| 4,4’-二羟基-2,2’-联吡啶的高效合成方法 |
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| 引用本文： | 张新玉,汤红英,张中标.4,4’-二羟基-2,2’-联吡啶的高效合成方法[J].天津师范大学学报(自然科学版),2011,31(4):92-94. |
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| 作者姓名： | 张新玉 汤红英 张中标 |
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| 作者单位： | 天津师范大学天津市水资源与水环境重点实验室,天津,300387 |
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| 基金项目： | 天津师范大学青年博士基金资助项目，天津师范大学人才引进基金资助项目 |
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| 摘 要： | 以2,2’-联吡啶为原料,经过氧化、硝化、甲氧基化、脱氧和去甲基五步反应,系统高效地合成了4,4’-二羟基-2,2’-联吡啶,并采用核磁共振、熔点、红外光谱等实验方法对产物的结构进行了表征.
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| 关 键 词： | 氧化 硝化 甲氧基化 脱氧 去甲氧基 4 4’-二羟基-2 2’-联吡啶 系统高效 |
High-effective synthesis of 2,2'- bipyridinyl-4,4'- diol |
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| ZHANG Xinyu,TANG Hongying,ZHANG Zhongbiao.High-effective synthesis of 2,2'- bipyridinyl-4,4'- diol[J].Journal of Tianjin Normal University(Natural Science Edition),2011,31(4):92-94. |
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| Authors: | ZHANG Xinyu TANG Hongying ZHANG Zhongbiao |
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| Institution: | ZHANG Xinyu,TANG Hongying,ZHANG Zhongbiao(Tianjin Key Laboratory of Water Resources and Environment,Tianjin Normal University,Tianjin 300387,China) |
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| Abstract: | 2,2'-bipyridinyl-4,4'-diol was synthesized from 2,2'-bipyridine through five steps: oxidation,nitration,methoxylation,deoxidation and demethylation.This method was proved to be systemic and high-effective.2,2'-bipyridinyl-4,4'-diol was characterized by NMR,melting point measurement and FT-IR. |
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| Keywords: | oxidation nitration methoxylation deoxidation demethylation 2 2'-bipyridinyl-4 4'-diol systemic and high-effective |
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