| 海洋天然产物环倍半萜醇Capnelenol的研究Ⅰ二环中间体4，7，7－三甲基二环［3，3，0］辛烷酮的合成 |
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| 引用本文： | 汪波,李瑞声,龙康侯.海洋天然产物环倍半萜醇Capnelenol的研究Ⅰ二环中间体4，7，7－三甲基二环［3，3，0］辛烷酮的合成[J].中山大学学报(自然科学版),1996(6). |
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| 作者姓名： | 汪波 李瑞声 龙康侯 |
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| 作者单位： | 中山大学化学系 |
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| 摘 要： | 三并五员环倍半萜醇Ｃａｐｎｅｌｅｎｏｌｓ是从软珊瑚Ｃａｐｎｅｌａｉｍｂｒｉｃａｔａ中分离得到的一类结构新颖并且具有生理活性的化合物．通过５步反应路线合成了关键的二环中间体４，７，７－三甲基二环［３，３，０］辛烷酮并且对其中的４步合成方法作了改进
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| 关 键 词： | 合成，倍半萜，4，7，7－三甲基二环［3，3，0］辛烷酮，Capnelenol |
Total Synthesis of the Marine Nature Product Triquinane Capnellenol |
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| I Synthesis of the Key Intermediate , Trimethybicyclooctanone Wang Bo.Total Synthesis of the Marine Nature Product Triquinane Capnellenol[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,1996(6). |
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| Authors: | I Synthesis of the Key Intermediate Trimethybicyclooctanone Wang Bo |
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| Institution: | I Synthesis of the Key Intermediate 4,7,7 Trimethybicyclooctanone Wang BoDepartment of Chemistry,Zhongshan University,Guangzhou 510275 Li Ruisheng Long Kanhou |
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| Abstract: | Capnellenols are series of sesquiterpenes isolated from soft coral Capnella imbricata. They posses unusual linear triquinane skeleton and biological activity. In this paper the key intermediate for the synthesis of Capnellenols, 4,7,7 trimethylbicyclooctanone was synthesized with a five step route. The reaction conditions or methods of the four steps of this route were improved, and the results were satisfactory. |
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| Keywords: | synthesis triquinane 4 7 7 trimethylbicyclooctanone Capnellol |
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