| Low-heating solid state synthetic reactions of cyclopeantadienyl organolanthanide complexes |
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| 作者姓名： | ZHUMing LiYanrong LUOJun ZHOUZigeng |
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| 作者单位： | DepartmentofChemistry,FudanUniversity,Shanghai200433,China |
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| 基金项目： | 国家自然科学基金，教育部优秀青年教师资助计划 |
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| 摘 要： | A novel and simple one-step,solid state reaction of multicomponent systems has been developed to synthesize cyclopentadienyl-containing organolanthanide complexes,in which the effects of the coordinated solvent molecules and the nature of the reactants were also studied.We also studied the solid state decomposition reaction of Cp2 YbPz(HPz),and the formation of CpYb(Pz)2|2 may indicate that the constrained environment in solid state can lead to a novel chemical transformation,with product selectivity possibly different from that in the liquid phase.
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| 关 键 词： | 低热固态反应 合成 茂基有机镧系络合物 绿色化学 环戊二烯 [CpYb（Pz）2｜2 Cp2YbPz（HPz） 镱配合物 |
Low-heating solid state synthetic reactions of cyclopeantadienyl organolanthanide complexes |
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| ZHUMing LiYanrong LUOJun ZHOUZigeng.Low-heating solid state synthetic reactions of cyclopeantadienyl organolanthanide complexes[J].Chinese Science Bulletin,2003,48(19):2041-2043. |
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| Authors: | Ming Zhu Yanrong Li Jun Luo Xigeng Zhou |
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| Institution: | (1) Department of Chemistry, Fudan University, 200433 Shanghai, China;(2) State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 200032 Shanghai, China |
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| Abstract: | A novel and simple one-step, solid state reaction of multicomponent systems has been developed to synthesize cyclopentadienyl-containing organolanthanide complexes, in which the effects of the coordinated solvent molecules and the nature of the reactants were also studied. We also studied the solid state decomposition reaction of Cp2YbPz(HPz), and the formation of CpYb(Pz)2]2 may indicate that the constrained environment in solid state can lead to a novel chemical transformation, with product selectivity possibly different from that in the liquid phase. |
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| Keywords: | low-heating solid state reaction organolanthanide complex green chemistry cyclopentadienyl synthesis |
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