| 新型N-杂环卡宾研究进展 |
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| 引用本文： | 孔勇,褚奇,杨帆,李胜.新型N-杂环卡宾研究进展[J].科学技术与工程,2016,16(32). |
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| 作者姓名： | 孔勇 褚奇 杨帆 李胜 |
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| 作者单位： | 中国石化石油工程技术研究院,中国石化石油工程技术研究院,中国石化石油工程技术研究院,中国石化石油工程技术研究院 |
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| 基金项目： | 国家科技重大专项子课题“川西低渗气藏低伤害钻井液技术研究(2016ZX05021004-002)”、中石化科技部项目“环境响应铝基处理剂前瞻研究(P15105)”资助。 |
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| 摘 要： | 近20年来,N-杂环卡宾已经成为有机化学研究领域的明星分子。随着研究不断深入,各种新型N-杂环卡宾被合成出来。结合N-杂环卡宾的相关研究报道,简要介绍了经典N-杂环卡宾(1,3-二取代咪唑卡宾)的基本情况,随后重点介绍了反常N-杂环卡宾和其他新型N-杂环卡宾的合成和研究情况。在此基础上,指出了今后N-杂环卡宾合成研究的发展方向。
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| 关 键 词： | N-杂环卡宾 合成 官能团 催化 综述 |
| 收稿时间： | 2016/6/30 0:00:00 |
| 修稿时间： | 2016/6/30 0:00:00 |
Research Advances of New N-heterocyclic Carbene |
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| KONG Yong,CHU Qi,YANG Fan and LI Sheng.Research Advances of New N-heterocyclic Carbene[J].Science Technology and Engineering,2016,16(32). |
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| Authors: | KONG Yong CHU Qi YANG Fan and LI Sheng |
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| Institution: | Research Institute of Petroleum Engineering,Sinopec,Research Institute of Petroleum Engineering,Sinopec,Research Institute of Petroleum Engineering,Sinopec |
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| Abstract: | N-heterocyclic carbene has become a star in the field of organic chemistry research, over the past 20 years. A number of new N-heterocyclic carbenes have been synthesized, while the research is developing. According to the recent reports, the classic N-heterocyclic carbene (1,3-disubstituted imidazole carbene) was briefly introduced, firstly. The recent research advances of abnormal N- N-heterocyclic carbene and other novel N-heterocyclic carbene were focused on. The development trends of N-heterocyclic carbine synthesis and research were proposed, on the basis. |
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| Keywords: | N-heterocyclic carbene synthesis functional group catalyze review |
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