| 杯[4]芳烃磺酸钠的合成及其表征 |
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| 引用本文： | 周伟,刁国旺.杯[4]芳烃磺酸钠的合成及其表征[J].扬州大学学报(自然科学版),2003,6(2):16-20. |
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| 作者姓名： | 周伟 刁国旺 |
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| 作者单位： | 扬州大学化学化工学院,江苏扬州,225002 |
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| 基金项目： | 国家教育部留学回国人员启动基金资助项目，江苏省教委自然科学基金资助项目 (98KJB15 0 0 0 4 )，江苏省“青蓝工程”中青年学术带头人基金资助项目 |
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| 摘 要： | 采用三步法合成水溶性杯4]芳烃磺酸钠，先合成对叔丁基杯4]芳烃，再脱去叔丁基生成杯4]芳烃，最后台成杯4]芳烃磺酸钠．采用红外分光光度法和紫外可见分光光度法对产物进行了表征，并研究了杯4]芳烃磺酸钠的电化学特性．结果发现，杯4]芳烃磺酸钠在NaAc—HAc水溶液(pH＝4．0)中，当电位扫描范围为0．3～1．0V(vs SCE)之间时，可观察到一个对应于酚羟基氧化的不可逆峰，氧化峰电位在0．83V(vs SCE)左右，且随扫描速率不同而略有变化．
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| 关 键 词： | 杯[4]芳烃磺酸钠 合成 循环伏安法 |
| 文章编号： | 1007-824X(2003)02-0016-05 |
THE SYNTHESIS AND CHARACTERIZATION OF p-SULFONATED SODIUM OF CALIX[4]ARENE |
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| ZHOU Wei,DIAO Guo-wang.THE SYNTHESIS AND CHARACTERIZATION OF p-SULFONATED SODIUM OF CALIX[4]ARENE[J].Journal of Yangzhou University(Natural Science Edition),2003,6(2):16-20. |
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| Authors: | ZHOU Wei DIAO Guo-wang |
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| Institution: | ZHOU Wei DIAO Guo-wang * |
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| Abstract: | To synthesize the p sulfonated sodium of calixarene, the p butyl calixarene was synthesized first and calixarene was synthesized by the reaction of p butyl calixarene with anhydrous AlCl_3. Finally, the p sulfonated sodium of calixarene was obtained. The product was confirmed by FT-IR and UV-vis spectrometry. The electrochemical behavior of the p sulfonated sodium of calixarene was also studied. When the potential scans from 0.3 to 1.0 V (vs SCE), there is a irreversible electrochemical reaction-wave in NaAcHAc (pH=4.0) buffer solution. The peak potential locates at about 0.83 V (vs SCE), which is slightly affected by the scan rate. |
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| Keywords: | p sulfonated sodium of calix[4]arene synthesis cyclic voltammetry |
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