以氧化钙为主要原料从铌钽矿富锆尾矿中制备氧氯化锆

对铌钽矿的富锆尾矿与碱石灰在一定温度下熔融 ,经过一系列化学处理来制备ZrOCl2 ·8H2 O的方法进行了研究。结果表明 :在用氧化钙熔融法分解富锆尾矿过程中加入少量NaOH可以大大提高锆的浸出率。进而提出了用廉价的生石灰作原料 ,以少量固体氢氧化钠作为反应助剂来分解富锆尾矿 ,生产氯氧化锆的新方法。确定了相应的反应条件为 :NaOH :CaO :尾矿的质量比 =0 .2 :1 .5 :1 ;熔融温度为 1 2 5 0℃ ,时间 2h。     

Triassic U-Pb age for zircon from granites in the Tonghua area and its response to the Dabie-Sulu ultrahigh-pressure collisional orogenesis

Single-grain zircon U-Pb dating was carried out to constrain the emplacement timing of granitic plutons at Chaxinzi, Xiaoweishahe and Longtou in the Tonghua area, south of Jilin Province. The results show that these plutons formed in the Triassic with ages of 203—217 Ma. Geological and geochemical characteristics indicate that the plutons are composed of quartz diorite and granite. The former was derived from partial melting of mafic lower crust, whereas the latter originated from thickened crust with garnet as the residue in the source. It appears that protoliths of these two types of granitits are different although they have the same emplacement age. Considering that these plutons are petrologically different from the coeval granites in the Xingmeng (Xing‘an-Mongolian) to Jihei (Jilin-Heilongjiang) orogenic belt in the north, it is suggested that their formation was related to the Dabie-Sulu ultrahigh-pressure collisional orogenesis since their ages are only 10—20 Ma younger than timing of the ultrahigh-pressure metamorphism, but comparable to that of the first rapid exhumation of the ultra-high-pressure metamorphic rocks and the emplacement of the post-collisional granites.     

SHRIMP zircon U-Pb dating for volcanic rocks of the Dasi Formation in southeast Hubei Province, middle-lower reaches of the Yangtze River and its implications

The Jinniu Basin in southeast Hubei,located at the westernmost part of middle-lower val-ley of the Yangtze River,is one of the important vol-canic basins in East China. Volcanic rocks in the Jin-niu Basin are distributed mainly in the Majiashan Formation,the Lingxiang Formation and the Dasi Formation,consisting of rhyolite,basalt and basaltic andesite,(trachy)-basalt and basaltic trachy-andesite and (trachy)-andesite and (trachy)-dacite and rhyolite respectively,in which the Dasi volcanism is volumet-rically dominant and widespread. The Dasi volcanic rocks were selected for SHRIMP zircon U-Pb dating to confirm the timing of volcanism. The results indi-cate that there exist a large amount of magmatic zir-cons characterized by high U and Th contents in the volcanic rocks. The concordia ages for 13 points are 128 ± 1Ma (MSWD = 3.0). On account of the shape of zircons and Th/U ratios,this age is considered to represent the crystallization time of the Dasi volcan-ism. The volcanic rocks in the Dasi,Majiashan and Lingxiang Formations share similar trace elementand REE partition patterns as well as Sr-Nd isotopic compositions. In combination with the regional geol-ogy,it is proposed that the southeast Hubei volcanic rocks were formed mainly during the Early Creta-ceous,just like other volcanic basins in middle-lower Yangtze valley. A lithospheric extension is also sug-gested for tectonic regime in this region in the Cre-taceous Period.     

辽北新宾?苇子峪地区太古宙花岗质岩石的形成年代、成因及其地质意义

辽北新宾?苇子峪地区的花岗质岩石主要由英云闪长质?奥长花岗质片麻岩和二长花岗岩?正长花岗岩岩体等组成。为确定其形成年代及成因, 对这些花岗质岩石进行锆石U-Pb-Hf同位素和全岩地球化学分析。锆石LA-ICP-MS U-Pb同位素定年结果表明这些花岗质岩石均形成于新太古代, 英云闪长质和奥长花岗质片麻岩的岩浆结晶年龄分别为2588±4 Ma (MSWD=1.3)和2587±6 Ma (MSWD=1.8), 二长花岗岩?正长花岗岩则侵位于2555±4 Ma (MSWD=0.51)。全岩地球化学和锆石Lu-Hf同位素研究表明, 英云闪长质?奥长花岗质片麻岩形成于俯冲板片的部分熔融, 其原始岩浆在上升过程中受到地幔楔岩石的交代; 而二长花岗岩?正长花岗岩中一部分岩浆起源于变质杂砂岩的部分熔融, 其余形成于以变质玄武岩与变质沉积岩为主要成分的混合源区的部分熔融。结合近年的研究成果, 认为新宾?苇子峪地区的新太古代花岗质岩石可能形成于活动大陆边缘的动力学背景。     

大兴安岭中段哈达陶勒盖组火山岩U-Pb定年及成因

为了研究大兴安岭中段哈达陶勒盖组火山岩的形成时代和岩石成因,进行了锆石U-Pb同位素年龄测试和地球化学研究.LA-ICP-MS锆石U-Pb定年结果显示,哈达陶勒盖组火山岩形成于234~244Ma的中三叠世.岩石地球化学研究表明,哈达陶勒盖组火山岩具有低硅富碱、富钙镁的特征;稀土丰度总量w(∑RE)= 122.32×10^-6~140.66×10^-6,轻、重稀土分馏较明显,m(La)/m (Yb)_N=11.99~18.68, 无明显Eu负异常(δ_○Eu=0.84~0.98),微量元素以富集Rb,K,Ba,Th,亏损Nb,P,Ti为特征.哈达陶勒盖组火山岩岩浆源区为富集的岩石圈地幔, 并遭受了地壳物质的混染.     

西秦岭中生代花岗岩锆石U-Pb-Lu-Hf同位素特征及地质意义

对西秦岭地区中川岩体、柏家庄岩体和教场坝花岗岩体进行LA-ICP-MS锆石U-Pb同位素年代学分析, 获得其岩浆侵位年龄分别为220±1, 216±6和222±3 Ma, 表明3个岩体均形成于中?晚三叠世。样品的全岩地球化学分析结果表明, 3个岩体具有相似的稀土及微量元素特征, 均表现为显著亏损高场强元素Nb, Ti和P等, 具有明显的右倾式球粒陨石标准化稀土元素配分模式。锆石Lu-Hf同位素分析结果表明, 3个岩体锆石测年样品的ε_Hf(t)值介于?3.31~+1.68之间, 二阶段模式年龄介于1151~1456 Ma之间。岩石成因分析表明, 这些印支期花岗岩体的母岩浆主要来源于新元古代地壳物质的部分熔融。结合岩体形成时代、岩石成因和区域岩浆作用, 认为这些岩体形成于南秦岭与华南板块沿勉略缝合带相碰撞的造山动力学背景, 可能与华南板块的俯冲板片断离有关。     

哈尔滨东部海西期钾长花岗岩的锆石U-Pb年代学及其地质意义

通过对哈尔滨东部地区海西期钾长花岗岩年代学、地球化学特征的研究,讨论兴蒙造山带的演化.研究区钾长花岗岩呈肉红色细粒,主要由钾长石、斜长石、石英和黑云母组成.岩石中siO2的质量分数为74.70％～75.70％,为酸性岩.Al2 O3的质量分数为12.07％～13.18％;Na2O+K2O的质量分数为7.78％～8.09％,K2O/Na2O为0.93％～1.60％.里特曼指数为1.85～2.06.∑REE的质量分数为96.32×10-6～172.83×10-6,δEu为0.21～0.77,为铕负异常;铝饱和指数为0.88～1.12,属于高钾钙碱性花岗岩,与造山带垮塌导致的大规模岩石圈伸展作用有关.该花岗岩LA-ICP-MS锫石U-Pb年龄为(298.54士0.86) Ma(MSWD=0.94),属于晚石炭世,形成于古亚洲洋闭合后兴安地块和松嫩地块碰撞拼合后的伸展作用.     

Zircon U-Pb ages of granites at Changba and Huangzhuguan in western Qinling and implications for source nature

Mesozoic granitoids are widespread in the Qinling-Dabie-Sulu orogenic belt. Precise U-Pb dating on these granitoids can reveal the evolution of the continental collision orogen and thus provide information on the nature of magma sources. This study presents zircon LA-ICP-MS U-Pb dating and whole-rock geochemical analyses for two intrusions at Changba and Huangzhuguan in western Qinling. Zircon U-Pb ages for central and marginal phases of the Huangzhuguang intrusion are 214±1 Ma and 213±3 Ma, respectively. Zircons from the Changba intrusion yield a dominant cluster with an U-Pb age of 213±2 Ma. Collectively, these ages are younger than ages of 220 to 240 Ma for ultrahigh-pressure metamorphism due to the continental collision between the South China Block and the North China Block, corresponding to syn-exhumation magmatism. Some inherited zircons occur in the Changba intrusion, yielding a weighted mean of ²⁰⁶Pb/²³⁸U ages at 757±14 Ma. This indicates that the Changba intrusion has the crustal source of mid-Neoproterozoic ages and a tectonic affinity to the South China Block. Geochemically, the two intrusuons are both rich in LILE and LREE but depleted in HFSE and HREE, similar to arc-type igneous rocks. The Huangzhuguang intrusion exhibits linear correlations between SiO₂ and the other major oxides, implying chemical evolution from a cognate magma source. It contains mafic enclaves, suggesting possible mixing of felsic-mafic magmas. The Changba granite is rich in Si and K but poor in Fe and Mg as well as has a high value of Fe*, suggesting strong differentiation of granitic magma. Therefore, the two intrusions were derived from the Late Triassic anatexis of the continental crust of different compositions in the northern margin of South China Block. This process may be coupled with exhumation of the subducted continental crust in the stage of late collision.