| 四(对-硝基)苯基卟啉配合物的合成和光谱性质 |
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| 引用本文： | 师同顺,郑国栋,付振生,曹锡章,王翠英.四(对-硝基)苯基卟啉配合物的合成和光谱性质[J].吉林大学学报(理学版),1992(3). |
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| 作者姓名： | 师同顺 郑国栋 付振生 曹锡章 王翠英 |
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| 作者单位： | 吉林大学化学系 长春
(师同顺，郑国栋，付振生，曹锡章)，沈阳建筑工程学院 沈阳(王翠英) |
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| 摘 要： | 用改进的Aider方法合成了四(对-硝基)苯基卟啉Cr(Ⅲ),Mn(Ⅲ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ)配合物。用元素分析、紫外可见光谱、红外光谱、激光拉曼光谱、X射线光电子能谱等方法表征了配合物的组成和结构。用紫外可见光谱和红外差谱研究了一氧化氮配合物的光谱性质。
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| 关 键 词： | 卟啉 配合物 合成 一氧化氮 |
Studies on Preparation and Spectroscopic Properties of Tetra-(p-nitrophenyl)Porphyrinatometal Complexes |
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| Shi Tongshun,Zheng Guodong,Fu Zhensheng and Cao Xizhang.Studies on Preparation and Spectroscopic Properties of Tetra-(p-nitrophenyl)Porphyrinatometal Complexes[J].Journal of Jilin University: Sci Ed,1992(3). |
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| Authors: | Shi Tongshun Zheng Guodong Fu Zhensheng and Cao Xizhang |
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| Abstract: | The improved Adler's method was used to prepare the complexes of tetra-(p-nitro-phenyl) porphyrinatometal. The structures and compositions of the complexes were determined by elemental ananlysis, UV, IR, Raman and XPS. Adducts of the complexes with nitric oxide were studied by UV-VIS spectra and infrared subtracted spectra. |
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| Keywords: | porphyrin complex syntheses nitric oxide |
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