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铁铜复合催化混凝剂的制备及应用
引用本文:张永利.铁铜复合催化混凝剂的制备及应用[J].中山大学学报(自然科学版),2009,48(3).
作者姓名:张永利
作者单位:韩山师范学院化学系生态环境研究所,广东,潮州,521041
基金项目:广东省教育厅2008年度高校学科建设专项基金,广东省潮州市科技局资助项目 
摘    要: 催化湿式氧化法处理COD为2.458 mg/L的印染废水,以废水COD去除率、脱色率、出水pH评价药剂对废水的处理效果。为了提高实验药剂的性能指标,对实验前期所筛选的Fe、Cu催化剂,研制了复合型药剂Fe1Cu1(即m(Fe 2+)∶m(Cu2+)=1∶1),并对其降解印染废水的机理及应用进行研究。实验表明:Fe1Cu1起到了催化和混凝的双重作用;废水的处理效果随药剂量的增加及反应温度的升高而增强;实验确定适宜的Fe1Cu1投加量为150 mg/L,而反应温度为210 ℃。处理后废水的可生化性大幅度提高,BOD5/COD值由初始的0.016提高到0.420。

关 键 词:Fe  Cu  湿式氧化  印染  废水  催化剂  混凝剂
收稿时间:2008-08-30;

Preparation and Application of Fe-Cu Catalyst Flocculant
ZHANG Yongli.Preparation and Application of Fe-Cu Catalyst Flocculant[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2009,48(3).
Authors:ZHANG Yongli
Institution:(Institute of Eco Environment, Department of Chemistry,Hanshan Normal University, Chaozhou 521041, China)
Abstract:Printing and dyeing wastewater with COD content up to 2.458 mg/L was treated using catalytic wet oxidation technology.The performance of the wastewater treatment was evaluated by COD removal rates, decolorization rates and effluent pH. Based on the previous research using Fe and Cu separately as catalysts, a new compound medicament Fe1Cu1 was developed. The degradation mechanism of this new medicament for printing and dyeing wastewater and its application were researched. The experimental results indicated that Fe1Cu1 exhibited both catalyst and flocculant functions; the performance of printing and dyeing wastewater treatment increased with the increase in medicament dosage and reaction temperature;the optimal Fe1Cu1 dosage is 150 mg/L, and reaction temperature is 210 ℃. The biochemical property of effluent is significantly improved with the increase of BOD5/COD value from 0.016 to 0.420.
Keywords:Fe  Cu
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