| 四(3,4-亚甲二氧基苯基)卟啉及其钴配合物的合成与表征 |
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| 引用本文： | 吕艳阳,翟秋阁,李娟,刘多.四(3,4-亚甲二氧基苯基)卟啉及其钴配合物的合成与表征[J].信阳师范学院学报(自然科学版),2011,24(1):120-123. |
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| 作者姓名： | 吕艳阳 翟秋阁 李娟 刘多 |
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| 作者单位： | 信阳师范学院,化学化工学院,河南,信阳,464000 |
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| 基金项目： | 河南省教育厅自然科学基金 |
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| 摘 要： | 以3,4-亚甲二氧基苯甲醛(胡椒醛)和吡咯为原料合成3,4-亚甲二氧基苯基卟啉及其钴配合物,探索溶剂、催化剂等反应条件对产品纯度及产率的影响.结果表明,以丙酸为溶剂及催化剂制备3,4-亚甲二氧基苯基卟啉的产率高、纯度好.新化合物结构分别被UV-Vis,IR,1HNMR及元素分析所证实.
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| 关 键 词： | 3 4-亚甲二氧基苯基卟啉 钴 合成 光谱分析 |
Synthesis and Characterization of Meso-Tetra(3,4-Methylenedioxy Benzaldehyde)Porphyrin and Its Cobalt(Ⅱ)Complexes |
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| LV Yan-yang,ZHAI Qiu-ge,LI Juan,LIU Duo.Synthesis and Characterization of Meso-Tetra(3,4-Methylenedioxy Benzaldehyde)Porphyrin and Its Cobalt(Ⅱ)Complexes[J].Journal of Xinyang Teachers College(Natural Science Edition),2011,24(1):120-123. |
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| Authors: | LV Yan-yang ZHAI Qiu-ge LI Juan LIU Duo |
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| Institution: | LV Yan-yang,ZHAI Qiu-ge,LI Juan,LIU Duo(College of Chemistry and Chemical Engineering,Xinyang Normal University,Xinyang 464000,China) |
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| Abstract: | The synthesis methods of 3,4-methylenedioxy benzaldehyde porphyrin and its cobalt complexes were researched.The influence of the reaction condition such as solvent and catalyst was explored in the product purity and yield.The results indicated that 3,4-methylenedioxy benzaldehyde porphyrin was high yield and purity with the propionic acid as solvent and catalysts.Their structures were confirmed by UV-Vis,IR,1H NMR spectra and elemental analysis. |
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| Keywords: | 3 4-methylenedioxy benzaldehyde porphyrin cobalt synthesis spectral analysis |
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