| 几个聚合物负载的奎宁催化剂的合成 |
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| 引用本文： | 马秋石,张莲鹏,李文,汤峨.几个聚合物负载的奎宁催化剂的合成[J].云南大学学报(自然科学版),2011,33(6):699. |
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| 作者姓名： | 马秋石 张莲鹏 李文 汤峨 |
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| 作者单位： | 教育部自然资源药物化学重点实验室云南大学化学科学与工程学院; |
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| 基金项目： | 国家自然科学青年基金资助项目(20802063); 教育部自然资源药物化学重点实验室研究基金; 2009年云南大学国家级大学生创新性实验计划项目(X3108052)联合资助 |
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| 摘 要： | 基于聚合物试剂合成的后处理简单,纯化方便和易于回收的特点,分别用聚苯乙烯和聚乙二醇树脂为载体进行几个手性奎宁催化剂的固相和液相组合合成,考察了MPEG5000负载的奎宁催化剂沉降率的影响因素.
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| 关 键 词： | 奎宁 手性聚合物试剂 合成 |
Synthesis of several polymer-supported quinines |
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| MA Qiu-shi,ZHANG Lian-peng,LI Wen,TANG E.Synthesis of several polymer-supported quinines[J].Journal of Yunnan University(Natural Sciences),2011,33(6):699. |
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| Authors: | MA Qiu-shi ZHANG Lian-peng LI Wen TANG E |
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| Institution: | MA Qiu-shi,ZHANG Lian-peng,LI Wen,TANG E(Key Laboratory of Medicinal Chemistry for Natural Resources,Ministry of Education School of Chemistry and Technology,Yunnan University,Kunming 650091,China) |
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| Abstract: | Several polymer-supported quinines as chiral catalysts were synthesized from polystyrene and polyethylene glycol as supporter.The synthesis has the advantages of easy purification and recovery.The factors to influence the sedimentation of MPEG-supported quinine were also discussed. |
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| Keywords: | polymer-supported quinine chiral catalysts synthesis |
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