| 三种硫代酯的合成和表征 |
| |
| 引用本文： | 周晓静,袁福根.三种硫代酯的合成和表征[J].苏州科技学院学报(自然科学版),2009,26(2):60-63. |
| |
| 作者姓名： | 周晓静 袁福根 |
| |
| 作者单位： | 苏州科技学院化学与生物工程学院,江苏,苏州,215009 |
| |
| 摘 要： | 研究了三种不同类型的硫代酯的合成,即苄基二硫代苯甲酸酯（BDB）、N,N-二苯基-2-苄基二硫代氨基甲酸酯（BDC）和2-叔丁基-2’-苄基三硫代碳酸酯（BTC）。详细描述和分析了反应过程中溶液颜色状态和热效应等变化现象。产物经过柱层析分离或重结晶提纯,经过核磁共振波谱、红外光谱、质谱、元素分析等表征,确定合成产物与目标化合物相符。
|
| 关 键 词： | 硫代酯 合成 苄基 二硫化碳 |
Synthesis and Characterization of Three Thioesters |
| |
| ZHOU Xiao-jing,YUAN Fu-gen.Synthesis and Characterization of Three Thioesters[J].Journal of University of Science and Technology of Suzhou,2009,26(2):60-63. |
| |
| Authors: | ZHOU Xiao-jing YUAN Fu-gen |
| |
| Institution: | (School of Chemistry and Biochemistry,SUST,Suzhou 215009, China) |
| |
| Abstract: | Three thioesters are prepared, i.e. benzyl dithiobenzoate （BDB）,N,N-diphenyl-2-benzyl dithiocarbamate（BDC） and 2-tert-butyl-2＇-benzyl trithiocarbonate （BTC）. The changes of solution colors and thermal effects in the processes of reactions have been analyzed in detail. The products are purified by column liquid chromatography and recrystallization,and characterized by ^1H NMR,IR,MS and elemental analysis. It demonstrates that the products are consistent with the expected. |
| |
| Keywords: | thioester synthesis benzyl carbon disulfide |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
