| 灭蝇胺的合成与应用研究 |
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| 引用本文： | 陈静波,张玉顺,刘宇,梁佶轩,孙竹先,刘娜娜,古昆.灭蝇胺的合成与应用研究[J].云南大学学报(自然科学版),2008,30(4):392-395. |
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| 作者姓名： | 陈静波 张玉顺 刘宇 梁佶轩 孙竹先 刘娜娜 古昆 |
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| 作者单位： | 1. 云南大学,教育部自然资源药物化学重点实验室,云南,昆明,650091
2. 云南省第一人民医院,云南,昆明,650032 |
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| 基金项目： | 云南省自然科学基金
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昆明市科委重点科技计划项目 |
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| 摘 要： | 灭蝇胺是防治双翅目昆虫病虫害的高效、低毒生态农药,以三聚氯氰为原料,经环丙氨代和氨代一勺烩反应得中间体(6-氯-2-环丙氨基-4-氨基-1,3,5-三嗪),再加压氨代得灭蝇胺.两步反应总收率72.1%.
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| 关 键 词： | 灭蝇胺 N-环丙基-1 3 5-三嗪-2 4 6-三胺 生态农药 合成 应用 |
Study on the synthesis of cyromazine |
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| CHEN Jing-bo,ZHANG Yu-shun,LIU Yu,LIANG Ju-xuan,SUN Zhu-xian,LIU Na-na,GU Kun.Study on the synthesis of cyromazine[J].Journal of Yunnan University(Natural Sciences),2008,30(4):392-395. |
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| Authors: | CHEN Jing-bo ZHANG Yu-shun LIU Yu LIANG Ju-xuan SUN Zhu-xian LIU Na-na GU Kun |
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| Institution: | 1. Key Laboratory of Medicinal Chemistry for Natural Resource(Yunnan University), Ministry of Education, Kunming 650091, China;2. The First People Hospital of Yunnan Province, Kunming 650032, China |
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| Abstract: | Cyromazine,an environmental benign pesticide with high potency and low toxicity,was used for prevention and cure of plant diseases and insect pests resulted from dipsters.One-pot reaction,with 2,4,6-trichloro-1,3,5-triazine as raw material,of cyclopropylamination and amination provided the intermediate(6-chloro-2-cyclopropylamino-4-amino-1,3,5-triazine),another amination under pressure yielded the target compound.The total yield was 72.1%. |
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| Keywords: | cyromazine N-cyclopropyl-1 3 5-triazine-2 4 6-triamine environmental benign pesticide synthesis application |
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