| 两种新型二茂铁氮氧自由基化合物的合成和晶体结构 |
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| 引用本文： | 邱潇,吕遐,蓝闽波.两种新型二茂铁氮氧自由基化合物的合成和晶体结构[J].上海应用技术学院学报,2013,13(4):263-268. |
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| 作者姓名： | 邱潇 吕遐 蓝闽波 |
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| 作者单位： | [1]上海应用技术学院化学与环境工程学院,上海201418 [2]上海市食品药品监督管理局徐汇分局,上海200030 [3]华东理工大学,上海200237 |
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| 基金项目： | 上海市优秀青年教师基金资助项目（yyy11022）;上海应用技术学院引进人才基金资助项目（YJ2011-47） |
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| 摘 要： | 设计并合成两种二茂铁氮氧自由基化合物（4．二茂铁丙酰胺基-2，2，6，6-四甲基哌啶氮氧自由基和4-二茂铁丙烯酰胺基-2，2，6，6-四甲基哌啶氮氧自由基），并利用单晶X射线衍射研究了其晶体结构特征。结果发现尽管两者的整体构型有明显区别，但各化合物的二茂铁基团以及2，2，6，6-四甲基哌啶氮氧自由基基团的结构却相差不大。
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| 关 键 词： | 二茂铁 氮氧自由基 合成 晶体结构 |
Synthesis and Crystal Structure of Two Novel Ferrocenyl Nitroxides Compounds |
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| QIU Xiao,LU Xia and LAN Min-bo.Synthesis and Crystal Structure of Two Novel Ferrocenyl Nitroxides Compounds[J].Journal of Shanghai Institute of Technology: Natural Science,2013,13(4):263-268. |
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| Authors: | QIU Xiao LU Xia and LAN Min-bo |
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| Institution: | 1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, 2. Shanghai Municipal Food and Drug Administration Xuhui Office, Shanghai 200030, China; 3. East China University of Science and Technology, Shanghai 200237, China) |
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| Abstract: | Two ferrocenyl nitroxide compounds, 4- （ferrocene propionamide）-2, 2, 6, 6-tetramethyl pi- peridin-oxyl radical and 4- （ferrocene acrylamide）-2, 2, 6, 6-tetramethyl piperidin-oxyl radical were de- signed and synthesized. Structure characteristics of single-crystal were studied by utilizing the single- crystal X-ray diffraction. The results indicated that two compounds had similar ferrocene and TEMPO moieties in spite of their distinct overall configuration difference. |
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| Keywords: | ferrcene nitroxide synthesis crystal structure |
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