吕梁地区近周营组蚀变火山岩 U-Pb-Hf同位素特征及其地质意义

选择吕梁群中原岔上群北部地层的蚀变火山岩进行锆石U-Pb年代学和Hf同位素研究。锆石U-Pb测试获得两组年龄结果, 较年轻的谐和年龄为1813±6 Ma (n=7), 较老的²⁰⁷Pb/²⁰⁶Pb加权平均年龄为2516±31 Ma(n=2), 前者为火山岩喷发时代, 后者代表捕获锆石年龄。年轻锆石的ε_Hf(t)值为-10.8~-2.3, T_DM1值为2308~2655 Ma; 捕获锆石的ε_Hf(t)值为+10.0~+13.1。年龄约为2.5 Ga锆石的ε_Hf(t)值高于亏损地幔演化线, 考虑到UPb同位素和Hf同位素测点位置不完全相同, 说明所获得的Hf同位素组成为无地质意义的混合数值; 年龄约为1.8 Ga锆石的Hf同位素特征反映其可能源于富集地幔或受地壳物质混染的亏损地幔。结合前人的研究成果, 推断岩浆作用事件发生在约1.81 Ga 的碰撞后阶段。     

浙西北钟吕群流纹岩锆石U-Pb年龄及其年代地层学意义

 钟吕群出露于浙西北地区,为一套强变形、浅变质的碎屑岩-火山岩系,其下未见底,上被南华纪休宁组不整合覆盖。传统上将其对比于赣东北双桥山群。本文主要研究钟吕群流纹岩的锆石U-Pb 年龄。样品A120408-4 采自苏庄断层以北,层位上属钟吕群的中上部,岩性为灰白色致密块状流纹岩,强烈片理化。样品A120408-4 中获得大量锆石,完成LA-ICP-MS 锆石UPb定年测点38 个,获得年龄加权平均值为(777.1±3.6)Ma,结合地层特点及变质变形特征,得出钟吕群主体相当于河上镇群上墅组,应属扬子古陆新元古代晚期大陆裂谷的地质记录。     

Constraint on the late Mesozoic regional angular unconformity in West Liaoning--North Hebei by LA-ICP-MS dating

The angular unconformity between the Tuchengzi Formation and the Zhangjiakou Formation in the Chengde area is commonly regarded as the direct evidence of boundary between Jurassic and Cretaceous systems, and as the evidence of tectonic transformation interfaces in Mesozoic Era in the West Liaoning-North Hebei. Moreover, the lower boundary age of the Zhangjiakou Formation in the Chengde was to be thought about 135 Myr in the past. Based on the detailed study and systematic sampling in Yixian-Beipiao, Lingy- uan, Chengde and Luanping areas in the field, the authors obtained the following isotopic ages by means of LA-ICP-MS dating： In the Lingyuan area, the Zhangjiakou Formation and the Yixian Formation are in angular unconformable contact; the age range of the Zhangjiakou Formation volcanic rock is from 133 to 130 Myr （seven samples）, and that of the Yixian Formation volcanic rock is from 126 to 121 Myr （eleven samples）. In the Luotuoshan of Chengde, the Tuchengzi Formation and the Zhangjiakou Formation are in angu- lar unconformable contact; the age at the lower Zhangjiakou Formation is about 124 Myr （one sample）, which reflects that the age range of the lower Zhangjiakou Formation is from 129 to 124 Myr combined with the previous study. In the Luanping basin, there is the larg- est sediment gap in upper Mesozoic, whose lower boundary age is confined in 131 to 130 Myr. In the Yixian-Beipiao area, the second Member of the Yixian Formation, making up more than 3/4 thickness of the Yixian Formation, was formed in 126 to 119 Myr, and the age of the Yixian Formation at the bottom is about 132 Myr. Moreover, the upper boundary age of the Tuchengzi Formation is about 136 Myr in the West Liaoning-North Hebei region. Based on the above isotopic data combined with the geological characteristics in the field in the West Liaoning-North Hebei region, it reflects that there was a widespread tectonic event in the period of 136 to 126 Myr （mainly in 130-126 Myr） in the West Liaoning-North Hebei, and it formed th     

LA-ICP-MS dating of Zhangjiakou Formation volcanic rocks in the Zhangjiakou region and its geological significance

The geological cross section of the Zhangjiakou Formation is originally established in the Zhangjiakou region. From the dating of four samples from typical cross sections of the Zhangjiakou Formation in the Zhangjiakou region, the age range is found to be mainly from 143.0 ± 3.7 Myr to 136.1 ± 1.4 Myr, which almost equals the sum of the age range of the Zhangjiakou Formation （136-135 Myr） and that of the Tuchengzi Formation （143-136 Myr） in the Luanping region, and the Zhangjiakou and Tuchengzi Formations in Zhang- jiakou-Luanping of North Hebei are found to be conformable. The evidence above indicates that the Zhangjiakou and Tuchengzi Formations, which are distributed in Zhangjiakou-Luanping, were formed under the same geological setting. Volcanic activity was earlier and longer （143-136 Myr） in the western region （Zhangjiakou） than that in the eastern region （Luanping）. The ＂Zhangjiakou Formation＂ in Chengde and Pingquan formed in the period in which the Yixian Formation in West Liaoning formed, so should be renamed the Yixian Formation.     

～4.1 Ga xenocrystal zircon from Ordovician volcanic rocks in western part of North Qinlin80rosenic Belt

High-precision U-Pb dating by in situ LA-ICP-MS yields an age of 4079±5 Ma for a xenocrystal zircon from Ordovician volcanics of the Caotangou Group in western part of the North Qinling Orogenic Belt. As a result, the North Qinling Orogenic Belt becomes one of a few localities in the world that contain Hadean age records （4276±6 Ma and 4404±8 Ma detrital zircons from Jack Hill of the Yilgarn craton, 4016 Ma Acasta gneisses of the Wopmay Orogeny and Burang quartzite with detrital zircon of 4103 Ma in Tibet）. It is also the first report of the Hadean age in Phanerozoic volcanics. The finding of the 4.1 Ga xenocrystal zircon provides not only the geochronological record of the oldest crustal materials in China, but also the condition for further search for rocks forming in the region during the early time of the Earth＇s evolution. Thirty-six zircon U-Pb dates from the Ordovician volcanic rocks are subgrouped into seven generations that represent different tectono-magmatic events in the North Qinling Orogenic Belt. Among them, two periods of 0.9--1.5 Ga and 0.4--0.5 Ga are consistent with Mesoproterozoic and Early Paleozoic orogenies, respectively.     

秦岭柞水岩体和东江口岩体的锆石U-Pb 年代学及其意义

柞水岩体和东江口岩体位于秦岭造山带南秦岭构造域, 主要由似斑状花岗闪长岩和二长花岗岩组成。通过LA-ICP-MS 锆石U-Pb 同位素定年, 结合锆石阴极发光图像, 揭示柞水岩体的似斑状二长花岗岩(样品ZS01-01)存在两个谐和年龄, 分别为209±2和199±2Ma;东江口岩体似斑状二长花岗岩(样品ZS04-01)也存在两个谐和年龄, 分别为219±2 和209±2 Ma。结合前人的地球化学和区域构造背景研究, 判定这两个岩体属于同一岩浆事件的不同阶段侵位, 东江口岩体的似斑状二长花岗岩侵位结晶略早于柞水岩体, 柞水岩体主期岩浆侵位时, 东江口岩体也有同期岩浆侵位结晶。这两个岩体年龄的准确测定, 表明在219 ～199 Ma 期间沿商丹断裂有3个阶段的构造-岩浆活动。     

春秋时期秦青铜器微量元素的激光剥蚀等离子体质谱

利用激光剥蚀等离子体质谱测定甘肃礼县、陕西陇县、宝鸡、凤翔出土的春秋时期秦青铜器中微量元素.研究发现:青铜器物不同组成部分所用原料是相同的,同一器物本体和补块使用了同样的原料.因子分析显示礼县、陇县、宝鸡和凤翔四个地区秦青铜器中的微量元素组成无显著差异,说明秦人可能已经拥有独立的矿冶和青铜制造业,而且有着比较稳定的矿料来源.激光剥蚀等离子体质谱具有的特点,为测试青铜器残存基体中的微量元素提供了非常好的测试研究方法.研究结果进一步丰富了春秋时期秦人历史文化研究的内容,也为研究文物微区的微量元素组成提供了新方法.     

不同激光束直径对LA-ICP-MS检测泥土的准确性影响分析

目的:通过试验找出不同模式下,适合用于电感耦合等离子体质谱与激光联用技术检测泥土的激光束直径。方法:在raster取样方法和线取样方法下,分别取激光束直径为25um,50um,100um,150um,200um,对标准土样GSS-1到GSS-8进行检测,并对ICP计数、样品相应元素测试准确性和标准曲线的相关系数三个方面进行分析。结果:在raster取样方法和线取样方法下,激光束直径为150um时测量值准确,相关系数均在0.99以上。结论:150um的直径最为合适。     

辽南梁屯-矿洞沟古元古代岩体LA-ICP-MS锆石U-Pb年龄及岩石地球化学特征

辽南梁屯-矿洞沟古元古代岩体包括坎子岩体、卧龙泉岩体、学校后街岩体与梁屯岩体,岩性分别为中细粒二长花岗岩、中细粒似斑状黑云母二长花岗岩、细粒黑云母二长花岗岩、细粒正长岩。学校后街岩体与梁屯岩体LA-ICP-MS锆石U-Pb年龄加权平均值为1 887.2±5.4 Ma、1 883.9±2.6 Ma,为古元古代。从坎子岩体到梁屯岩体岩石化学体现了一个偏铝-过铝型,钙碱性-碱性的演化序列,K及Mg O含量逐渐增高,富集大离子亲石元素K、Rb、Ba、Sr,亏损高场强元素Nb、Ta、Zr、Hf,稀土元素配分模式右倾,属具有负铕异常的轻稀土富集、重稀土亏损型。结合相关构造环境分析,古元古代岩体在辽河岩群沉积完成后存在着一个活动大陆边缘-碰撞造山-造山晚期,岩石类型由I型-S型-A型的演化过程。     

西藏芒康盆地粗面岩LA-ICP-MS锆石U-Pb定年及地质意义

通过对藏东地区芒康盆地拉屋拉组高钾岩体(粗面岩体)2个代表性样品的LA-ICP-MS锆石U-Pb同位素年龄测试,获得该岩体的形成时代。岩石蚀变较轻,主要由长石(斜长石、钾长石)和黑云母组成;其LA-ICP-MS锆石U-Pb测年得到的加权平均年龄分别为(35.2±1.3)Ma和(36.4±0.3)Ma。这些测年值为高钾岩体的形成提供了一个准确时限。同时表明,芒康盆地高钾岩体属晚始新世的产物,为藏东地区金沙江-红河构造带的重要组成部分,也是金沙江-红河构造带发生局部的陆内俯冲的又一具体表现。