| 内型异莰烷基一氯甲烷的合成 |
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| 引用本文： | 肖转泉,赖春球.内型异莰烷基一氯甲烷的合成[J].江西师范大学学报(自然科学版),1994,18(4):291-294. |
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| 作者姓名： | 肖转泉 赖春球 |
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| 作者单位： | 江西师大化学系!南昌330027 |
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| 摘 要： | 该文报道了从莰烯先经甲酰化制得8-甲酰基莰烯,再依次用Pd-C和Ni(R)催化氢化合成内型异莰烷基甲醇,使内型异莰烷基甲醇与亚硫酰氯反应合成内型异莰烷基一氯甲烷.产品进行了纯化和红外、核磁共振与质谱分析.为从莰烯合成新型的异莰烷类化合物开辟了一条新的途径.
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| 关 键 词： | 合成 莰烯 内型异莰烷 一氯甲烷 萜类化合物 |
The Synthesis of Endo-isocamphanylchloromethane |
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| Xiao Zhuanquan Lai Chunqiu.The Synthesis of Endo-isocamphanylchloromethane[J].Journal of Jiangxi Normal University (Natural Sciences Edition),1994,18(4):291-294. |
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| Authors: | Xiao Zhuanquan Lai Chunqiu |
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| Abstract: | :In this paper,endo-isocamphanylchloromethane was synthesized by the chlorination of endo-iso-camphaylmethanol(4),which was prepared from camphene by forraylation and catalytic hydrogenation. Theproducts have been purified and characterized with IR,H-NMR and MS. Thus,a new way for the syntheses ofnew endo-isocarnphyane derivatives was established. |
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| Keywords: | synthesis catalytic hydrogenation chlorination camphene |
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