Synthesis of novel polymer-bonded water-soluble metal porphyrins |
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| Authors: | Li Zao-ying Li Cong Liang Jiang-lin Zhang Yue-ning |
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| Institution: | (1) College of Chemistry, Wuhan University, 430072 Wuhan, China |
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| Abstract: | The reaction of 5, 10, 15, 20-tetra-(4-pyridyl) porphyrin 1 with triruthenium dodecacarbonyl Ru3(CO)12], zinc(II) acetate, copper(II) acetate, cobalt(II) acetate afforded complexes 2a−2d respectively. Treatment of 2a−2d with
Merrifield’s peptide resin obtained 3a−3d. The compounds 3a−3d reacted with methyl iodide respectively gave 4a−4d. New complexes
4a−4d have been identified by IR, UV-visible spectra, and AES.
Foundation item: Supported by the Natural Science Foundation of Hubei Province
Biography: LI Zao-ying (1949-), female, Associate professor. |
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| Keywords: | polymer-bonded metal porphyrin water-soluble porphyrin synthesis |
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