Hollow bismuth ferrite combined graphene as advanced anode material for sodium-ion batteries

Hollow bismuth ferrite nanofibers were fabricated via simple electrospinning process,and the storage properties of Na-ions were investigated by atmospheric pressure X-ray photoelectron spectrum(APXPS) and Synchrotron Radiation.The results show that the hollow bismuth ferrite nanotubes demonstrate impressive sodium storage properties and good cycling stability that the specific capacity can exceed 500 mA h g~(-1) and the cycle number reaches several hundred cycles.The graphene-coated bismuth ferrite nanotubes exhibit a specific capacity of600 mAhg~(-1)and a 89% capacity retention after 200 cycles.The present strategy can be a significant step to fabricate hollow perovskite oxides and serve as sodium ion batteries.     

热处理温度对La0.75Sr0.25Mn0.95Δ0.05O3中B位空位含量的影响

为了解决在空气条件下热处理温度和次数对含有B位空位锰氧化物La0.75Sr0.25Mn0.95Δ0.05O3中氧含量影响的物理问题,采用改进的溶胶凝胶法,成功制备了名义成分为La0.75Sr0.25Mn0.95Δ0.05O3的钙钛矿锰氧化物材料,先后对样品在973,107 3,127 3,147 3K进行了4次热处理,对其结构和磁性进行了研究.结果表明,经973K热处理后样品晶粒表面明显缺氧,导致其中存有碳元素;经过后3次热处理,样品的氧含量逐渐增加,从正分到过剩.结合晶体缺陷热平衡理论,氧含量过剩时,实际上形成了B位含有空位的AB1-Δ-zO3型钙钛矿结构.     

钙钛矿型LaMnO3+λ的结构及对二甲苯氧化的活性研究

合成了系列稀土复合氧化物LaMnO3＋λ，并对其进行了XRD测试，用TREOR程序进行晶胞参数的计算并对二甲苯氧化的活性进行了测定。初步解释了其结构与性能的关系．     

Giant magneto resistance and temperature coefficient of resistance in Sm0.55Sr0.30Ag0.15MnO3 perovskite

Silver ions substituted samarium strontium manganite (Sm0.55Sr0.30Ag0.15MnO3) pervoskite was synthesized by using respective oxides in stoichiometric ratio through solid state reaction. The as-prepared sample was characterized by various analytical techniques to confirm its formation and understand the effect of monovalent silver ions in pervoskite lattice. X-ray diffraction pattern confirms the single phase formation while grain morphology in SEM image indicates good connectivity among the grains. The enhancement in metal to insulator transition temperature shows quenched disorder and magnetoresistance phenomena. The magnetoresistance (MR) and temperature coefficient of resistance (TCR) emerge from grain growth factor and homogeneity induced by Ag+ ions in the lattice. The reduction in hysteresis loss resulted from antiferromagnetic - ferromagnetic (TN) and ferromagnetic - paramagnetic (Tc) transitions reveals the removal of disorder in perovskite lattice by Ag+ ions substitution. This increases the magnetic moment across distinct ions on the applying magnetic field. The rise in MR% (~99%) with silver doping emerging from smooth spin tunneling of the grains across the boundary and suppression of the disordered magnetic fluctuations with increase in magnetic field has been reported. The present compound exhibits the first order nature of magnetism and observed first time the highest value of TCR ~ 95%.     

Ag掺杂类钙钛矿Ca(Mn_2Cu_1)Mn_4O_(12)的电磁性能

采用固相反应法制备了系列Ca(Mn2Cu1)Mn4O12/mAg2O多晶类钙钛矿锰氧化物。X射线衍射表明,m≤0.3的样品呈比较纯净的类钙钛矿相,而m>0.3的样品,是由类钙钛矿和金属Ag相组成的复合物。所有样品呈现半导体导电性质,电阻率低于未掺杂的Ca(Mn2Cu1)Mn4O12样品。居里温度测量表明,随着Ag掺杂量的增加,样品的居里温度逐渐升高。对于m=0.3和m=0.6的样品,120K温度和1T磁场下磁电阻比可达-10%左右。     

稀土钙钛矿型LaMnO3+λ催化剂的结构与性能的研究

研究了稀土钙钛矿型LaMnO3 λ催化剂的结构与性能的关系,合成过程中控制氧分压的不同,所得样品的结构与性能存在差异,并呈现规律性变化.该系列催化剂分别进行了CO氧化,二甲苯燃烧,水汽转化实验,其催化性能的差异与其结构变化相吻合.     

Highly effective La-deficient La_(1-x)Ce_xMnO_3 mixed oxides for the complete oxidation of methane

La-deficient La_(1-x)Ce_xMnO_3 mixed oxides, obtained by selective dissolution in 1 M nitric acid, were employed in methane complete oxidation. The majority of the La cations in these perovskites were removed, resulting in increased specific surface areas, better reducibility and greater activity. Incorporation of a small amount of Ce stabilized the structure and a perovskite phase persisted in La-deficient La_(1-x)Ce_xMnO_3 mixed oxides after 12 h of acid dissolution. La_(0.95)Ce_(0.05)MnO_3 after the acid treatment exhibited satisfactory catalytic activity, with T50 and T90 values of 365 and 459℃, respectively, which was even comparable to that previously reported 1% Pd/Al_2O_3 catalysts. And it showed excellent long-term activity even in the presence of CO_2 and H_2O.     

氯苯反溶剂制备p-i-n型钙钛矿太阳能电池的性能优化

在使用反溶剂辅助的一步旋涂法制备钙钛矿太阳能电池（Pero-SCs）中的钙钛矿层时,前驱体溶液的配方对反溶剂的种类十分敏感。目前对反溶剂的研究主要集中在反溶剂的种类上, 少有研究针对某一种反溶剂,结合前驱体溶液的溶剂组分和反溶剂的滴加时间与用量来探索最优制备条件。基于此,将氯苯作为反溶剂,在碘化铅（PbI2）: 氯化铅（PbCl2）: 甲基碘化铵（MAI）= 1.25 M: 0.15 M: 1.3 M且溶剂为γ-丁内酯（GBL）和二甲基亚砜（DMSO）的体系中,当前驱体溶液溶剂体积比为7:3,反溶剂用量为500 μL,反溶剂滴加时间为倒数第10 s时,制备的钙钛矿薄膜晶粒小且致密,表面粗糙度较小,结晶度、吸光度和缺陷状态均为最佳,最终得到的最佳电池效率为14.90 %。     

利用脉冲激光剥蚀技术制备PZT铁电薄膜

利用脉冲激光剥蚀技术在抛光的硅片上制备出了Ｐｂ（Ｚｒ，Ｔｉ）Ｏ３铁电薄膜．经过淀积后的激光退火工艺，大大改善了这种膜的铁电性．研究了影响薄膜性能的多种因素，利用Ｘ射线衍射，分析了薄膜的结构．测量了薄膜的居里温度和电滞回线     

低浓度甲醇完全氧化钙钛矿型La1-xSrxMnO3催化剂研究

采用溶胶－凝胶法制备钙钛矿型复合氧化物Ｌａ１－ｘＳｒｘＭｎＯ３,研究其对低浓度甲醇完全氧化催化性能．实验结果表明：Ｓｒ２＋取代量和样品焙烧温度对催化剂活性均有显著影响,以８７３Ｋ焙烧的Ｌａ０．６Ｓｒ０．４ＭｎＯ３的催化活性为佳;催化剂的ＢＥＴ,ＸＰＳ,Ｏ２－ＴＰＤ,Ｈ２－ＴＰＲ表征研究结果证实,较大的比表面,较高的表面Ｍｎ浓度和氧吸附量都有利于催化剂活性的提高．