催化光度法测定甲醇

基于甲醇对K2S2O8与亮绿间的氧化裉色反应有强烈的负催化作用,从而建立了一种测定甲醇动力学光度新方法.该法的线性范围为8.0×10-6～4.0×10-4mol/L;检出限为2.7×10-6mol/L;对1.0×10-5mol/L甲醇溶液连续进行11次测定,相对标准偏差为4.2%.将该方法用于工业洒精样品中甲醇含量的测定,结果较为满意.     

Polarized Emission of Molecular Film With Lanthanide (Ⅲ) Complex

1 Results In the coordination system by using complexation with organic ligand, the ff emission of lanthanide(Ⅲ) (Ln(Ⅲ)) is induced the excitation energy transfer form the organic chromophore under the light-irradiation. However, there are not so much number of reports to discuss the energy relaxation mechanism in such complexes with Ln(Ⅲ). Recently, we succeeded firstly to estimate the rate constant of the energy transfer between the ligand and Ln(Ⅲ) in Pr(Ⅲ)-phenanthroline analogs[1]. Here, we will di...     

新型纳米纤维膜对地下水中重金属的过滤去除研究

采用扫描电镜表征了氯化聚氯乙烯静电纺丝纳米纤维膜的微观结构特征,并进行了去除地下水中铜、铅、镉等重金属阳离子的过滤试验,包括直接过滤、加土壤过滤、加硅藻土过滤和胶束强化过滤。结果表明,最佳的过滤工艺是胶束强化过滤,其最佳试验条件是10层膜过滤和5mmol/L的SDBS浓度,对铜、铅、镉的去除率分别超过73%,82%和91%。     

羧基淀粉的制备及其吸附性能的研究

本文研究羧基淀粉的制备条件与吸附重金属离子的容量关系,并研究它的使用条件和性能。     

催化电位法测定人发中痕量碘

采用碱灰化法消解发样,于中性溶液中离心去除杂质,在酸性溶液中以催化电位法测定发碘含量,回收率达98.6％;变异系数(CV)为8.7％;测出中碘地区一个教学班20名男学生发碘平均含量为0.93μg/g,与文献报道相近。     

液态金属压铸机的实时压射控制系统

为了满足压铸工艺的要求，有必要进行压射机构的改造并对压射实施自动控制．为此，研究了液态金属压铸机压射结构的重新设计及其实时控制，设计了一套对压射进行实时控制的系统，着重研究了该系统的组成、基本原理及其特点．     

烟气分析在转炉冶炼过程中的应用研究

介绍转炉烟气分析控制系统,研究转炉烟气和炉气在冶炼过程中的变化规律,并开发烟气定碳模型。结论表明,在转炉冶炼过程中利用烟气成分的变化规律,可进行转炉炉况判断、终点判断和了解炉内反应过程。开发的烟气定碳模型对于含碳量低于0.12%的炉次,其控制精度为±0.02%,命中率为90%。     

The detection of structural deformation errors in attitude determination

In the determination of the attitude parameters from a multi-antenna GPS array, one of the major assumptions is that the body frame is rigid at all times. If this assumption is not true then the derived attitude parameters will be in error. It is well known that in airborne platforms the wings often experience some displacement during flight, especially during periods of initializing maneouvres, such as taking off, landing,and banking. Often it is at these points in time that it is most critical to have the most precise attitude parameters.There are a number of techniques available for the detection of modeling errors.The CUSUM algorithm has successfully been implemented in the past to detect small persistent changes. In this paper the authors investigate different methods of generating the residuals, to be tested by the CUSUM algorithm, in an effort to determine which technique is best suited for the detection of structural deformation of an airborne platform. The methods investigated include monitoring the mean of the residuals generated from the difference between the known body frame coordinates, and those calculated from the derived attitude parameters. The generated residuals are then passed to a CUSUM algorithm to detect any small persistent changes. An alternative method involves transforming the generated residuals into the frequency domain through the use of the Fast Fourier Transform. The CUSUM algorithm is then used to detect any frequency changes. The final technique investigated involves transforming the generated residuals using the Haar wavelet. The wavelet coefficients are then monitored by the CUSUM algorithm in order to detect any significant change to the rigidity of the body frame.Detecting structural deformation, and quantifying the degree of deformation, during flight will ensure that these effects can be removed from the system, thus ensuring the most precise and reliable attitude parameter solutions. This paper, through a series ofsimulations, will assess the effectiveness of the above mentioned techniques for detecting structural deformation effects on a GPS multi-antenna array. These principles are then tested with experimental data.     

高功率型镍氢电池的循环性能

由于没有镉污染,对环境友好,用于高功率设备的镍氢电池的需求量增长很快,目前每年的需求量约为5亿只.但是镍氢电池的一些性能还不能完全满足电动工具的使用要求,突出表现在电池大电流充放循环寿命较差.因此,研制高性能的高倍率镍氢电池不仅具有重要的研究意义,也有很大的应用价值.本文研究影响SC型动力电池循环寿命衰减的主要因素,测量了在大电流循环过程中镍氢电池的内阻、温度及重量变化,并运用SEM、XRD对电池内阻升高的原因进行了分析.我们认为电池内阻升高是镍氢电池大电流循环寿命差的主要原因,分析发现在镍氢电池进行大电流充放电循环时,电池正极膨胀,负极微粉化,电池内部孔隙率增加,致使电解液干涸,电池内阻升高.通过增加负极容量,抑制正极膨胀,可以有效改进镍氢电池大电流充放时的循环性能.     

论艺术概括的基本方式和三个层次

艺术概括是塑造优秀文学形象的重要手段 ,它的基本方式是必须融会在个性书写过程中 ,以个性书写为形态。艺术概括包涵三个由浅入深的层次 ,即 ( 1)通过个性概括同类现象的共同特征 ;( 2 )通过个性深入揭示内在本质 ;( 3 )通过个性显示深广的社会意义。达到这三个层次 ,文学形象便可获得深厚的内在意蕴