低氧LiF–NdF3熔盐体系阳极过程的电化学行为研究

The oxidation of oxygen ions and the generation of an anode effect at a low oxygen content of 150 mg/kg were discussed in this paper. Cyclic voltammetry and square-wave voltammetry tests were conducted to explore the anodic processes of LiF–NdF₃ melt after a lengthy period of pre-electrolysis purification at 1000°C (during which the oxygen content reduced from 413 to 150 mg/kg). The oxidation process of oxygen ions was found to have two stages: oxidation product adsorption and CO/CO₂ gas evolution. The adsorption stage was controlled by diffusion, whereas the gas evolution was controlled by the electrochemical reaction. In comparison with oxygen content of 413 mg/kg, the decrease in the amplitude of the current at low oxygen content of 150 mg/kg was much gentler during the forward scanning process when the anode effect occurred. Fluorine-ion oxidation peaks that occurred at about 4.2 V vs. Li/Li+ could be clearly observed in the reverse scanning processes, in which fluorine ions were oxidized and perfluorocarbons were produced, which resulted in an anode effect.     

不同生长时期泽泻蕨叶片光响应曲线的研究

为探索人工栽培过程中泽泻蕨营养生长期和生殖生长期对光强的不同需求,运用气体交换法研究了以上两个时期泽泻蕨叶片的光响应曲线及相关参数,并选取了适用于泽泻蕨的光响应曲线模型.结果表明:泽泻蕨营养生长期和生殖生长期叶片的光响应曲线趋势相似,营养生长期的表观光量子效率大于生殖生长期,差异不显著,最大净光合速率和光饱和点显著大于生殖生长期,暗呼吸速率、光补偿点等指标均与生殖生长期差别不大;在泽泻蕨双曲线模型的拟合方面双曲线修正模型较其他常用模型更为精确.实验认为泽泻蕨营养生长期叶片较生殖生长期更适应弱光环境,且具有较低的光饱和点,可能在高光强更易出现光抑制.     

层式通风房间垂直温度分布预测方法

基于层式通风房间室内空气流动特性建立了室内垂直温度分布预测模型.该模型将室内空气流动特性与热质平衡方程有机结合,并反映了室内热源强度、墙体辐射及送风参数等边界条件对室内垂直温度分布的影响.通过将模型计算结果与实验数据进行对比分析,发现室内垂直温度预测值与实验数据吻合较好,并在趋势上反映出层式通风房间室内垂直温度的变化特征.因此,本文提出的模型具有较好的预测精度,能够很好地用来指导层式通风系统的实际应用及能耗分析.     

工程图学斜轴测投影矩阵变换算法

用矩阵变换算法研究了轴测投影的图形问题学,探讨了错切变换的有效性和多样性,通过改变变换矩阵中的参数值和错切变换的矩阵变换组合方式,生成不同轴间角和轴向伸缩系数的斜轴测投影图.发现错切变换结果是多种多样的,可以生成满足不同工程需要的斜轴测投影图,为教学和编程提供了一种有效的制图方法.     

纳米孔壳聚糖接枝四(对-羧基苯基)锰卟啉催化氧化乙苯

为模拟细胞色素P-450酶的催化空腔场所,提高壳聚糖接枝四(对-羧基苯基)锰卟啉(Mn TCPP)的催化活性。采用冷冻干燥法制备纳米孔壳聚糖(np-CTS),并用酰化反应接枝四(对-羧基苯基)锰卟啉获得仿生催化材料―Mn TCPP/np-CTS,同时制备相应的无孔催化材料―Mn TCPP/nonp-CTS。用紫外可见光谱(UV-vis),傅里叶变换红外光谱(FT-IR),X射线(XRD),热重分析(TG)和扫描电镜(SEM)技术对其进行表征,并用于催化空气氧化乙苯研究。催化结果表明:在最佳反应条件下(145℃,0.8 MPa),纳米孔壳聚糖接枝四(对-羧基苯基)锰卟啉比无孔催化材料催化活性提高26%,醇酮收率提高38%。实验结果表明:纳米级空腔有利于充分发挥所固载的锰卟啉催化活性,最大程度地提高固载仿生催化材料的催化效率。     

Design of optimum solid oxide membrane electrolysis cells for metals production

Oxide to metal conversion is one of the most energy-intensive steps in the value chain for metals production. Solid oxide membrane (SOM) electrolysis process provides a general route for directly reducing various metal oxides to their respective metals, alloys, or intermetallics. Because of its lower energy use and ability to use inert anode resulting in zero carbon emission, SOM electrolysis process emerges as a promising technology that can replace the state-of-the-art metals production processes. In this paper, a careful study of the SOM electrolysis process using equivalent DC circuit modeling is performed and correlated to the experimental results. A discussion on relative importance of each resistive element in the circuit and on possible ways of lowering the rate-limiting resistive elements provides a generic guideline for designing optimum SOM electrolysis cells.     

旋转激励振动载荷对平面摩擦副的影响实验

振动可以减小摩擦,利用自制的旋转激励环境下摩擦力测试实验装置研究了旋转激励振动载荷的幅值和频率对不同材料平面摩擦副摩擦力的影响。实验表明:旋转激励振动载荷降低了平面摩擦副的摩擦系数。相同激振频率下,随着名义振幅的增大,摩擦系数不断减小,且二者呈现近似线性关系。相同名义振幅条件下,Q235A-Q235A平面摩擦副摩擦系数减小率最大,Q235A-花岗岩平面摩擦副摩擦系数减小率次之,Q235A-400目砂纸平面摩擦副摩擦系数减小率最小。相同名义振幅下,随着激振频率的增大,摩擦系数亦呈现减小的趋势;在激振频率为15 Hz以前,摩擦系数减小速率较快,当激振频率超过15Hz后,摩擦系数减小速率变慢。     

河南省四个经济区产业梯度比较及优化探讨

通过计算比较劳动生产率和区位商,测算了河南省4个经济区的产业梯度系数,分析了4个经济区的产业差别,分别找出了4个经济区的优势产业。根据计算和分析结果,对河南省4个经济区工业行业优化调整提出了3点建议。     

行列式的计算方法解析

行列式求解在各个领域中有非常广泛的运用.通过分析一些具体实例,介绍了7种行列式的计算常用方法,包括n阶行列式、抽象行列式、行列式的展开定理以及代数余子式的应用,为今后学者们求解行列式提供了一些可行的方法.