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| 1-苯甲酰基3-(邻氯苯基)硫脲的简便合成法 | |
| 引用本文： | 杜文虎,徐娟,支三军,韦长梅.1-苯甲酰基3-(邻氯苯基)硫脲的简便合成法[J].淮阴师范学院学报(自然科学版),2011,10(2):122-126. |
| 作者姓名： | 杜文虎 徐娟 支三军 韦长梅 |
| 作者单位： | 1. 淮阴师范学院化学化工学院,江苏淮安223300;江西生物科技职业学院动物科学系,江西南昌330200 2. 淮阴师范学院化学化工学院,江苏淮安,223300 3. 淮阴师范学院化学化工学院,江苏淮安223300;江苏省低维功能材料重点建设实验室,江苏淮安223300 |
| 基金项目： | 江苏省教育厅产业化推进工程项目，淮安市产学研合作促进计划项目 |
| 摘 要： | 研究了在PEG-400催化下,二氯甲烷溶剂中,以苯甲酰氯、硫氰酸铵和邻氯苯胺为原料简便合成1-苯甲酰基3-(邻氯苯基)硫脲的方法.通过考察反应时间、温度、物料比及溶剂等因素对产率的影响,获得了反应的优化条件.产品结构经元素分析、1H NMR和IR表征. |
| 关 键 词： | 酰基硫脲 邻氯苯胺 合成 |
The Simple Synthesis Method of 1 -Benzoyl-3- ( o- chlorophenyl ) thiourea |
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| DU Wen-hu,XU Juan,ZHI San-jun,WEI Chang-mei.The Simple Synthesis Method of 1 -Benzoyl-3- ( o- chlorophenyl ) thiourea[J].Journal of Huaiyin Teachers College(Natrual Science Edition),2011,10(2):122-126. | |
| Authors: | DU Wen-hu XU Juan ZHI San-jun WEI Chang-mei |
| Abstract: | The simple synthesis method of 1-Benzoyl-3-(o-chlorophenyl)thiourea by using benzoyl chloride,ammonium thiocyanate and o-chloroaniline as raw material in the presence of PEG-400 as catalyst and methylene dichloride as solvent.The optimum conditions of increase in the product yield were obtained by investigating the influences of reaction temperature,time,solvent and the quantity of raw material.Respectively,elementary,1H NMR and IR analysis proved the structure of product. |
| Keywords: | acyl thiourea o-chloroaniline synthesis |
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