| 可逆加成-断裂链转移自由基聚合试剂的选择 |
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| 引用本文： | 汪国元,黄勇,余任亮.可逆加成-断裂链转移自由基聚合试剂的选择[J].江西科学,2009,27(6):927-931. |
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| 作者姓名： | 汪国元 黄勇 余任亮 |
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| 作者单位： | 1. 九江职业大学,江西,九江,332000
2. 江西省科学院,江西,南昌,330029 |
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| 摘 要： | 可逆加成-断裂链转移自由基（RAFT）聚合，是在常规自由基聚合过程中，添加一种可逆加成-断裂链转移制，达到“活性”聚合特征．根据单体自由基的活性、RAFT试剂R基团稳定性、Z基团的吸、推电子效应，选择结构合适的RAFT试剂。
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| 关 键 词： | 可逆加成-断裂链转移自由基聚合 试剂 选择 |
Selection for Reversible Addition-Fragmentation Chain Transfer Radical Polymerization Agents |
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| WANG Guo-yuan,HUANG Yong,YU Ren-liang.Selection for Reversible Addition-Fragmentation Chain Transfer Radical Polymerization Agents[J].Jiangxi Science,2009,27(6):927-931. |
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| Authors: | WANG Guo-yuan HUANG Yong YU Ren-liang |
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| Institution: | WANG Guo-yuan, HUANG Yong, YU Ren-liang ( 1. Jiujiang Vocational University ,Jiangxi Jiujiang 332000 PRC; 2. Jiangxi Academy of Seienees,Jiangxi Nanchang 330029 PRC) |
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| Abstract: | Reversible addition-fragmentation chain transfer （RAFT） radical polymerization is adding a kind of reversible addition-fragmentation chain transfer agents to the conversion radical polymerization system. Based on monomer radical activity, RAFT agents＇ R group stability,and Z group attracting-propelling electronic effect,can select proper RAFT agents for the RAFT polymerization. |
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| Keywords: | Reversible addition-fragmentation chain transfer radical polymerization Agent Selection |
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