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Recent developments in homobimetallic reagents and catalysts for organic synthesis
Authors:Wei Wu  DeLiang Gu  ShiMeng Wang  YingNan Ning  GuoLiang Mao
Institution:Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
Abstract:Organometallics are a family of useful organic chemicals because they play important roles in organic synthesis as reagents and as catalysts. They can be classified according to the number of metals they contain. Bimetallic compounds are important organometallics and they are either homobimetallic or heterobimetallic depending on whether the two metals are the same or different. In this paper, we focus on homobimetallic compounds. Homobimetallic compounds are generally used as dianions to react with electrophiles in organic synthesis. Recently, homobimetallics have also been used as catalysts in organic reactions such as in asymmetric reactions.
Keywords:homobimetallics  reagent  catalyst  synthesis  application
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