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高硫煤的电化学净化对煤质的影响
引用本文:李登新,高晋生,孟繁玲,宋吉勇,陈丽慧.高硫煤的电化学净化对煤质的影响[J].华东理工大学学报(自然科学版),2001,27(2):169-172,194.
作者姓名:李登新  高晋生  孟繁玲  宋吉勇  陈丽慧
作者单位:1. 华东理工大学资源环境学院,
2. 山东科技大学,
基金项目:中国科学院山西煤炭化学研究所煤炭转化国家重点实验室开放项目
摘    要:研究了煤在酸性或碱性条件下电化学净化对煤质的影响。结果表明,在适当的电解条件下电化学脱硫对煤质影响不大,但若提高有机硫的脱硫率,则对煤质影响明显。将处理过的煤用四氢呋喃(THF)萃取,并将THF可溶部分进一步用环烷萃取,完全宿煤THF可溶物和环乙烷不溶物含量高于原煤。

关 键 词:脱硫  煤质  电化学  萃取  高硫煤
文章编号:1006-3080(2001)02-0169-04

Changes of Coal Behavior in Coal Electrolytic Desulfurization
LI Deng-xin,GAO Jin-sheng,MENG Fan-ling,SHONG Ji-yong,CHEN Li-hui.Changes of Coal Behavior in Coal Electrolytic Desulfurization[J].Journal of East China University of Science and Technology,2001,27(2):169-172,194.
Authors:LI Deng-xin  GAO Jin-sheng  MENG Fan-ling  SHONG Ji-yong  CHEN Li-hui
Abstract:Electrolytic cleaning of coal was carried out in acidic and alkaline electrolytes respectivity. The effects of electrolysis on the properties of coal were studied. It is found that the calorific value, elemental composition, combustion and pyrolysis behavior of electrolyzed coal don't vary, but the surface oxygen on coal increases. When coal is oxidized deeply and the ratio of organic sulfur removal is higher, the calorific value of the coal become lower because of increase of oxygen and decrease of carbon in coal. Coals after electrolysis were extracted with tetrahydrofuran (THF), and the THF soluble fraction was extracted with cyclohexane. The THF soluble fraction and cyclohexane insoluble fraction of electrolyzed Beisu coal are found to be much higher than that of the original coals.
Keywords:desulfurization  properties of coal  electrolysis  extraction
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