2,2-二{4-二[2,3(3,4)-二氰基苯氧基]苯基}丙烷的合成、表征与性质研究

以二甲基亚砜为溶剂、氢氧化锂为催化剂,在室温下,将双酚A分别与3-硝基邻苯二腈、4-硝基邻苯二腈反应合成了两种2,2-二{4-二2,3(3,4)-二氰基苯氧基]苯基}丙烷化合物,产物经~1HNMR,IR,HPLC-MS进行了表征确证,讨论了反应时间及催化剂用量对产率的影响,并对两种产物的紫外-可见光谱及荧光光谱进行研究.

Synthesis,Characterization and Properties of 2,2-di{4-di[2,3(3,4)-Dicyanophenoxy]Phenyl}Propane

While Bisphenol A and 3-nitro,4-nitro phthalic nitrile were introduced as raw material,lithium hydroxide was selected as catalyst,2,2-di4-di(2,3-dicyanophenoxy)phenyl]propane and 2,2-di4-di(3,4-dicyanophenoxy)phenyl]propane compounds were synthesized in the dimethyl sulfoxide at room temperature,the target compounds were determined by ~1HNMR,IR and HPLC-MS,the effects of reaction time and catalyst dosage on yield were discussed,the UV-vis spectrum and fluorescence spectrum of target products were studied preliminarily.