完全二部图K11,n(11≤n≤88)的点可区别E-全染色

设图G是简单图,如果给图G中相邻的2个顶点染有不同的颜色,并且让这2个顶点的每条关联边和关联边的端点染不相同颜色的一个全染色称为图G的一个全染色f.如果满足条件对?u,v∈V(G),u≠v,存在C(u)≠C(v),那么f叫做图G的一个E-全染色,简称为VDET染色.文章利用反证法和分析法,讨论完全二部图K11,n(11...     

Novelty phase synthesis mechanism and morphology in resin-bonded Al-Al2O3-TiO2 composites at high temperatures under flowing N2

An Al-AlN core-shell structure is beneficial to the performance of Al-Al₂O₃ composites. In this paper, the phase evolution and microstructure of Al-Al₂O₃-TiO₂ composites at high temperatures in flowing N₂ were investigated after the Al-AlN core-shell structure was created at 853 K for 8 h. The results show that TiO₂ can convert Al into Al₃Ti (~1685 K), which reduces the content of metal Al and rearranges the structure of the composite. Under N₂ conditions, Al₃Ti is further transformed into a novelty non-oxide phase, TiCN. The transformation process can be expressed as follows:Al₃Ti reacts with C and other carbides (Al₄C₃ and Al₄O₄C) to form TiC_x (x < 1). As the firing temperature increases, Al₃Ti transforms into a liquid phase and produces Ti(g) and TiO(g). Finally, Ti(g) and TiO(g) are nitrided and solid-dissolved into the TiC_x crystals to form a TiCN solid solution.     

Martensitic transformation and magnetic properties of aged Ni-Fe-Ga-Ti shape memory alloy

This article reports the effect of ageing on the microstructure, martensitic transformation, magnetic properties, and mechanical properties of Ni₅₁Fe₁₈Ga₂₇Ti₄ shape memory alloy. There are five specimens of this alloy aged at 573 up to 973 K for 3 h per each. This range of ageing temperature greatly affects the microstructure of the alloy. As the ageing temperature increased from 573 up to 973 K, the microstructure of Ni₅₁Fe₁₈Ga₂₇Ti₄ alloy gradually changed from the entirely martensitic matrix at 573 K to the fully austenitic microstructure at 973 K. The volume fraction of precipitated Ni₃Ti particles increased with the ageing temperature increasing from 573 to 773 K. Further increasing the ageing temperature to 973 K decreased the content of Ni₃Ti in the microstructure. The martensitic transformation temperature was decreased steadily by increasing the ageing temperature. The magnetization saturation, remnant magnetization, and coercivity increased with the ageing temperature increasing up to 773 K. A further increase in ageing temperature decreased these magnetic properties. Moreover, the hardness values were gradually increased at first by increasing the ageing temperature to 773 K, and then dramatically decreased to the lowest value at 973 K.     

Microstructure and mechanical properties of Al3Ti-based alloys in Al-Ti-Mo-X quaternary systems

A part of Al-Ti-Mo-Cr quaternary phase diagram is constructed for the microstructure control of DO₂₂-Al₃Ti or its derivative, Ll₂-(Al,Cr)₃Ti, -based alloys. It was found that quaternary bce phase equilibrates with either DO₂₂-Al₃Ti or Ll₂-(Al,Cr)₃Ti, or both, exist in large compositional areas. The mechanical properties is strongly affected by precipitates appearing, and presumablyalloy microstructures.     

钐对SmxMn0.3?xTi催化剂NH3选择性催化还原NOx过程中N2选择性的影响

本文研究了Sm对Mn基催化剂NH₃选择性催化还原NO的改善作用。采用共沉淀法制备了一系列Sm_xMn_0.3?xTi催化剂(x = 0, 0.1, 0.15, 0.2和0.3)。活性测试表明,Sm_0.15Mn_0.15Ti催化剂在180?300°C条件下,NO转化率达100%,N₂选择性达87%以上。表征结果表明,Mn基催化剂中添加Sm,抑制了TiO₂和Mn₂O₃相的结晶,提高了比表面积和酸性,其中Sm改性催化剂的比表面积从152.2增加至241.7 m2·g?1。这些作用有利于提高催化活性。X射线光电子能谱(XPS)结果表明,Sm_0.15Mn_0.15Ti的Sm3+/Sm和O_β/O的相对原子比分别为76.77at%和44.11at%,添加Sm增加了表面吸附氧(O_β),降低了Mn4+的表面浓度;程序升温还原H₂(H₂-TPR)结果表明,Sm_0.15Mn_0.15Ti催化剂还原温度提高,H₂消耗量降低至0.3 mmol?g?1。Sm的引入降低了催化剂Mn4+表面浓度,使得该催化剂氧化还原性能降低,进一步抑制NH₃氧化和非选择性催化还原反应生成N₂O,从而提高了催化剂的N₂选择性。原位漫反射红外傅立叶变换光谱(DRIFTs)表明,Sm_0.15Mn_0.15Ti催化剂的NH₃-SCR反应主要遵循Eley?Rideal机制。Sm掺杂增加了Sm_0.15Mn_0.15Ti催化剂的表面吸附氧(O_β),降低了氧化还原性能,提高了Sm_0.15Mn_0.15Ti催化剂的NO转化率和N₂选择性。     

一类非线性三阶差分方程正周期解的存在性和多解性

考虑一类非线性三阶差分方程Δ³u(t-3)+αΔ²u(t-2)+βΔu(t-1)=f(t,u(t)), t∈［3,T］_Z正周期解的存在性和多解性, 其中 T>4, α>0, -1<β<0, f:［3,T］_Z×［0,∞)→R关于 u∈［0,∞)连续, f(t+ω,u)=f(t,u), ω∈Z⁺。主要结果的证明基于Guo-Krasnoselskii 不动点定理。     

(Nd1-xErx)3Fe27.31Ti1.69化合物的磁晶各向异性

用振动样品磁强计并结合X射线衍射准确判定了Nd_2.4Er_0.6Fe_27.31Ti_1.69化合物的磁晶各向异性方式, 研究结果发现, Nd_2.4Er_0.6Fe_27.31Ti_1.69化合物的磁晶各向异性从室温时的易面转变到低温时的易锥.     

n阶多时滞微分方程的周期解

用上下解的单调迭代方法, 通过建立新的极大值原理, 构造n阶时滞微分方程-u⁽ⁿ⁾(t)=f(t,u(t),u(t-τ₁),u(t-τ₂),…,u(t-τ_n)),t∈R, ω-周期解的单调迭代求解程序, 并证明其ω 周期解的存在性和唯一性, 其中f: R×Rⁿ⁺¹→R连续且关于t以ω为周期, τ₁,τ₂,…,τ_n是正常数.     

带有导数项的二阶周期问题正解

获得了非线性函数带有导数项的二阶周期边值问题{u″(t)+au(t)=f(t,u(t),u'(t)),〓t∈［0,1］,u(0)=u(1), u'(0)=u'(1)正解的存在性, 其中(π²)/4π², f:［0,1］×R⁺×R→R⁺连续。 f(t,x,y)满足Nagumo条件, 且关于 x 和 y 满足一定的超线性增长条件。针对超线性情形, Nagumo条件关于y严格控制了f的增长。主要结果的证明基于不动点指数理论。     

带有凸-凹非线性项的平均曲率问题正解的个数

考虑一维Minkowski空间中给定平均曲率问题{-((u')/((1-u'²)^1/2))'=λf(u), x∈(-L,L),u(-L)=0=u(L)正解的确切个数及其分歧曲线,其中参数λ>0,L>0, f∈C¹［0,∞)∩C²(0,∞), f(0)=0, f(u)>0,u∈(0,L)且f在(0,L)上为凸-凹函数。通过详细的时间映像分析,在两种不同的情况下,根据λ的不同范围,获得了该问题没有正解,恰有一个或两个正解的结果。     

制备方法对Ti0.8Zr0.2O2/沸石结构及光催化性能的影响

以酸处理后的信阳上天梯天然斜发沸石作为载体,分别采用浸渍法和溶胶凝胶法制备Ti0.8Zr0.2O2/沸石光催化剂.采用X-射线衍射、红外光谱和扫描电镜分析样品的微观结构和形貌.结果表明,80℃下,4 mol/L盐酸处理10 h后沸石结构发生了显著变化,Al—O—Si骨架结构保持.扫描电镜证明钛锆氧化物在溶胶凝胶法制备的光催化剂上高度分散,以罗丹明B(RhB)为模型污染物考察了该样品的吸附与光催化效果.300 W紫外灯光照1.5 h后,0.2 g该催化剂可使20 mL浓度为80 mg/L RhB溶液的去除率达97.12%,重复使用8次后去除率为89.47%.     

Synergic catalytic effect of Ti hydride and Nb nanoparticles for improving hydrogenation and dehydrogenation kinetics of Mg-based nanocomposite

The Mg-9.3 wt% (TiH1.971-TiH)?0.7 wt% Nb nanocomposite has been synthesized by hydrogen plasma-metal reaction (HPMR) approach to enhance the hydrogen sorption kinetics of Mg at moderate temperatures by providing nanosizing effect of increasing H “diffusion channels” and adding transition metallic catalysts. The Mg nanoparticles (NPs) were in hexagonal shape range from 50 to 350 nm and the average size of the NPs was 177 nm. The small spherical TiH1.971, TiH and Nb NPs of about 25 nm uniformly decorated on the surface of the big Mg NPs. The Mg-TiH1.971-TiH-Nb nanocomposite could quickly absorb 5.6 wt% H2 within 5 min at 573 K and 4.5 wt% H2 within 5 min at 523 K, whereas the pure Mg prepared by HPMR could only absorb 4 and 1.5 wt% H2 at the same temperatures. TiH1.971, TiH and Nb NPs transformed into TiH2 and NbH during hydrogenation and recovered after dehydrogenation process. The apparent activation energies of the nanocomposite for hydrogenation and dehydrogenation were 45.0 and 50.7 kJ mol?1, which are much smaller than those of pure Mg NPs, 123.8 and 127.7 kJ mol?1. The improved sorption kinetics of the Mg-based nanocomposite at moderate temperatures and the small activation energy can be interpreted by the nanostructure of Mg and the synergic catalytic effects of Ti hydrides and Nb NPs.     

Ti3SiC2的生长机制

为探讨Ti3SiC2的生长机制,以Ti、Si、C元素粉末为原料,采用三种不同的真空烧结工艺,制备体积分数为89.12%、85.90%及93.01%的Ti3SiC2材料,并利用XRD和SEM对其进行组织结构分析。结果表明:Ti3SiC2晶体生长为台阶机制,在母层片的法线方向不受约束的情况下形成梯田形貌;在生长母层面的法线方向受到约束的情况下,Ti3SiC2的生长台阶被逐渐填满,形成晶型较完整的Ti3SiC2;在以Ti、Si、C粉末为原料制备Ti3SiC2时,在略高于1 300℃的温度进行长时间保温是有利的。     

硅或钛取代AlPO-11分子筛的合成及表征

介绍了硅，钛取代A1PO-11分子筛SAPO-11、TAPO-11的合成方法，采用X射线衍射（XRD）、扫描电子显微镜（SEM）、热重-差热、氮气吸脱附等手段对合成的分子筛进行了表征，考察了晶化温度和原料比对分子筛合成的影响。结果表明，硅，钛取代A1PO-11分子筛能生成AEL结构的TAPO-11分子筛；SAPO-11与A1PO-11分子筛表观形貌相差不大，而TAPO-11分子筛表观形貌则与A1PO-11分子筛有很大不同；硅，钛取代后分子筛的孔道半径及其孔容有所改变；3种分子筛都具有较好的热稳定性。     

Ti3SiC2/TiC复合材料的制备及力学性能研究

弓网系统中,各种类型的受电弓滑板承担着传输电能的重要功能,其严酷的工作条件对受电弓滑板材料的性能提出了非常苛刻的要求。目前最主要的受电弓滑板有：粉末冶金滑板,纯碳滑板和浸金属碳滑板。其中碳滑板材料性能较好但价格昂贵,粉末冶金滑板材料价格便宜,但性能明显逊于前者。Ti3SiC2/TiC是一种兼具陶瓷与金属性质的新型材料,与碳滑板材料相比,其电阻率低,且具有良好的抗氧化性和自润滑减摩性,因此Ti3SiC2/TiC将可能成为一种工艺简单、成本更低、而性能则更高的新型受电弓滑板材料。本研究以Si、Ti和C为原料,利用熔渗反应烧结技术制备出Ti3SiC2/TiC复合材料,研究结果表明,制备样品的弯曲强度与硬度分别达到 423MPa~564MPa 和169~249HB。同时,本文对Ti3SiC2/TiC复合材料的断裂机理进行了研究。     

Na0.54Bi0.46Ti0.96Al0.04O2.94氧离子导体制备与性能研究

采用传统的固相反应法合成Na0.54Bi0.46Ti0.96Al0.04O2.94氧离子导体,借助于交流阻抗谱和介电弛豫谱分别研究了钠和铝的双掺杂对Na0.5Bi0.5TiO3材料电学性能及氧离子扩散的影响。在400℃时,Na0.54Bi0.46Ti0.96Al0.04O2.94材料的晶粒电导率可以达到1.51×10-3 S/cm,是Na0.5Bi0.5TiO3材料电导率的5.5倍。在Na0.54Bi0.46Ti0.96Al0.04O2.94材料中观察到一个与氧离子弛豫相关的介电弛豫峰,弛豫参数为E= 0.80 eV和t0= 6.12×10-13 s,氧离子在Na0.54Bi0.46Ti0.96Al0.04O2.94材料中主要通过Na-Bi-Ti的路径进行扩散迁移的。结合结构参数容忍因子及自由体积的分析,钠和铝的双掺杂改善了氧离子在Na0.5Bi0.5TiO3材料中的扩散通道,但是铝的引入一定程度上提高了氧空位扩散的能量壁垒。     

EPBS方法分析含氘/氚钛膜及与PVT法的比较

本文使用EPBS方法分析了含氚及含氘与氚钛膜样品中氚及氘的含量与深度分布,并将氚的分析结果与PVT方法所给出的结果进行了比较.实验所使用的Ti膜衬底是Mo,在EPBS能谱的低能端, Mo元素的模拟谱与实验谱偏差较大,会导致分析结果不准确.为消除EPBS实验谱中的Mo谱对分析的影响,本文使用了一个Mo衬底的TiH_(1.81)样品成功扣除了EPBS实验谱中的Mo本底,扣除Mo本底后可以直接模拟样品中氘与氚的能谱,使得分析结果更为精确可靠.     

CaCu3Ti4O12和La2/3Cu3Ti4O12陶瓷的电导特性

采用固相反应法制备CaCu₃Ti₄O₁₂和La_2/3Cu₃Ti₄O₁₂陶瓷材料并研究了其电导特性.结果表明,CaCu₃Ti₄O₁₂和La_2/3Cu₃Ti₄O₁₂的电导率随温度的变化规律相似.在低温（<150 K ) 区域,CaCu₃Ti₄O₁₂的电导率随温度升高而增大,即呈负阻温特性;在150~170 K温度区域,电导率出现极大值,且其电导率极大值为La_2/3Cu₃Ti₄O₁₂的近4倍;在较高的温度（170~250 K ）区域,电导率随温度的升高而减小.这是由于Ca2＋被La3＋替代后在该位置留下1/3空位而使La_2/3Cu₃Ti₄O₁₂的激活能高达1.01 eV 的缘故.     

泡沫铝夹心板轧制预制坯的粉末冶金发泡工艺

对采用轧制复合法制备的发泡预制坯的粉末冶金发泡过程进行了研究,确定了制得的泡沫铝夹心板的组织及物相,分析了发泡剂TiH2颗粒尺寸及团聚对发泡效果的影响.研究结果表明:轧制坯充分发泡后,泡壁主要有Al3.21Si0.47,Ti及Ti3O相,Ti和Ti3O颗粒同泡壁结合紧密;预制坯内大尺寸发泡剂TiH2颗粒的周围易形成微裂纹,发泡时裂纹的宽度可扩展至100μm以上,裂纹周围的泡孔发育不良;混料及轧制阶段形成的TiH2团聚导致局部发泡驱动力过大,发泡后芯层内易形成大尺寸泡孔.     

Co_3Ti和氢化Co_3Ti的电子结构与总能(英)

采用紧束缚LMTO（TB－LMTO）方法计算了Co3Ti和它的氢化物Co3TiH的电子结构与电子总能．计算得到的晶格常数及体弹性模量与实验符合得很好．Co3Ti吸收H后的能量及体积变化的结果表明Co3Ti的氢化反应很容易发生，这与实验结果也是相符的．