| 过渡金属金刚烷甲酸配合物的合成和表征 |
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| 引用本文： | 王艳芳,赵国良.过渡金属金刚烷甲酸配合物的合成和表征[J].浙江师范大学学报(自然科学版),2008,31(3):308-311. |
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| 作者姓名： | 王艳芳 赵国良 |
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| 作者单位： | 1. 宁波天一职业技术学院,浙江,宁波,315000
2. 浙江师范大学化学与生命科学学院,浙江,金华321004 |
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| 摘 要： | 在沸水体系中，由过渡金属醋酸盐与金刚烷甲酸（Hadam，C10H15COOH）反应，合成了6种配合物M（adam）2·nH2O（M=Mn，n=2；M=Co，n=6；M=Ni，n=3．5；M=Cu，n=1；M=Zn，n=0；M=Cd，n=0），并用元素分析、摩尔电导、红外光谱和热分析方法对配合物进行了表征。结果表明，中心金属离子M^2＋与2个配体（adam）羧基中的4个氧原子以双齿形式发生配位，形成了分子配合物，配位数为4（其中铜有1个配位水，其配位数为5）。
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| 关 键 词： | 金刚烷甲酸 过渡金属 配合物 合成 表征 |
Synthesis and characterization of transition metal complexes with adamantanecarboxylic acid |
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| WANG Yanfang,ZHAO Guoliang.Synthesis and characterization of transition metal complexes with adamantanecarboxylic acid[J].Journal of Zhejiang Normal University Natural Sciences,2008,31(3):308-311. |
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| Authors: | WANG Yanfang ZHAO Guoliang |
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| Institution: | WANG Yanfang , ZHAO Guoliang ( 1. Ningbo Tianyi College of Occupation and Technology, Ningbo Zhejiang 315100, China; 2. College of Chemistry and Life Science, Zhejiang Normal University, Jinhua Zhefiang 321004, China) |
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| Abstract: | Six solid complexes with the stoichiometric formulae M （ adam）2 ·nH2O（M = Mn, n = 2; M = Co, n = 6; M = Ni, n = 3.5; M = Cu, n = 1;M = Zn, n = 0; M = Cd, n = 0; Hadam = adamantancecarboxylic acid, C10H15COOH） had been synthesized by reacting transition matal acetate with adamantanecarboxylic acid in boling water system, and characterized by elemental anlysis, molar conductance, IR spectra and TG-DTG. Every central ion M （Ⅱ） in the complexes coordinates with four atoms of the two adamantanecarboxylato groups at the form of bidentate. Their coordination numbers were four, but coordination number of the copper（Ⅱ） complex was five. |
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| Keywords: | adamantancecarboxylic acid transition metal complex synthesis characterization |
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