| 用飞行时间质谱仪对HMX热分解机理的研究 |
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| 引用本文： | 景中兴,白木兰.用飞行时间质谱仪对HMX热分解机理的研究[J].北京理工大学学报,1988(3). |
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| 作者姓名： | 景中兴 白木兰 |
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| 作者单位： | 北京工业学院化学工程系
(景中兴)，北京工业学院化学工程系(白木兰) |
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| 摘 要： | 本文的主要工作是用ZHP-6型飞行时间质谱仪研究了环四亚甲基四硝胺(HMX)的热分解,并采用专用的热分解反应装置较好的排除了HMX升华气体产物对其热分解产物的影响。从而取得了在不同温度下HMX热分解产物的图谱,并对HMX热分解的反应机理提出了新的观点。
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| 关 键 词： | 飞行时间质谱仪 热分解 反应机理 质谱图 奥克托金 |
STUDY OF THE MECHANISM OF THERMAL DECOMPOSITION OF CYCLOTETRAME- THYLENE TETRANITRAMINE BY USING TIME OF FLIGHT MASS SPECTROMETER |
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| Jing Zhongxing Bai Mulan.STUDY OF THE MECHANISM OF THERMAL DECOMPOSITION OF CYCLOTETRAME- THYLENE TETRANITRAMINE BY USING TIME OF FLIGHT MASS SPECTROMETER[J].Journal of Beijing Institute of Technology(Natural Science Edition),1988(3). |
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| Authors: | Jing Zhongxing Bai Mulan |
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| Institution: | Department of Chemical Engineering |
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| Abstract: | Studies on the thermal decomposition of cyciotetrametylone tetrani-tramine(HMX) were preformed by use time of flight mass spectrometer. In order to prevent the sublimated HMX entering the ion source, a decomposition reactor was applied. The mass spectrums of decomposition of HMX with different temperatures were obtained. A new view point of mechanism on the thermal decomposition of HMX was gived. |
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| Keywords: | time of flight mass spectrometer thermal decomposi t ion mechanism reaction mass spectrometer HMX |
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