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有机溶剂中C.cylindracea脂肪酶催化有机硅醇的转酯反应
引用本文:邱树毅,宗敏华,姚汝华.有机溶剂中C.cylindracea脂肪酶催化有机硅醇的转酯反应[J].贵州工业大学学报(自然科学版),1999,28(5).
作者姓名:邱树毅  宗敏华  姚汝华
作者单位:贵州工业大学轻工系!贵州贵阳55003(邱树毅),华南理工大学生物工程系!广东广州510641(宗敏华,姚汝华)
基金项目:国家自然科学基金资助,广东省自然科学基金资助
摘    要:C.cylindracea 脂肪酶能在有机介质中催化有机硅醇与酯的转酯反应。高浓度酯和有机硅醇未有抑制酶催化转酯反应活性。在饱和水的有机溶剂中酶催化转酯反应转化率高于脱水有机溶剂中的酶催化转酯反应。

关 键 词:脂肪酶  有机硅醇  转酯反应

Interesterification of Trimethylsilyl-Alcohol Catalyzed by C.cylindracea Lipase in Organic Medium
QIU Shu-yi,ZONG Min-hua,YAO Ru-hua.Interesterification of Trimethylsilyl-Alcohol Catalyzed by C.cylindracea Lipase in Organic Medium[J].Journal of Guizhou University of Technology(Natural Science Edition),1999,28(5).
Authors:QIU Shu-yi  ZONG Min-hua  YAO Ru-hua
Abstract:A kind of lipase from C.cylindracea was used to catalyze interesterification of trimethylsilylalcohol with fatty acid ester in organic medium.Enzyme activity was not inhibited by the high concentration of organsilicon alcohol and fatty acid ester.The conversion ratio of interesterification was higher in saturated water octane than that in removed water octane.
Keywords:lipase  trimethylsilyl  alcohol  interesterification
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