| Ph3SnO2C4H3S的合成、性质和晶体结构 |
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| 引用本文： | 尹汉东,王勇,马春林.Ph3SnO2C4H3S的合成、性质和晶体结构[J].聊城大学学报(自然科学版),2003,16(3):4-5,80. |
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| 作者姓名： | 尹汉东 王勇 马春林 |
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| 作者单位： | 聊城大学,化学化工学院,山东,聊城,252059 |
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| 基金项目： | 国家自然科学基金(20271025)，山东省自然科学基金(Z200802)资助项目 |
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| 摘 要： | 用Ph3SnCl与NaO2C4H3S反应，合成了Ph3SnO2C4H3S，并进行了红外光谱、核磁共振氢谱及质谱表征．X-射线单晶衍射表明，该化合物的晶体是由孤立的分子所组成，四配位的锡原子呈畸变的四面体构型，配体噻吩环上的硫原子和锡原子之间存在弱的配位作用．
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| 关 键 词： | Ph3SnO2C4H3S 晶体结构 合成 三苯基锡 2-噻吩甲酸 三苯基锡2-噻吩甲酸酯 有机锡羧酸酯 |
| 文章编号： | 1007-8304(2003)03-0004-02 |
Synthesis and Crystal Structure of Ph3SnO2C4H3S |
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| YIN Han-Dong,WANG Yong,MA Chun-Lin.Synthesis and Crystal Structure of Ph3SnO2C4H3S[J].Journal of Liaocheng University:Natural Science Edition,2003,16(3):4-5,80. |
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| Authors: | YIN Han-Dong WANG Yong MA Chun-Lin |
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| Abstract: | Ph_3SnO_2C4H_3S was synthesized by the reaction of Ph3SnCl with NaO2C4H3S and was characterized by IR,1H NMR and MS spectra. The crystal structure was determined by X-ray single crystal diffraction. In the crystals,the structure consist of discrete molecule containing four-coordinate tin atom in a distorted tetrahedral configuration |
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| Keywords: | triphenyltin 2-thiophenecarboxylic acid synthesis crystal structure |
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