| 三维网状结构钴配合物的合成与晶体结构表征 |
| |
| 引用本文： | 赵增兵,台夕市.三维网状结构钴配合物的合成与晶体结构表征[J].潍坊学院学报,2009,9(6):84-86. |
| |
| 作者姓名： | 赵增兵 台夕市 |
| |
| 作者单位： | 1. 青海师范大学,青海,西宁,810008;潍坊学院,山东,潍坊,261061
2. 潍坊学院,山东,潍坊,261061 |
| |
| 基金项目： | 国家自然科学基金，山东省自然科学基金，潍坊市科技发展计划 |
| |
| 摘 要： | 以1,5-萘二磺酸钠为原料合成了一种钴的配合物,用X-单晶衍射仪测定其晶体结构。该配合物为单斜晶系,晶胞为P2（1）/c,晶胞参数：a=13.2216（18）,b=6.67561（10）,c=9.6957（15）,β=92.0970（10）,°V=855.2（2）3,Z=2,Mr=453.29,Dc=1.760 g/cm3,T=289（2）K,F（000）=466,μ（MoKa）=1.307 mm-1,R=0.0275,wR=0.0686,配合物分子通过分子内和分子间氢键形成三维网状结构。
|
| 关 键 词： | 1 5-萘二磺酸钠 钴配合物 合成 晶体结构 |
Synthesis and Cystal Stucture Characterization of Cobalt Complex with Three-dimensional Framework |
| |
| ZHAO Zeng-bing,TAI Xi-shi.Synthesis and Cystal Stucture Characterization of Cobalt Complex with Three-dimensional Framework[J].Journal of Weifang University,2009,9(6):84-86. |
| |
| Authors: | ZHAO Zeng-bing TAI Xi-shi |
| |
| Institution: | ZHAO Zeng-bing,TAI Xi-shi (1.Qinghai Normal University,Xining 810008,China;2.Weifang University,Weifang 261061,China) |
| |
| Abstract: | A cobalt complex was synthesized using 1,5-naphthalenedisufonic acid disodium salt as starting materials by solvent evaporation approach,and was determined the crystal structure by X-ray single crystal diffraction.The results showed that the compound was monoclinic,with P2（1）/c,a = 13.2216（18）,b = 6.6756（10）,c = 9.6957（15）,β = 92.0970（10） °,V = 855.2（2）3,Z = 2,M r= 453.29,Dc = 1.760 g/cm3,T = 289（2）K,F（000） = 466,μ（MoKa） = 1.307 cm-1,R = 0.0275 and Wr = 0.0686.The complex formed three-dimensional framework through intermolecular and intramolecular hydrogen bonds. |
| |
| Keywords: | 1 5-naphthalenedisufonic acid disodium salt cobalt complex synthesis crystal structure |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
