| CuI-Cu_2O-P_2O_5-B_2O_3四元系铜快离子玻璃的形成区和电导 |
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| 引用本文： | 李光远,蔡坚毅.CuI-Cu_2O-P_2O_5-B_2O_3四元系铜快离子玻璃的形成区和电导[J].华东理工大学学报(自然科学版),1987(1). |
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| 作者姓名： | 李光远 蔡坚毅 |
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| 作者单位： | 华东化工学院物理系，华东化工学院物810班 毕业生 |
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| 摘 要： | 本文研究了0.30CuI0.70(Cu_2OP_2O_5B_2O_3)四元系玻璃的形成区,测量了此系玻璃的离子电导率和玻璃的转变温度,并从结构和化学键的观点上解释了玻璃电导率随组成的变化。四元系是由相应的三元系CuI-Cu_2O-P_2O_5中引入B_2O_3而得到的。实验表明,四元系能够得到比相应的三元系好的离子电导率和热稳定性。
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| 关 键 词： | 铜固体电解质 四元系 玻璃形成区 电导率 热稳定性 玻璃 |
A study on the glass forming region and the copper ionic conduction of a quaternary system--CuI-Cu_2O-P_2O_5-B_2O_3 system |
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| Li Guangyuan,Cai Jianyi.A study on the glass forming region and the copper ionic conduction of a quaternary system--CuI-Cu_2O-P_2O_5-B_2O_3 system[J].Journal of East China University of Science and Technology,1987(1). |
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| Authors: | Li Guangyuan Cai Jianyi |
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| Institution: | Li Guangyuan;Cai Jianyi Department of Physics |
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| Abstract: | The glass forming region of a quaternary system, 0. 30 CuI 0. 70(Cu_2OP_2O_5B_2O_3),was studied, the conductivity and the glass transition temperature of this system weremeasured. In the light of glass structure and chemical bonds, the variations of conductivitywith composition and transition temperature with B_2O_3 content were interpreted. Experimental results show that the quaternary system has better conductivity andthermal stability than that of the original ternary system, CuI-Cu_2O-P_2O_5, from whichthe quaternary system was derived with the introduction of B_2O_3. |
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| Keywords: | copper electrolyte quaternary system glass region conductivity thermal stability glass |
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