金属陶瓷复合涂层技术

金属陶瓷复合涂层技术是优越的现代材料表面处理技术和材料复合技术。对各种金属陶瓷复合涂层技术的主要内容，发展概况和技术特点进行了综述，对各种涂层技术的发展趋势进行了展望。     

Microstructure and mechanical properties of Cr doped WCoB based cermets by spark plasma sintering and first principle calculation

WCoB based cermet is a potential hard alloy to replace WC-Co cermets with high hardness and corrosion resistance. WCoB based cermets with different Cr doping contents were fabricated by spark plasma sintering in liquid phase sintering stage. The densification behavior, phase composition, microstructure and mechanical properties of Cr doped WCoB cermets were investigated by XRD, EDS and SEM. Due to the lower density of Cr,the density of WCoB cermets decreased with the increasing of Cr doping content. The phase composition consisted of Cr doped WCoB, unreacted W, Co–Cr binary binder phase. When the doping content exceeded11.736 wt%, the Cr enrichment zones appeared, which was harmful to the TRS. The increasing of Cr doping content contributed to the increase of unreacted W phases content and the formation of pores. The maximum value of Vickers hardness was 1751 Hv0.5 at 9.356 wt% Cr doping content. The variation trend was explained by first principle calculation, which is consistent with Hv-Zhou hardness model.     

超细Ti(C,N)基金属陶瓷硬质相粉末的分散行为

通过粒径和ζ电位的测定，探讨了超细TiN、TiC和WC粉末在水溶液和无水乙醇中的分散行为以及表面活性剂对分散的影响．实验结果表明：分散介质的种类和介质的pH值对3种超细粉的分散效果有很大有影响，表面活性剂聚氧乙烯十二烷基醚和聚乙二醇可作为超细TiC粉末在水溶液和乙醇溶液中分散、以及超细WC在水溶液中分散的分散剂．