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O Rozenblatt-Rosen RC Deo M Padi G Adelmant MA Calderwood T Rolland M Grace A Dricot M Askenazi M Tavares SJ Pevzner F Abderazzaq D Byrdsong AR Carvunis AA Chen J Cheng M Correll M Duarte C Fan MC Feltkamp SB Ficarro R Franchi BK Garg N Gulbahce T Hao AM Holthaus R James A Korkhin L Litovchick JC Mar TR Pak S Rabello R Rubio Y Shen S Singh JM Spangle M Tasan S Wanamaker JT Webber J Roecklein-Canfield E Johannsen AL Barabási R Beroukhim E Kieff ME Cusick DE Hill K Münger JA Marto J Quackenbush 《Nature》2012,487(7408):491-495
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Exposure of rare-earth films to hydrogen can induce a metal-insulator transition, accompanied by pronounced optical changes. This 'switchable mirror' effect has received considerable attention from theoretical, experimental and technological points of view. Most systems use polycrystalline films, but the synthesis of yttrium-based epitaxial switchable mirrors has also been reported. The latter form an extended self-organized ridge network during initial hydrogen loading, which results in the creation of micrometre-sized triangular domains. Here we observe homogeneous and essentially independent optical switching of individual domains in epitaxial switchable mirrors during hydrogen absorption. The optical switching is accompanied by topographical changes as the domains sequentially expand and contract; the ridges block lateral hydrogen diffusion and serve as a microscopic lubricant for the domain oscillations. We observe the correlated changes in topology and optical properties using in situ atomic force and optical microscopy. Single-domain phase switching is not observed in polycrystalline films, which are optically homogeneous. The ability to generate a tunable, dense pattern of switchable pixels is of technological relevance for solid-state displays based on switchable mirrors. 相似文献
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大叶白麻叶化学成分的研究 总被引:1,自引:0,他引:1
从大叶白麻[poacynumhendersonii(Hookf)woodson]叶中分得2个木脂素类化舍物,经理化常数测定和光谱分析,分别鉴定为(-)-丁香脂素[(-)-Syringaresino1]和( )-松脂素-4-O-β-D-葡萄糖甙[( )-Pinoresionol-4-0-β-D-glucopyranoside]. 相似文献
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