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Synthesis of a Novel UV-Curable Diluent Benzyl Glycidyl Ether Acrylate and Its Application |
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| Authors: | HUANG Bi-wu WENG Zi-xiang ZHENG Xue-lin JIANG An-Kun LIU Shi-min |
| Institution: | 1. School of Material Science and Engineering, Nanchang University, Nanchang 330031, China 2. Department of Chemistry, Nanchang University, Nanchang 330031, China 3. Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China |
| Abstract: | A novel UV-curable diluent benzyl glycidyl ether acrylate (BGEA) was synthesized by utilizing benzyl glycidyl ether (BGE) and acrylic acid (AA) as starting materials,N,N-dim ethylbenzylamine as catalyst and p-hydroxyanisole as inhibitor.The optimum synthetic conditions were that the concentration of N,Ndimethylbenzylamine was 0.90％ of reactants by weight,the concentration of p-hydroxyanisole was 0.20％ of reactants by weight the reaction temperature was 90-100℃,and the molar ratio of BGE to AA was 1.00:1.10.The experiment shows that BGEA is a kind of good diluent.The mechanical properties of the UV-cured films with BGEA as diluent to prepare UV-curing coating were superior to that of the UV-cured films with butyl acrylate as diluent to prepare UV-curing coating. |
| Keywords: | benzyl glycidyl ether acrylate (BGEA) synthesis acrylic acid UV-curable diluent film |
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