域构造背景及岩石学、地球化学特征, 可以认为桥湾北岩体是北山南带后碰撞过程岩浆活动的产物, 反映出在晚石炭世北山地区的碰撞拼贴已经完成。     

Indosinian isotope ages of plutons and deposits in southwestern Miaoershan-Yuechengling,northeastern Guangxi and implications on Indosinian mineralization in South China

The Miaoershan-Yuechengling complex pluton is the largest granitoid complex in the western Nanling metallogenic belt with a surface exposure of >3000 km2.The complex pluton is composed of an early stage granitoid batholith and late stage small intrusions.The early stage batholith contains mainly medium-grained porphyritic mica granite and porphyritic monzonite granite,whereas the late stage intrusions are composed of muscovite granite porphyry and muscovite monzonitic granite.There are many W-Sn-Mo-Pb-Zn-Cu ores in the contact zone between the batholith and strata,forming an ore-rich belt around the batholith.Based on zircon LA-ICP-MS U-Pb ages,the southwestern part of the early stage batholith formed at 228.7 ± 4.1 Ma(MSWD = 2.49),with slightly earlier magmatic activity at 243.0 ± 5.8 Ma(MSWD = 2.62).The Yuntoujie muscovite granite was associated with W-Mo mineralization and has a zircon LA-ICP-MS U-Pb age of 216.8 ± 4.9 Ma(MSWD = 1.44).The Re-Os isochron age of molybdenite from the Yuntoujie W-Mo ore was 216.8 ± 7.5 Ma(MSWD = 11.3).Our new isotope data suggest that the late stage intrusive stocks from the southwestern Miaoershan-Yuechengling batholith were closely associated with W-Mo mineralization from the Indosinian period.These new results together with previous isotope data,suggest that South China underwent not only the well-known Yanshanian mineralization event,but also a widespread Indosinian metallogenic event during the Mesozoic period.Therefore,South China has a greater potential for Indosinian mineralization than previously thought such that more attention should be given to the Indosinian ore prospecting in South China.     

辽北新宾?苇子峪地区太古宙花岗质岩石的形成年代、成因及其地质意义

辽北新宾?苇子峪地区的花岗质岩石主要由英云闪长质?奥长花岗质片麻岩和二长花岗岩?正长花岗岩岩体等组成。为确定其形成年代及成因, 对这些花岗质岩石进行锆石U-Pb-Hf同位素和全岩地球化学分析。锆石LA-ICP-MS U-Pb同位素定年结果表明这些花岗质岩石均形成于新太古代, 英云闪长质和奥长花岗质片麻岩的岩浆结晶年龄分别为2588±4 Ma (MSWD=1.3)和2587±6 Ma (MSWD=1.8), 二长花岗岩?正长花岗岩则侵位于2555±4 Ma (MSWD=0.51)。全岩地球化学和锆石Lu-Hf同位素研究表明, 英云闪长质?奥长花岗质片麻岩形成于俯冲板片的部分熔融, 其原始岩浆在上升过程中受到地幔楔岩石的交代; 而二长花岗岩?正长花岗岩中一部分岩浆起源于变质杂砂岩的部分熔融, 其余形成于以变质玄武岩与变质沉积岩为主要成分的混合源区的部分熔融。结合近年的研究成果, 认为新宾?苇子峪地区的新太古代花岗质岩石可能形成于活动大陆边缘的动力学背景。     

SHRIMP zircon U-Pb ages of Kalatongke No. 1 and Huangshandong Cu-Ni-bearing mafic-ultramafic complexes,North Xinjiang,and geological implications

In Xinjiang, northwestern China, there are some veryimportant magmatic Cu-Ni sulfide deposits hosted by ma-fic-ultramafic complexes. In addition to the Jingbulake inwestern Tianshan and the Xingdi in northeastern Tarimblock, the others are concentrated in the Kalatongke andHuangshan-Jingerquan mafic-ultramafic complex beltsand two largest Cu-Ni sulfide deposits occur in the Kala-tongke No.1 and Huangshandong complexes. In the pastdecade, a great number of researches have been conductedfo…