| Molecular Weight Distributions of Cotton Cellulose Treated with a Polycarboxylic Acid at Different pH |
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| 作者姓名： | 毛平平 CharlesQ.Yang |
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| 作者单位： | [1]CollegeofChemistry＆ChemicalEngineering,DonghuaUniversity,Shanghai200051 [2]DepartmentofTMI,UniversityofGeorgia,USA |
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| 基金项目： | The Project Sponsored by SRF for ROCS,SEM and EYTP of MOE |
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| 摘 要： | In last paper, the average molecular weight of a control cotton fabric and cotton fabrics treated with the polycarboxylic acid at different pH were measured. The result doesn‘t support the hypothesis that the pH of the finishing bath can affect the depolymerization of the finished cotton fabric. In order to understand more about it, the molecular weight distributions of the control and finished cotton fabrics were measured and the reason was fund. From the ratio and the molecular weight of the low molecular part one can see that the pH of the finishing bath can affect the depelymerization of the f‘mished cotton fabrics. The phenomenon that the average molecular weights of the cotton fabric crosslinked with BTCA at different pH are almost same is attributed to that the crosslinks are not broken completely when treated with 0.5 M NaOH solution at 50℃ for 144 h.
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| 关 键 词： | 棉纤维 分子重量分配 棉织物 酸处理 PH值 |
Molecular Weight Distributions of Cotton Cellulose Treated with a Polycarboxylic Acid at Different pH |
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| MAO Zhi-ping,Charles Q.Yang.Molecular Weight Distributions of Cotton Cellulose Treated with a Polycarboxylic Acid at Different pH[J].Journal of Donghua University,2004,21(5):19-21. |
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| Authors: | MAO Zhi-ping Charles QYang |
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| Institution: | 1. College of Chemistry & Chemical Engineering, Donghua University, Shanghai 200051
2. Department of TMI, University of Georgia, USA |
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| Abstract: | In last paper, the average molecular weight of a control cotton fabric and cotton fabrics treated with the polycarboxylic acid at different pH were measured. The result doesn't support the hypothesis that the pH of the finishing bath can affect the depolymerization of the finished cotton fabric. In order to understand more about it, the molecular weight distributions of the control and finished cotton fabrics were measured and the reason was fund. From the ratio and the molecular weight of the low molecular part one can see that the pH of the finishing bath can affect the depolymerization of the finished cotton fabrics. The phenomenon that the average molecular weights of the cotton fabric crosslinked with BTCA at different pH are almost same is attributed to that the crosslinks are not broken completely when treated with 0.5M NaOH solution at 50℃ for 144h. |
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| Keywords: | Cotton cellulose polycarboxylic acid depolymerization molecular weight distribution |
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