| 卟啉,酞菁化合物荧光量子产率的溶剂效应 |
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| 引用本文： | 陈艳丽.卟啉,酞菁化合物荧光量子产率的溶剂效应[J].山东师范大学学报(自然科学版),1997,12(2):167-169. |
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| 作者姓名： | 陈艳丽 |
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| 作者单位： | 济南联合大学化学系 |
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| 摘 要： | 测定了大环共轭体系卟啉和酞菁在１１种溶剂中的荧光光谱，发现体系的最大荧光发射波长λｍａｘ受溶剂的影响较小，而荧光量子产率受溶剂的影响较大，在非质子性溶剂中，两种化合物的荧光量子产率和溶剂极性参数间存在一定的线性关系，在质子性溶质中，化合物的荧光量子产率相对于在非质子性溶剂中降低很多，这可能是有氢键形成的缘故。
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| 关 键 词： | 卟啉 酞菁 溶剂效应 荧光量子产率 |
SOLVENTS EFFECTS ON THE FLUORESCENCE EFFICIENCY OF PORPHYRIN AND PHTHALOCYANINE |
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| Chen Yanli.SOLVENTS EFFECTS ON THE FLUORESCENCE EFFICIENCY OF PORPHYRIN AND PHTHALOCYANINE[J].Journal of Shandong Normal University(Natural Science),1997,12(2):167-169. |
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| Authors: | Chen Yanli |
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| Abstract: | The fluorescence spectra of porphyrin and phthalocyanine in eleven solvents were determined.It was found that the maximum wavelength of the fluorescence emission was barely affected by the solvent,but the fluorescence quantum yield of the porpyrin and phthalocyanine was affected by the solvent greatly.It varied linearly with the polarity parameters of the solvents.The fluorescence quantum yield decreased greatly in protonic solvent compared with that in nonprotonic solvents.This may be ascribed to the formation of hydrogen bonds between solvent and porphyrin or phthalocyanine. |
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| Keywords: | porphyrin phthalocyanine solvent effect fluorescence efficiency |
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