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1.
利用热力学软件计算了齿轮钢氧含量与夹杂物成分控制、夹杂物转变条件.结果表明,20CrMoH钢中具有较高塑性的非金属夹杂物成分(质量分数)为:SiO2 0%~10%、Al2O3 22%~55%、CaO 42%~60%、MgO 5%~10%,与之平衡的钢液中铝的质量分数大于0.020%,钙的质量分数大于0.7×10-6,a[O]为0.0005%左右;选择组成为CaO>40%、Al2O3≤37%、MgO10%、(%CaO+%MgO)/%SiO2为10、SiO2含量尽量低的渣系,钢中Al2 O3、MgO.Al2 O3夹杂物可转变为低熔点的钙铝酸盐.试验发现LF和RH精炼结束时钢液T[O]含量均随炉渣碱度增加而降低,采用高Al2O3含量的炉渣对降低T[O]含量有利;精炼过程钢液中夹杂物按"Al2O3系夹杂物→MgO--Al2O3系夹杂物→CaO--MgO--Al2O3系夹杂物"顺序发生转变,其中MgO--Al2 O3系夹杂物向CaO--MgO--Al2 O3系夹杂物的转变是由外向内逐步进行的,转变速度相对较慢;降低T[O]含量有利于生成较低熔点的CaO--MgO--Al2O3系夹杂物.  相似文献   

2.
基于当代红旗营子群是否应该解体这一观点,研究了崇礼红旗营子群中黑云斜长片麻岩的地质地球化学特征。研究表明原岩为泥质沉积岩,其特点为SiO2〉56%,Al2O3〉MgO,Na2O〉K2O,Na2O/(Na2O+K2O)〉0.5,且其他氧化物与SiO2含量呈现出有规律的变化,随着岩石中SiO:含量的增加,TiO2,AL2O3,FeO,Fe2O3,MgO,CaO,Na2O和K2O呈明显下降趋势。稀土元素总量较低;轻重稀土分离程度较高,LREE/HREE的值为5.16~7.98,La。/Yb。的值为4.28~8.62,轻稀土富集,重稀土平坦分布,稀土配分曲线表现出中等程度的负Eu异常,δEu的值为0.73~0.83。稀土元素Ce基本无异常或略显负异常,表明其形成环境可能为一浅海相或边缘海或被陆地封闭海。  相似文献   

3.
应用ICP-AES法测定水泥中Al2O3、Na2O、K2O、CaO、MgO、SO3、TiO2含量,并对不同的溶样方法及方法的准确度和精密度进行研究.连续7次洲定实际样品含量,计算其相对标准偏差(RSD%),RSD均小于5%;加标回收率在101%~103%之间.证明此方法重现性好,可信度高.  相似文献   

4.
基于409L不锈钢VOD生产实际,分析了Al脱氧条件下MgO.Al2O3复合夹杂物的组成形态;同时采用热力学计算方法得出1873K时MgO,MgO.Al2O3和Al2O3的平衡相图,研究了MgO.Al2O3夹杂物生成与转变的热力学条件.结果表明,钢水中的尖晶石复合夹杂物中的MgO.Al2O3相呈非晶态结构,夹杂物尺寸在5μm左右.生产过程中,当钢水中Al的质量分数控制在0.04%,w(Mg)≥1.3×10-8时,钢水中即可生成MgO.Al2O3夹杂物;w(Mg)≥9.7×10-7时,MgO.Al2O3开始转变成为MgO夹杂.  相似文献   

5.
衢州市上方镇位于钦杭结合带东段,是中国著名的重钙用大理岩产区,区内大理岩矿床均赋存于石炭系黄龙组碳酸盐岩地层.在野外地质调查的基础上,对上方镇大理岩矿床的碳酸盐岩进行了详细的岩相学、矿物学和地球化学研究.研究结果表明,上方大理岩矿床矿石主要为大理岩和大理岩化灰岩,具粒状变晶结构,大理岩方解石结晶较好,颗粒较大且规则,含杂质较少,大理岩化灰岩则含较多杂质,其方解石结晶较差,颗粒不规则且有溶蚀交代现象.地球化学特征显示两类碳酸盐岩化学组成相似,大离子亲石元素(Sr、Ba等)和高场强元素(Nb、Zr、U、Hf、Th等)明显富集,而Ti明显亏损.K2O/Na2O、100×MgO/Al2O3、Ga、Ba、Sr和U/Th等指标暗示碳酸盐岩原岩为沉积型碳酸盐岩,且沉积环境为受陆源碎屑物质影响较少的浅海海相沉积,显示为较强的贫氧-缺氧的还原环境特征.  相似文献   

6.
利用热力学软件FactSage 7.0计算1873K下四元渣系CaO-SiO_2-Al_2O_3-MgO与60Si2Mn弹簧钢平衡时的等氧线,通过渣-钢高温平衡试验,测定了不同精炼渣方案下钢中溶解氧和全氧含量,并对钢中非金属夹杂物的形貌、数量和尺寸分布进行表征。结果表明,1873K温度下,w(MgO)=6%且w(CaO)/w(Al_2O_3)=1时,钢液中溶解[O]及T[O]含量随着渣中w(SiO_2)的增大而增加,而当w(SiO_2)=30%时,随着w(CaO)/w(Al_2O_3)的增加,钢液中溶解[O]及T[O]含量分别呈降低和升高的趋势,这与钢液中SiO_2的活度有关;不同精炼渣方案得到的钢中,尺寸小于10μm的夹杂物所占比例超过87%,尺寸小于4μm的夹杂物所占比例超过50%,且单位面积夹杂物的数量与钢中T[O]含量的变化趋势一致。与试验结果对比可知,利用热力学软件FactSage 7.0计算钢中溶解氧含量是可行的。  相似文献   

7.
海南石碌铁多金属矿床是以铁矿为主,共生或伴生有钴、铜等多金属和白云岩等非金属矿产的超大型矿床。碳酸盐岩作为新元古代石碌群的重要组成部分,是主要的赋矿围岩之一。开展了石碌群第六层上、中、下段的碳酸盐岩主、微量元素地球化学研究。结果表明,主量元素以CaO、MgO为主,除SiO_2含量变化较大外,其它成分基本小于1%。碳酸盐岩∑REE含量为1.34×10~(-6)~29.06×10~(-6)(平均为10.89×10~(-6)),明显低于PAAS,稀土配分型式主要呈左倾或向上凸起,蛛网图中亏损高场强元素,富集大离子亲石元素。根据地球化学性质可将样品分为两组:一组具正Eu异常、无Ce异常,Y/Ho值较低(平均为29.49);另一组Eu无异常,具Ce负异常,Y/Ho值较高,为38.28~63.88(平均为44.65)。该特征表明微量元素继承于海水和海底高温热液两个源区,暗示了海底高温热液可能是铁、钴铜多金属的重要来源。根据Ce异常变化规律所揭示的第六层从下段到中、上段氧化性逐渐增强的特征,认为石碌群第六层沉积环境为受限的弧后海盆,石碌群经历了从浅海相到海湾-泻湖相的沉积演化。  相似文献   

8.
在pH 5.2 Hac-NaAc缓冲溶液和PVA存在的条件下,H2O2 在Fe2+的催化作用下产生的羟自由基·OH,·OH氧化I-并生成的 I-3,而I-3又与带正电荷的结晶紫形成缔合物微粒,导致体系溶液共振光散射明显增强.在546.8 nm处,共振光强度的改变值ΔI溶液中H2O2的含量在0.017~0.714 μg/mL范围内呈良好的线性关系,据此建立了一种共振光散射法检测H2O2,方法检出限5.10×10-3 μg/mL H2O2,相对标准偏差为3.1%~3.5%,该方法用于水样的测定,加标回收率为96.1%~102%,结果满意.  相似文献   

9.
本文研究了镁对H13模具钢中夹杂物的影响,对H13钢中夹杂物的变性进行了热力学计算,分析了镁对夹杂物成分、形貌和粒径分布的影响。结果表明,镁处理H13钢后,夹杂物由Al2 O3转变为MgO·Al2 O3,复合型夹杂物的析出位置也发生了改变,夹杂物粒径变小。镁处理使钢中1μm左右的夹杂物增多,2μm以上的夹杂物减少,随着镁含量的升高,粒径的变化更明显。铝质量分数为0.01%~0.03%的H13钢中,微量的镁就可促使MgO·Al2O3夹杂物形成,镁质量分数超过1×10^-4会导致H13钢中MgO·Al2O3完全消失,镁质量分数在3×10^-5~5.5×10^-5时钢液中镁铝尖晶石的数量达到最多。  相似文献   

10.
铝热自蔓延制备CuCr合金渣系粘度测量及模型建立(Ⅱ)   总被引:1,自引:0,他引:1  
用已建立的针对非二氧化硅体系的粘度模型对CaO Al2O3体系的粘度值进行估算,与前人的测量值进行了比较,估算值和文献测量值吻合·根据已知文献确定了CaO Al2O3体系中的Al3+和Ca2+的离子作用系数L·由测量知,CaO Al2O3体系共晶点附近的熔渣流动性好,在1460℃时粘度值低于0 5Pa·s·对于Al2O3 CaO MgO体系按两个不同共晶点处的成分配渣,其中含氧化钙较多的渣粘度较低,1500℃时,其粘度小于0 03Pa·s·添加剂MgO能显著降低CaO Al2O3体系的熔渣粘度·  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

15.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

16.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

17.
以AC-13级配为基础,将橡胶颗粒代替部分集料掺入混合料中,以低温弯曲试验为评价方法对不同橡胶颗粒掺量下沥青混合料的低温抗裂性进行研究,并引入应变能密度值对混合料的低温抗裂性进行综合评价.试验结果表明:橡胶颗粒沥青混合料试件的破坏微应变均超过2 300,满足冬寒区的技术指标;无论是否掺加橡胶颗粒,随着温度的下降,沥青混合料破坏时的最大弯拉强度增大,弯拉应变降低,劲度模量增大;弯曲应变能密度在胶粒掺量为1%左右时具有较大的弯曲应变能密度值,此时橡胶颗粒沥青混合料具有较好的低温抗裂性.  相似文献   

18.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

19.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

20.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

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