Dechlorination of 2,4-dichlorophenol by nickel nanoparticles under the acidic conditions |
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Authors: | Li Feng XiaoPeng Ge Yi Li DongSheng Wang HongXiao Tang |
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Institution: | (1) Institute of Metal Research, Chinese Academy of Sciences, 110016 Shenyang, P R China;(2) Shenyang National Laboratory for Materials Science, 110016 Shenyang, P R China |
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Abstract: | Metal nanoparticles are effective for remediation of contamination with a range of compounds including chlorinated organics.
However, the sorption process of the passivation oxide layers on the metal nanoparticle surfaces may result in incomplete
degradation of contaminants. This phenomenon can be prevented by an acidic washing procedure or reaction in an acidic medium.
In this paper, nickel nanoparticles manufactured via the carbonyl powder process were analyzed using scanning electron microscopy,
transmission electron microscopy, X-ray diffraction and energy-dispersive X-ray spectroscopy. The sorption and degradation
of 2,4-dichlorophenol (2,4-DCP) by nickel nanoparticles under acidic conditions was then investigated. Transmission electron
microscopy and XRD results showed that the nickel nanoparticles range in size from 10 to 20 nm, and a thin passivation layer
of NiO is present on the surface. This oxide layer can be removed by pretreatment washing with acidic solutions. It was indicated
that dechlorination was the key reaction pathway for degradation of 2,4-DCP by nickel nanoparticles under acidic conditions.
The main degradation products were 4-Chlorophenol, 2-Chlorophenol, and Phenol, and among these, Phenol was dominant. The acidic
medium promoted degradation by providing an appropriate pH, and H+ may be involved in the reaction. Dechlorination of 2,4-DCP by nickel nanoparticles under the acidic condition follows the
second order kinetic model, and the rate constants at 298, 306, 316 K are 0.02, 0.2 and 0.3 (g L h)−1, respectively. |
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Keywords: | nickel nanoparticles 2 4-dichiorophenol dechlorination sorption acid conditions |
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