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| 苯甲酸铝的流变相反应法合成及热分解机理 | |
| 引用本文： | 宋力,何波,袁良杰,张克立.苯甲酸铝的流变相反应法合成及热分解机理[J].河南大学学报(自然科学版),2007,37(3):249-254. |
| 作者姓名： | 宋力 何波 袁良杰 张克立 |
| 作者单位： | 1. 信阳师范学院,化学化工学院,河南,信阳,464000;武汉大学,化学与分子科学学院,湖北,武汉,430072 2. 信阳职业技术学院,化学系,河南,信阳,464000 3. 武汉大学,化学与分子科学学院,湖北,武汉,430072 |
| 摘 要： | 用流变相反应法合成2种苯甲酸铝配合物,通过元素分析,红外光谱,TG、DTG和DTA确定了配合物的组成,用TG、DTG、DTAI、R、XRD、FABMS表征了热分解产物并研究了配合物在氮气气氛中的热分解过程.苯甲酸铝在氮气气氛中的热分解分2步进行:第一步失去水分子成为苯甲酸内盐;第二步苯甲酸内盐分解生成氧化铝和有机化合物,生成的有机化合物成分比较复杂,主要成分是9,10-蒽醌等. |
| 关 键 词： | 苯甲酸铝配合物 流变相反应 热分解 |
| 文章编号： | 1003-4978（2007）03-0249-06 |
| 修稿时间： | 2006-03-26 |
Synthesis with Rheological Phase Reaction and Thermal Decomposition of Aluminium Benzoate |
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| SONG Li,HE Yi-bo,YUAN Liang-jie,ZHANG Ke-li.Synthesis with Rheological Phase Reaction and Thermal Decomposition of Aluminium Benzoate[J].Journal of Henan University(Natural Science),2007,37(3):249-254. | |
| Authors: | SONG Li HE Yi-bo YUAN Liang-jie ZHANG Ke-li |
| Institution: | 1 .Department of Chemistry and Chemical Engineering , Xinyang Normal University, Henan Xinyang 464000, China; 2 .College of Chemistry and Molecular Sciences , Wuhan University, Wuhan 430072, China; 3 .Department of Chemistry, Xinyang Vocational and Technical College, Henan Xinyang 464000, China |
| Abstract: | Aluminium benzoates were synthesized with rheological phase reaction.The complexes were characterized by elemental analysis,IR.The mechanisms of thermal decomposition of aluminium benzoates in N2 were studied with TG,DTG,DTA,IR,XRD and FABMS.The thermal decomposition of aluminium benzoates in N2proceeded in two stages:first it decomposes to form aluminium benzoates and organic compounds.The organic compounds are mainly 9,10-anthraquinone benzoic acid and so on,then decomposes further to form aluminium oxide. |
| Keywords: | aluminium benzoate rheological phase reaction thermal decomposition |
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