| 苯酚双环戊二烯环氧树脂的合成与固化性能研究 |
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| 引用本文： | 于萌,王涛,张立新,万平玉.苯酚双环戊二烯环氧树脂的合成与固化性能研究[J].北京化工大学学报(自然科学版),2006,33(3):89-93. |
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| 作者姓名： | 于萌 王涛 张立新 万平玉 |
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| 作者单位： | 北京化工大学理学院,北京,100029;北京化工大学理学院,北京,100029;北京化工大学理学院,北京,100029;北京化工大学理学院,北京,100029 |
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| 基金项目： | 北京化工大学校科研和教改项目 |
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| 摘 要： | 以苯酚和双环戊二烯为原料，通过Friedel-Crafts反应，合成了双环戊二烯酚树脂(DPR)。用环氧氯丙烷对该树脂进行环氧化，还制得了含有双环戊二烯结构的环氧树脂(DER)。系统地考察了合成反应的条件，所得环氧树脂的最大环氧值为0.31~0.35，有机氯含量小于0.02mol/100g。用红外光谱考察了以甲基六氢苯酐(MeHHPA)为固化剂时该树脂在180 ℃时的固化速度，固化3.5 h时, 环氧开环的转化率大于92%。DSC的分析表明DER与双酚A环氧树脂E51混合(质量比为1:1)，固化树脂的玻璃化转变温度Tg比E51固化树脂的玻璃化转变温度高15 ℃。
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| 关 键 词： | 双环戊二烯酚树脂 双环戊二烯环氧树脂 合成 固化 |
| 收稿时间： | 2005-10-31 |
| 修稿时间： | 2005年10月31日 |
Synthesis and curing of dicyclopentadiene-containing epoxy resin |
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| YU Meng,WANG-tao,ZHANG Li-xin,WAN Ping-yu.Synthesis and curing of dicyclopentadiene-containing epoxy resin[J].Journal of Beijing University of Chemical Technology,2006,33(3):89-93. |
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| Authors: | YU Meng WANG-tao ZHANG Li-xin WAN Ping-yu |
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| Institution: | College of Science, Beijing University of Chemical Technology, Beijing100029, China |
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| Abstract: | Using phenol and dicyclopentadiene (DCPD) as raw materials, DCPD-containing phenolic resin (DPR) was prepared via Friedel-Crafts alkylation and DCPD-containing epoxy resin (DER) was prepared via epoxidation of DPR with epichlorohydrin. Their reaction conditions and mode were optimized. The epoxy value of DER is 0.31~0.35. The content of organic chloride is less 0.02 mol/100g. MeHHPA as curing agent, the curing was carried out and the rate of curing was evaluated by FT-IR. When the curing temperature is 180 ℃, the yield of the opening of epoxy group was more than 92% after 3.5 h. DSC analyses found that the Tg of cured epoxy resin DER+E51(1:1) is higher than that of resin E51. |
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| Keywords: | DCPD-containing phenolic resin DCPD-containing epoxy resin synthesis curing |
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