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镉-二茂铁亚甲基苯并咪唑配合物的合成、晶体结构与电化学性质
引用本文:周晓莉,侯红卫.镉-二茂铁亚甲基苯并咪唑配合物的合成、晶体结构与电化学性质[J].中州大学学报,2008,25(3):113-118.
作者姓名:周晓莉  侯红卫
作者单位:[1]郑州大学化学系,郑州450052; [2]中州大学实验管理中心,郑州450044
摘    要:制备了一个新型的三维超分子化合物:镉-二茂铁亚甲基苯并咪唑配合物Cd(FBIM)2I2](FBIM=二茂铁亚甲基苯并咪唑),并通过X-射线衍射仪对其晶体结构进行了表征。循环伏安测试结果表明其氧化还原过程是受扩散控制的,计时电流法和计时电量法测得其扩散系数分别为1.02×10^-5和I.36×10^-5cm^2/s。

关 键 词:合成  晶体结构  二茂铁配合物  电化学性质

Synthesis, Crystal Structure and Electrochemical Properties of Ferrocenyl Methyl Benzimidazole Cadmium Complex
ZHOU Xiao-li,HOU Hong-wei.Synthesis, Crystal Structure and Electrochemical Properties of Ferrocenyl Methyl Benzimidazole Cadmium Complex[J].Journal of Zhongzhou University,2008,25(3):113-118.
Authors:ZHOU Xiao-li  HOU Hong-wei
Institution:ZHOU Xiao - li,HOU Hong - wei(1. Dept. of Chemistry, Zhengzhou University, Zhengzhou 450052 China;2. Experiment Administrative Center, Zhongzhou University, Zhengzhou 450044 China)
Abstract:A novel 3 - D superamolecular network Cd(FBIM)2I2 ] 1 (FBIM = ferrocenyl methyl benzimidazole) has been synthesized and structurally characterized by x - ray single crystal diffraction. The cyclic vohammetry (CV) studies show that the redox processes of 1 is controlled by the diffusion. The diffusion coefficients (D) are obtained from chronocoulometry (CC) and chronoamperometry (CA) methods. The D values are 1.02×10^-5 and 1.36 × 10^-5 cm^2/s, respectively.
Keywords:synthesis  crystal structure  ferrocenyl complex  electrochemical properties
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