| 缬氨酸锑和缬氨酸铋配合物的制备与结构分析 |
| |
| 引用本文： | 杨宇翔,郇伟伟,纪国媛,陈娅如.缬氨酸锑和缬氨酸铋配合物的制备与结构分析[J].同济大学学报(自然科学版),2011,39(3):451-455. |
| |
| 作者姓名： | 杨宇翔 郇伟伟 纪国媛 陈娅如 |
| |
| 作者单位： | 华东理工大学,化学与分子工程学院,上海,200237 |
| |
| 基金项目： | 上海市科委各类项目（项目编号） |
| |
| 摘 要： | 采用室温固相合成法合成了缬氨酸与三氯化锑、三氯化铋的两种生物配合物,其组成为Sb(C5H1002N)3·2H2O,Bi(C5 H1002N)2Cl·0.5H2O.缬氨酸锑配合物的晶体结构属于三斜晶系,晶胞参数为a=0.959 9 nm,b=1.506 8 nm,c=1.985 1 nm,α=92.27°,β=95.05...
|
| 关 键 词： | 缬氨酸 配合物 锑 铋 三氯化物 固相反应 合成 |
| 收稿时间： | 9/7/2009 11:51:21 AM |
| 修稿时间： | 1/25/2011 7:21:03 PM |
Preparation and Structure Analysis of Antimony Trichloride and Bismuth Trichloride Comlexes with Valine |
| |
| YANG Yuxiang,HUAN Weiwei,JI Guoyuan and CHEN Yaru.Preparation and Structure Analysis of Antimony Trichloride and Bismuth Trichloride Comlexes with Valine[J].Journal of Tongji University(Natural Science),2011,39(3):451-455. |
| |
| Authors: | YANG Yuxiang HUAN Weiwei JI Guoyuan and CHEN Yaru |
| |
| Institution: | Department of Chemistry, East China University of Science & Technology, Shanghai 200237,China;Department of Chemistry, East China University of Science & Technology, Shanghai 200237,China;Department of Chemistry, East China University of Science & Technology, Shanghai 200237,China;Department of Chemistry, East China University of Science & Technology, Shanghai 200237,China |
| |
| Abstract: | Two compounds of antimony trichloride and bismuth trichloride with valine are synthesized by solid phase synthesis at room temperature.Their compositions,determined by element analysis,are Sb(C5H10O2N)3·2H2O and Bi(C5H10O2N)2Cl·0.5H2O.The crystal structure of antimony complex with valine belongs to triclinic system and its lattice parameters are: a= 0.959 9 nm,b=1.506 8 nm,c=1.985 1 nm,α=92.27°,β=95.05°,γ=104.27°.The crystal structure of bismuth complex with valine belongs to monoclinic system and its lattice parameters are: a=1.601 2 nm,b=1.894 1 nm,c=1.839 nm,β=99.73°.The far-infrared spectra and the infrared spectra show that the amino group and carboxyl of valine may be coordinated to antimony and bismuth,respectively,in two compounds.The TG-DSC results also reveal that the complexes are formed. |
| |
| Keywords: | valine complexes antimony bismuth trichloride solid phase reaction synthesis |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《同济大学学报(自然科学版)》浏览原始摘要信息 |
| 点击此处可从《同济大学学报(自然科学版)》下载免费的PDF全文 |
|
