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PTIO的合成及对NO的氧化特性
引用本文:杜尧国,李润博,冯流,李绍民.PTIO的合成及对NO的氧化特性[J].吉林大学学报(理学版),2000(1).
作者姓名:杜尧国  李润博  冯流  李绍民
作者单位:吉林大学环境科学与工程系,长春,130023
摘    要:从 2 -硝基丙烷出发 ,经过 4步反应合成 PTIO ( 2 - phenyl- 4,4,5,5- tetramethyl-imidazoline- 3- oxide- 1 - oxyl)蓝色晶体 .该合成物的熔点、元素分析结果以及顺磁共振波谱经与国外产品进行对照实验 ,结果吻合 .并就 PTIO对 NO氧化特性进行研究

关 键 词:PTIO  无动力采样  总氮氧化物

Synthesis of PTIO and Its Oxidizing Property for NO
DU Yao-guo,LI Run-bo,FENG Liu,LI Shao-min.Synthesis of PTIO and Its Oxidizing Property for NO[J].Journal of Jilin University: Sci Ed,2000(1).
Authors:DU Yao-guo  LI Run-bo  FENG Liu  LI Shao-min
Abstract:A blue crystal PTIO was (2 phenyl 4,4,5,5 tetramethgl imidazoline 3 oxide 1 oxyl) synthesized from 2 nitropropane via a four step reaction. The melting point, the elemental analysis results and the paramagnetic resonance spectrum of the crystal compound are in agreement with these of the same product produced abroad. The cost for synthesizing the compound was reduced by 90% compared with the same Japanese product, and by 99% compared with the same American product. When it is used in NO x non electric samplers, its oxidizing property is better than that of other oxidants.
Keywords:phenyl  4  4  5  5  tetramethyl  imidazoline  3  oxide  1  oxyl  non  electric sampler  NO    x
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