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固体酸催化合成丙酸异戊酯
引用本文:俞善信,刘美艳,文瑞明.固体酸催化合成丙酸异戊酯[J].湖南文理学院学报(自然科学版),2007,19(3):29-33.
作者姓名:俞善信  刘美艳  文瑞明
作者单位:湖南师范大学,化学化工学院,湖南,长沙,410081;湖南城市学院,化学与环境工程系,湖南,益阳,413049
基金项目:湖南省教育厅科研基金资助项目(01C022)
摘    要:固体酸能够代替硫酸作为酯化催化剂.评述了甲烷磺酸盐,磺化苯膦酸锆,强酸性阳离子交换树脂,磺化聚氯乙烯,三氯化铁,聚氯乙烯三氯化铁树脂,氯化聚氯乙烯三氯化铁树脂,四氯化锡,氯化亚锡,离子交换树脂-四氯化钛,树脂负载三氯化铝,水合硫酸铁,十二水合硫酸铁铵,硫酸铈,硫酸铝,硫酸钛,-水硫酸氢钠,固体超强酸,杂多酸,固载杂多酸和分子筛等固体酸催化合成丙酸异戊酯的方法.

关 键 词:丙酸异戊酯  合成  固体酸  催化
文章编号:1672-6146(2007)03-0029-05
修稿时间:2007-05-08

Synthesis of Isoamyl Propionate Catalyzed by Solid Acid
YU Shan-xin,LIU Mei-yan,WEN Rui-ming.Synthesis of Isoamyl Propionate Catalyzed by Solid Acid[J].Journal of Hunan University of Arts and Science:Natural Science Edition,2007,19(3):29-33.
Authors:YU Shan-xin  LIU Mei-yan  WEN Rui-ming
Institution:1. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering Hunan City University, Yiyang Hunan 413049
Abstract:Solid acid can be used as catalyst for the esterifica-tion instead of sulphuric acid,The catalytic synthesis of isoamyl propionate with methane sulfonate,zirconium sulpho-phenylphosphonate,strongly acidic cationic exchange resin,sulfo-polyvinyl chloride,ferric chloride,polyvinyl chloride-ferric chloride resin,chlorinated polyvinyl chloride-ferric chloride resin,stannic chloride,stannous chloride,ion exchange resin-titanium chloride,aluminium chloride supported on resin,ferric sulfate hydrate,ammonium ferric sulfate dodecahydrate,cerium sulfate,aluminium sulfate,titanium sulfate,sodium bisulfate monohydrate,solid superacid,heterpoly acid,support heterpoly acid and molecular sieve etal.solid acid catalyst were reviewed.
Keywords:isoamyl propionate  synthesis  solid acid  catalysis
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