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苯并三唑类紫外线吸收剂的合成
引用本文:徐步斌,祁国珍.苯并三唑类紫外线吸收剂的合成[J].华东理工大学学报(自然科学版),1997,23(1):58-62.
作者姓名:徐步斌  祁国珍
作者单位:华东理工大学精细化工系
摘    要:经过重氮化,偶合,还原反应,合成了7个不同结构的苯并三唑类紫外线吸收剂。改进了还原反应条件,讨论了还原反应机理,分离出中间产物,并用红外光谱,质谱,核磁共振等方法确证了结构。讨论了紫外吸收和吸收剂结构间的关系。

关 键 词:紫外线吸收剂  苯并三唑  合成  还原反应

Synthesis of UV Absorbers of Benzotriazol Structure
Abstract:Seven UV absorbers of benzotriazol structure were prepared by diazotisation, coupling and reduction. Reaction conditions were modified and reaction mechanism was studied. The intermediate compounds of reduction were isolated and identified by IR, MS and H NMR . The relationship between the UV absorption and structure was also explained.
Keywords:UV absorber  benzotriazol  synthesis  reduction  photosatabilizer  
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