| 新型有机-无机杂化吡啶盐化合物的设计合成 |
| |
| 引用本文： | 李胜利,杨捷,郁建华,吴杰颖,田玉鹏.新型有机-无机杂化吡啶盐化合物的设计合成[J].安徽大学学报(自然科学版),2009,33(4). |
| |
| 作者姓名： | 李胜利 杨捷 郁建华 吴杰颖 田玉鹏 |
| |
| 作者单位： | 安徽大学化学,化工学院,安徽,合肥,230039 |
| |
| 基金项目： | 国家自然科学基金资助项目(50532030);;安徽省高等学校教学研究项目(01010175) |
| |
| 摘 要： | 设计合成3种非线性光学效应的新型有机-无机杂化物,即3种不对称D-π-A型取代苯乙烯基吡啶盐化合物,并运用常规方法进行表征.以实验证实,从分子设计,通过分子组装,是合成有机-无机杂化型化合物的有效方法,同时培养出其中一种化合物的高质量单晶,解析了晶体结构,分析和探讨了化合物的组成-结构-性质之间的关系.
|
| 关 键 词： | 有机-无机杂化 吡啶盐 合成 结构 |
Design and syntheses of novel organic-inorganic hybrid pyridinium compounds |
| |
| LI Sheng-li,YANG Jie,YU Jian-hua,WU Jie-ying,TIAN Yu-peng.Design and syntheses of novel organic-inorganic hybrid pyridinium compounds[J].Journal of Anhui University(Natural Sciences),2009,33(4). |
| |
| Authors: | LI Sheng-li YANG Jie YU Jian-hua WU Jie-ying TIAN Yu-peng |
| |
| Institution: | College of Chemistry and Chemical Engineering;Anhui University;Hefei 230039;China |
| |
| Abstract: | The materials of pyridinium compounds with striking optical nonlinearities were briefly discussed in the thesis.The research aim was mainly focused on the design and syntheses of organic-inorganic hybrid complexes.Three organic-inorganic hybrid coordination compounds,which contained the ambidentate thiocyanate(SCN-) ligand,metal ion and pyridinium deriver,had been synthesized by self-assembly,respectively.They were characterized by modern analysis methods such as IR,UV,Fluorescent spectra,Element analysis a... |
| |
| Keywords: | organic-inorganic hybrid pyridinium synthesis structure |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
